Responses of synanthropic vegetation to composting facility.

Composting facilities are habitats where biological materials are bio-oxidized. Biological waste represents a source of plant species diaspores and may promote changes in the species composition of the surrounding. The studied composting facility is situated in the Bohemian-Moravian Highlands, Czech Republic. Four sites, the composting pile and three habitats nearby were chosen of different use and disturbance conditions. Phytosociological plots were recorded in each of the habitat and the results were processed using multivariate analyses of ecological data. The information about plant species indication values was also analysed: (i) the relationship between soil disturbance and plant species occurrence, (ii) seed dormancy, (iii) seed bank, and (iv) vector of seed dispersion. During the research, 119 plant taxa were found in total. Conditions of the composting process (frequent disturbances, excessive available nutrients, enough water, and supply of new diaspores) represent a challenge for plant species. The presence of plant diaspores in the biowaste is a reason why the fundamental principle of appropriate composting process has to be adhered to. Another important task is to give attention to the methods determining the share of living diaspores in the final compost, which is still missing in practice. Compost might become a vehicle for spreading weeds. The capacity of vegetation to survive and multiply on the premises of composting facilities increases the importance of vegetation monitoring and control of the adjacent areas. The usual occurrence of rural brownfields near composting facilities increases the risk of diaspores being transmitted into biowaste or compost, thus increasing the share of undesirable viable diaspores. Composting facilities generate specific synanthropic conditions for the vegetation. Therefore, the composting facility projects should take into consideration the surrounding areas and vegetation management. It is recommended that the project should include semi-natural vegetation, which can create efficient barriers to the spreading of undesirable ruderal plant species. The novelty of this study is the confirmation that composting facilities and compost become a new factor affecting vegetation, which has been disregarded so far. The link between composting facilities and vegetation has to be included in the legislation related to parameters of compost quality. Moreover, the issue of weeds, their reproductive organs and their spread should be considered in the guidelines for the design, location, construction, and operation of composting facilities.

Urban Agriculture as an Alternative Source of Food and Water Security in Today's Sustainable Cities.

The concept of a regenerative city goes far beyond a sustainable one. The regenerative approach is to think of urban green space as a productive landscape, a source of food, and a support for biodiversity. In this approach, the so-called urban wastelands have a positive significance. Urban agriculture (UA) has become a commonly discussed topic in recent years with respect to sustainable development. Therefore, the combination of urban fabric and local food production is crucial for ecological reasons. The key issues are the reduction of food miles and the demand for processed food, the production of which strains the natural environment. At the same time, UA enables regeneration and restoration. An original methodological approach was used in the study following the mixed-method research concept: literature survey, case studies, and comparative analysis of objects. A review of UA architecture (UAA) projects was carried out to supplement the knowledge acquired during the bibliometric analysis. In sum, 25 existing projects, including allotment gardens, community gardens, and urban farms in the global north, were compared in this study. As a result of the analyses carried out, the breakdown of urban agriculture was developed into the following categories: (i) architectural-urban, (ii) ecological, (iii) social, and (iv) economic, including the impact of UA on physical activity and social interaction. UA is also a factor shaping the urban landscape. In conclusion, agrarian practice in urban environments has led to the creation of a new type of space, known as UAA. Production in the context of UA exceeds private goods, such as food produced for sale or for individual use. Additional goods include public goods. The review shows that UA fulfills economic, social, and environmental functions, thus falling under the concept of sustainable development.

Municipal solid waste landfill: Evidence of the effect of applied landfill management on vegetation composition.

Proper management of municipal solid waste (MSW) is crucial to avoid pollution, environmental impacts and threat to public health. The problem of MSW is mainly arising from inadequate landfill site management. The objective of this study was to evaluate the impact of management practices and environmental risks at two landfill sites. The landfills were subject to long-term (10 years) vegetation monitoring. The vegetation was assessed using a floristic survey of identified plant species. The vegetation analysis showed that significant differences existed between the two landfill locations, with neophytes, invasive and expansive species dominating on one of the landfill sites, which may be attributed to climatic and geomorphological differences between the two sites, but also to variations in landfill management. These environmentally problematic species can potentially spread from the landfill into adjacent ecosystems, displace native plants and degrade adjacent farmland areas. The study of vegetation monitoring data suggests that, in addition to other types of monitoring, landfills should be subjected to regular vegetation biomonitoring, too. Landfill management practices should target the regulation of unwanted species, create conditions that are favourable to native plant species and provide as early as possible the restoration of filled cells.

Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene.

Treatment of potassium salts of silole dianions with donor stabilised germanium dichlorides gave the anticipated silagermafulvenylidenes R2Si = Ge(Do) (R2Si = 1-silacyclopentadiendiyl, Do = N-heterocyclic carbene (NHC)) only as transient intermediates in a side reaction. They were detected by NMR spectroscopy and, in one case, the formal dimer, 2,4-disila-1λ3,3λ3-digermetane, was isolated. The main products of these reactions are sila-bis-λ3-germiranes, i.e. directly interconnected digermylenes that are part of a three-membered ring. The structural data, supported by the results of density functional calculations confirm the digermylene nature of these products with a long inner cyclic Ge-Ge bond that decreases the inherent high ring strain in silagermiranes.

Template Stripping of Perovskite Thin Films for Dry Interfacing and Surface Structuring.

Combining excellent optoelectronic properties with the benefits of solution processability, metal-halide perovskites are promising materials for photovoltaic and light-emitting technologies. To facilitate the integration of perovskite thin films into optoelectronic devices, a need exists for simple and efficient fabrication methods. Here, we present a template-stripping technique to produce ultraflat and flexible perovskite thin films. We apply a one-step spin-coating procedure to produce high-quality CH3NH3PbBr3 perovskite thin films on top of ultraflat silicon templates. These films can be mechanically cleaved from the template using a polymer adhesive to reveal the ultraflat perovskite surfaces. We demonstrate how the flatness and flexibility of the template-stripped films enable new processing strategies based on dry interfacing, by interfacing them with plasmonic hole arrays. Moreover, we show that by using prepatterned silicon templates, structured perovskite surfaces can be produced with feature sizes down to a micrometer.

Dual-Wavelength Lasing in Quantum-Dot Plasmonic Lattice Lasers.

Arrays of metallic particles patterned on a substrate have emerged as a promising design for on-chip plasmonic lasers. In past examples of such devices, the periodic particles provided feedback at a single resonance wavelength, and organic dye molecules were used as the gain material. Here, we introduce a flexible template-based fabrication method that allows a broader design space for Ag particle-array lasers. Instead of dye molecules, we integrate colloidal quantum dots (QDs), which offer better photostability and wavelength tunability. Our fabrication approach also allows us to easily adjust the refractive index of the substrate and the QD-film thickness. Exploiting these capabilities, we demonstrate not only single-wavelength lasing but dual-wavelength lasing via two distinct strategies. First, by using particle arrays with rectangular lattice symmetries, we obtain feedback from two orthogonal directions. The two output wavelengths from this laser can be selected individually using a linear polarizer. Second, by adjusting the QD-film thickness, we use higher-order transverse waveguide modes in the QD film to obtain dual-wavelength lasing at normal and off-normal angles from a symmetric square array. We thus show that our approach offers various design possibilities to tune the laser output.

Alternative method of composting on a reclaimed municipal waste landfill in accordance with the circular economy: Benefits and risks.

Waste composting is becoming a key element of integrated waste management. Composting has a number of advantages, including economic benefits, improvement of soil properties through the use of compost, reduction in the use of chemical fertilisers, and minimization of environmental pollution. Composting on a landfill surface appears to be an economical solution that can help close the waste loop and material cycle. In this study, a composting plant located on a landfill surface was analysed. The main objective of the research was to identify the species of plants growing in the organic fraction of municipal solid waste in temporary storage, in the composting plant, and in maturing compost located in a reclaimed plot at the landfill site. During monitoring, 88 plant species were identified altogether. It was observed that compost can become a source of weed infestation. To control the presence of weeds in the compost, basic principles of composting are to be followed to reduce the quantity of weed seeds. The thermophilic phase must occur to reduce the viability of seeds in the input materials and sufficient moisture must be ensured during the composting process. When these principles are strictly observed and the stored compost is maintained without vegetation, the supply of seeds in the compost will be low, and the undesirable spread of plant species to adjacent areas will be controlled. The results showed that the use of the obtained compost did not result in the propagation of weed species. This study demonstrates that composting on a reclaimed landfill offers various advantages such as a closed waste management cycle, coverage of the active landfill body, and fertilisation of the reclaimed part of the landfill.

