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1.
Polymers (Basel) ; 15(2)2023 Jan 16.
Artículo en Inglés | MEDLINE | ID: mdl-36679352

RESUMEN

The deformations that occur during composite forming processes are governed by the friction between the fabrics and tooling material on the mesoscopic level. The effect of normal load and multi-plies on the frictional behavior of the carbon plain weave is investigated by simulating the friction between the fabric and metal semi-cylinder tool by using the experimental method. The periodic wavy friction-displacement curve between the metal tool and fabric is caused by the interwoven structure of the fabric. Both the increase in the normal load and the number of layers cause an increase in the real contact area during friction, leading to an increase in the friction force. The real contact area is calculated based on the Hertzian contact model and the self-designed testing method. The friction force values obtained from multiplying the real contact area with shear strength are closely aligned with the measured results.

2.
J Chem Phys ; 143(11): 114903, 2015 Sep 21.
Artículo en Inglés | MEDLINE | ID: mdl-26395734

RESUMEN

The present work investigated the influence of organoclay (organo-montmorillonite, OMMT) on the phase separation behavior and morphology evolution of solution polymerized styrene-butadiene rubber (SSBR)/low vinyl content polyisoprene (LPI) blends with rheological methodology. It was found that the incorporation of OMMT not only reduced the droplet size of the dispersion phase, slowed down the phase separation kinetics, also enlarged the processing miscibility window of the blends. The determination on the wetting parameters indicated that due to the oscillatory shear effect, the OMMT sheets might localize at the interface between the two phases and act as compatibilizer or rigid barrier to prevent domain coarsening, resulting in slow phase separation kinetics, small droplet size, and stable morphology. The analysis of rheological data by the Palierne model provided further confirmation that the addition of OMMT can decrease the interfacial tension and restrict the relaxation of melt droplets. Therefore, a vivid "sea-fish-net" model was proposed to describe the effect of OMMT on the phase separation behavior of SSBR/LPI blends, in which the OMMT sheets acted as the barrier (net) to slow down the domain coarsening/coalescence in phase separation process of SSBR/LPI blends.

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