1.
Acta Crystallogr Sect E Struct Rep Online
; 65(Pt 8): m858, 2009 Jul 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21583326
RESUMEN
The asymmetric unit of the title compound, [Cu(C(5)H(3)O(3))(2)(C(12)H(8)N(2))(2)(H(2)O)]·0.5CH(3)OH, contains two Cu(II) complex mol-ecules and one methanol solvent mol-ecule with the metal centres in strongly distorted octahedral coordination. The coordinated water mol-ecule is involved in inter-molecular O-Hâ¯O hydrogen bonding, which links the complex mol-ecules into chains propagating along the c axis. Neighbouring chains inter-act further via π-π inter-actions between the aromatic rings of 1,10-phenanthroline fragments [centroid-centroid distances = 3.726â (4) and 3.750â (4)â Å].