Recyclable Fe/S co-doped nanocarbon derived from metal-organic framework as a peroxymonosulfate activator for efficient removal of 2,4-dichlorophenol.

In this study, a recyclable Fe/S co-doped nanocarbon (Fe/S-NC) was successfully prepared by the pyrolysis of ZIF-8 confined with Fe(II) and added S. Characterization showed that a highly graphitized carbon-based material co-doped with sulfur and iron was successfully prepared. This Fe/S-NC can efficiently activate PMS to remove organic pollutants in water. The effect of different synthesis conditions on the degradation efficiency of 2,4-DCP was studied by orthogonal experiments. The optimized Fe/S-NC/PMS system exhibited excellent catalytic performance and could degrade more than 99.7% of 2,4-DCP within 30 min. Even after 5 cycles, the degradation efficiency could still be maintained above 96.3%, which proved that the catalytic system had good cycle performance. In addition, the effect of pH on catalytic performance showed that the degradation rate of 2,4-DCP exceeds 96.7% in the pH range of groundwater (pH = 5-9). We had confirmed that the free radicals that caused 2,4-DCP degradation were SO4·-, ·OH, O2·-, and 1O2, which played important roles in degrading organic pollutants. These research results show that the Fe/S-NC/PMS system can be used as an efficient, stable, and environmentally friendly system to treat organic pollutants in groundwater.

The performance and pathway of benzothiazole degradation by electron beam irradiation.

Benzothiazole (BTH) is a typical refractory heterocyclic compound that can be used as a photosensitive material in organic synthesis and conditional plant resource research. The extensive use of BTH has led to high BTH concentrations in natural environment, such as in tap water and urine, which tend to inhibit animal hormone synthesis and induce genotoxicity. Traditional wastewater treatment processes cannot effectively remove BTH. Therefore, we aimed to use the electron beam method, an emerging method for pollutant degradation, to degrade BTH in water. Experiments showed that BTH can be effectively degraded (up to 90%) when the electron beam reaches 5 kGy and irradiation conformed perfectly to the pseudo first-order kinetics model. Experimental results showed that acidic conditions are more favorable for electron beam degradation of BTH, while the degradation of most other inorganic ions is inhibited (except SO42-). Hydroxyl radicals (•OH) was confirmed to play a major role in degradation by the experiment, and the mineralization rate was greatly increased by the addition of H2O2 and K2S2O8. In addition, our experimental and theoretical calculations showed that the degradation of BTH occurred mainly through the opening of the benzene ring. Theoretical calculations showed that the toxicity of BTH decreased significantly after electron beam degradation, making it an effective way to degrade BTH.

Degradation of anticorrosive agent benzotriazole by electron beam irradiation: Mechanisms, degradation pathway and toxicological analysis.

Benzotriazole (BTA), which is extensively served as household and engineering agent, is one of the emerging and persistent contaminants. Despite the spirit to remove BTA is willing, the traditional wastewater treatments are weak. Therefore, the degradation of BTA via electron beam was systematically explored in this study. It turned out that after 5.0 kGy irradiation, even 87.5 mg L-1 BTA could be completely removed, and the irradiation conformed perfectly to the pseudo first-order kinetics model. The effects of solution pH, inorganic anions (CO32-, HCO3-, NO3-, NO2-, SO42-, SO32-, Cl-), and gas atmosphere were all explored. And results indicated that oxidative hydroxyl radicals played critical role in BTA irradiation. Additionally, presence of H2O2 and K2S2O8 promoted significantly not only degradation extent but also mineralization efficiency of BTA due to they both augmented the generation of oxidative free radicals. Moreover, by combining theoretical calculations with experimental results, it could be inferred that degradation of BTA was mainly carried out by the benzene ring-opening. Further toxicity evaluation proved that as irradiation proceeded, the toxicity alleviated. Taken together, there were various indications that BTA could be effectively eliminated by electron beam irradiation in aquatic environments.