RESUMEN
A new form of pancake bouncing is discovered in this work when a droplet impacts onto micro-structured superhydrophobic surfaces in an environment pressure less than 2 kPa, and an unprecedented reduction of contact time by ≈85% is obtained. The mechanisms of forming this unique phenomenon are examined by combining experimental observation, numeical modelling and an improved theoretical model for the overpressure effect arising from the vaporisation inside micro-scaled structures. The competition among the vapor overpressure effect, the droplet impact force, and the surface adhesion determines if the pancake bouncing behavior could occur. After the lift-off the lamella, the pancake bouncing is initiated and its subsequent dynamics is controlled by the internal momentum transfer. Complementary to the prior studies, this work enriches the knowledge of droplet dynamics in low pressure, which allows new strategies of surface morphology engineering for droplet control, an area of high importance for many engineering applications.
RESUMEN
Solar evaporation of seawater is promising to mitigate the fresh water scarcity problem in a green and sustainable way. However, salt accumulation on the photothermal material prevents the system continuous operation, and the water supply driven by capillary force severely limits the scale-up of the evaporators. Here, we demonstrate a double-sided suspending evaporator with top water supply and a surface water distributor for high-efficient concurrent solar evaporation and salt harvesting for large area applications. Both sides of the evaporator can evaporate water with automatic salt harvesting from the edge concurrently. Top water supply gets away from the limitation of capillary force for a larger area application and completely cuts off the heat leak to the bulk water below for higher efficiency. The energy conversion efficiency reaches 95.7% at 1.40 kg·m-2·h-1 with deionized water under 1 sun with a remarkable low surface average temperature (28.2 °C). Based on the simulation and experiment, a novel radial arterial water distribution system is developed to efficiently distribute water on a larger evaporation surface. The water distribution system alters the water transport path in the evaporation surface, leading to salt accumulation on the surface body, where salt is unable to be harvested by gravity automatically. This problem is further resolved by cutting out the salt accumulation area (16.4%) on the surface to create a floriform evaporator, which forcedly exposes the salt at the edge for harvesting. Up to70 h continuous solar evaporation from salt water at a rate of 1.04 kg·m-2·h-1 with concurrent salt collection on this floriform evaporator is achieved. This work resolves water supply and salt accumulation problems in scaling up the solar evaporators and advances the structural design of evaporators for high-efficient large area applications.
RESUMEN
Hydrolysed polyacrylamide (HPAM) is widely used in many industrial fields where its rheological properties play a leading role. Recent discovery of the reduction of HPAM's viscosity by adding carbon quantum dots (CQDs), however, is controversial to the established theories. By using all atom molecular dynamics simulation with an OPLS-AA force field, this study aims to provide detailed molecular insight into such an uncommon phenomenon. The dynamic structures of the HPAM chain in the presence or absence of CQDs were clearly captured from the molecular aspect. The results reveal that the adsorption of CQD reduces the gyration radius of the HPAM chain, and it is the corresponding hydration effect that leads to the reduction of the viscosity. The amide rather than the carboxylate group along the HPAM chain is dominant in terms of the interaction with the CQDs, and the driven atoms depend on the surface where the polymer is adsorbed.
