RESUMEN
It is attractive to explore practical approaches to optimize the photodegraded NO property of TiO2. Herein, a typicalZ-shaped heterojunction C-TiO2/rGO composed of carbon-doped TiO2and reductive graphene oxide (rGO) was constructed to optimize the NO removal efficiency through anin situone-pot hydrothermal process with glucose as reductant and dopant. The C-TiO2/rGO (0.11%) composite displays a remarkable NO removal performance of 40.6% under visible light illumination. It was found that the C-TiO2nanoparticles were tightly attached to the rGO sheets and had strong interactions with rGO, which induced a positive impact on not only the light absorption and photo-generated charge separation but also the NO adsorption and reactive oxygen species formation, resulting in boosted photodegrade NO activity. As to the photodegrade NO process over the C-TiO2/rGO, the HOâ¢and O2â¢-were the dominant radicals, of which the O2â¢-radical originated from the interactions between C-TiO2and rGO. We proposed aZ-scheme mechanism to illuminate the advanced photocatalytic activity of C-TiO2/rGO. This work affords an approach to developing effective photocatalysts in the NO purification field.
RESUMEN
Hepatocyte growth factor (HGF) is multifaceted cytokine that regulates proliferation, differentiation, morphology, and motility within numerous stem cells. More recently, HGF has been reported to induce the differentiation of bone mesenchymal stem cells (BMSCs) into mature hepatocytes, but the underlying biochemical and molecular signaling is largely unknown. We isolated BMSC from the bone marrow of rats, which were then cultured and exposed to HGF for 15 days. We subsequently assayed these cells for liver functionality and markers, and blocked NF-кB signaling at various stages of the pathway. The present results demonstrate that HGF induces the differentiation of BMSCs toward hepatocyte-like cells through the NF-кB signaling. More specifically, HGF upregulated the translocation of NF-кB to the nucleus.
