Surface modification of gold by carbazole dendrimers for improved carbon dioxide electroreduction.

Four types of carbazole dendrimers were applied as modification molecules of Au surfaces to improve carbon dioxide electroreduction. The reduction properties depended on the molecular structures: the highest activity and selectivity to CO was achieved by 9-phenylcarbazole, probably caused by the charge transfer from the molecule to Au.

Multifunctional terahertz microscopy for biochemical and chemical imaging and sensing.

Laser-excited terahertz emission microscopy (LTEM) has exhibited great potential for studying the dynamic physical properties of various materials and device evaluation. In this study, an up-to-date version of LTEM, the terahertz chemical microscopy, was developed for biochemical and chemical imaging and sensing. By functionalizing a terahertz semiconductor emitter with an ion-sensitive membrane, a DNA aptamer, and a specific polymer, the change in the terahertz signal amplitude attributed to the surface electrical potential change was successfully detected. Accordingly, the measurement of calcium ions (Ca2+), stress biomarker cortisol, and 2, 4, 6-trinitrotoluene (TNT) explosive was achieved. Measured of charged Ca2+ was via the change in the electrical potential of the ion-sensitive membrane with ion accumulation. For non-charged cortisol and TNT measurements, the surface potential change was recorded by the conformational change of the negatively charged DNA aptamer bound to cortisol and the charge-transfer complex formation between TNT and polyethylenimine polymer, respectively. Moreover, the specificity of this sensing approach was demonstrated by molecular docking and measuring the interfering substances such as sodium ions, potassium ions, brain chemicals histamine and dopamine, and TNT analogues. The results showed that the developed multifunctional terahertz microscopy technique can be used for trace biochemical and chemical sensing via visualization of the terahertz amplitude distribution.

The impact of nuclear shape on the emergence of the neutron dripline.

Atomic nuclei are composed of a certain number of protons Z and neutrons N. A natural question is how large Z and N can be. The study of superheavy elements explores the large Z limit1,2, and we are still looking for a comprehensive theoretical explanation of the largest possible N for a given Z-the existence limit for the neutron-rich isotopes of a given atomic species, known as the neutron dripline3. The neutron dripline of oxygen (Z = 8) can be understood theoretically as the result of single nucleons filling single-particle orbits confined by a mean potential, and experiments confirm this interpretation. However, recent experiments on heavier elements are at odds with this description. Here we show that the neutron dripline from fluorine (Z = 9) to magnesium (Z = 12) can be predicted using a mechanism that goes beyond the single-particle picture: as the number of neutrons increases, the nuclear shape assumes an increasingly ellipsoidal deformation, leading to a higher binding energy. The saturation of this effect (when the nucleus cannot be further deformed) yields the neutron dripline: beyond this maximum N, the isotope is unbound and further neutrons 'drip' out when added. Our calculations are based on a recently developed effective nucleon-nucleon interaction4, for which large-scale eigenvalue problems are solved using configuration-interaction simulations. The results obtained show good agreement with experiments, even for excitation energies of low-lying states, up to the nucleus of magnesium-40 (which has 28 neutrons). The proposed mechanism for the formation of the neutron dripline has the potential to stimulate further thinking in the field towards explaining nucleosynthesis with neutron-rich nuclei.