Influence of a Municipal Solid Waste Landfill on the Surrounding Environment: Landfill Vegetation as a Potential Risk of Allergenic Pollen.

When the landfill use comes to end, important subsequent steps include aftercare, safety assurance, and ecological regeneration. Landfill revegetation is cost-effective and eco-friendly approach in the management of landfill areas, which serves the purpose of stabilization and provides a pleasant landscape. There are various vegetation types that can be planted, yet grass species are often used for low-cost reasons. Plants can be important sources of air pollution, particularly by grass pollen. The main goal of our study was to identify plant species that produce allergenic pollen. Long-term vegetation monitoring took place on three sites in the growing seasons of years 2008-2018. Studied objects were landfills located in the Czech Republic. The vegetation was assessed using a floristic survey of identified plant species. Plant species that produced allergens were recorded. During the monitoring, 298 plant species were determined. Plant species with allergenic pollen have a considerable share in the landfill vegetation. Thus, landfills are potential sources of various kinds of allergenic pollen. Moreover, our results indicated that there are three periods of pollen production: early spring, late spring, and early summer; late summer; and autumn. The second period is typical for the production of highly allergenic pollen by grasses. Most detected plant species with allergenic pollen are common for all monitored sites, which demonstrates that the vegetation of landfills is a significant source of allergenic pollen.

Defect-Tolerant Plasmonic Elliptical Resonators for Long-Range Energy Transfer.

Energy transfer allows energy to be moved from one quantum emitter to another. If this process follows the Förster mechanism, efficient transfer requires the emitters to be extremely close (<10 nm). To increase the transfer range, nanophotonic structures have been explored for photon- or plasmon-mediated energy transfer. Here, we fabricate high-quality silver plasmonic resonators to examine long-distance plasmon-mediated energy transfer. Specifically, we design elliptical resonators that allow energy transfer between the foci, which are separated by up to 10 µm. The geometry of the ellipse guarantees that all plasmons emitted from one focus are collected and channeled through different paths to the other focus. Thus, energy can be transferred even if a micrometer-sized defect obstructs the direct path between the focal points. We characterize the spectral and spatial profiles of the resonator modes and show that these can be used to transfer energy between green- and red-emitting colloidal quantum dots printed with subwavelength accuracy using electrohydrodynamic nanodripping. Rate-equation modeling of the time-resolved fluorescence from the quantum dots further confirms the long-distance energy transfer.

Room-Temperature Strong Coupling of CdSe Nanoplatelets and Plasmonic Hole Arrays.

Exciton polaritons are hybrid light-matter quasiparticles that can serve as coherent light sources. Motivated by applications, room-temperature realization of polaritons requires narrow, excitonic transitions with large transition dipoles. Such transitions must then be strongly coupled to an electromagnetic mode confined in a small volume. While much work has explored polaritons in organic materials, semiconductor nanocrystals present an alternative excitonic system with enhanced photostability and spectral tunability. In particular, quasi-two-dimensional nanocrystals known as nanoplatelets (NPLs) exhibit intense, spectrally narrow excitonic transitions useful for polariton formation. Here, we place CdSe NPLs on silver hole arrays to demonstrate exciton-plasmon polaritons at room temperature. Angle-resolved reflection spectra reveal Rabi splittings up to 149 meV for the polariton states. We observe bright, polarized emission arising from the lowest polariton state. Furthermore, we assess the dependence of the Rabi splitting on the hole-array pitch and the number N of NPLs. While the pitch determines the in-plane momentum for which strong coupling is observed, it does not affect the size of the splitting. The Rabi splitting first increases with NPL film thickness before eventually saturating. Instead of the commonly used [Formula: see text] dependence, we develop an analytical expression that includes the transverse confinement of the plasmon modes to describe the measured Rabi splitting as a function of NPL film thickness.

A One-Step Germole to Silole Transformation and a Stable Isomer of a Disilabenzene.

An unusual germole-to-silole transformation is described. As key intermediates hetero-fulvenes are formed which rearrange to more stable bicyclic carbene analogues. The so-formed germylenes undergo a reductive elimination yielding elemental germanium and siloles. In contrast, the analogous silylenes are stable at ambient conditions and were identified by MS spectrometry and NMR spectroscopy supported by the results of quantum mechanical calculations. These bicyclic silylenes are stable derivatives of the global minimum of the C4 Si2 H6 potential energy surface.