In situ surface turbidity sensor based on localized light scattering from tilted fiber Bragg gratings.

We propose a compact fiber-optic sensor for in situ and continuous turbidity monitoring, based on surface optical scattering of polarized evanescent waves from targeted particles. The sensor is composed of a tilted fiber Bragg grating (TFBG) packaged inside a microfluidic capillary. The transmission spectrum of the TFBG provides a fine comb of narrow cladding resonances that are highly sensitive to the turbidity due to the localized light scattering of polarized evanescent waves from the microparticles near the fiber surface (as opposed to traditional bulk/volumetric turbidity measurement). We also propose a transmission spectral area interrogation method and quantify the repeatable correlation between the surface turbidity and the optical spectral area response. We show that the maximum sensitive turbidity response is achieved when the wavelength of the sensing cladding resonance matches the size of surrounding solid particles.

Full-spectrum nonmetallic plasmonic carriers for efficient isopropanol dehydration.

Plasmonic hot carriers have the advantage of focusing, amplifying, and manipulating optical signals via electron oscillations which offers a feasible pathway to influence catalytic reactions. However, the contribution of nonmetallic hot carriers and thermal effects on the overall reactions are still unclear, and developing methods to enhance the efficiency of the catalysis is critical. Herein, we proposed a new strategy for flexibly modulating the hot electrons using a nonmetallic plasmonic heterostructure (named W18O49-nanowires/reduced-graphene-oxides) for isopropanol dehydration where the reaction rate was 180-fold greater than the corresponding thermocatalytic pathway. The key detail to this strategy lies in the synergetic utilization of ultraviolet light and visible-near-infrared light to enhance the hot electron generation and promote electron transfer for C-O bond cleavage during isopropanol dehydration reaction. This, in turn, results in a reduced reaction activation barrier down to 0.37 eV (compared to 1.0 eV of thermocatalysis) and a significantly improved conversion efficiency of 100% propylene from isopropanol. This work provides an additional strategy to modulate hot carrier of plasmonic semiconductors and helps guide the design of better catalytic materials and chemistries.

Operando optical fiber monitoring of nanoscale and fast temperature changes during photo-electrocatalytic reactions.

In situ and continuous monitoring of thermal effects is essential for understanding photo-induced catalytic processes at catalyst's surfaces. However, existing techniques are largely unable to capture the rapidly changing temperatures occurring in sub-µm layers at liquid-solid interfaces exposed to light. To address this, a sensing system based on a gold-coated conventional single-mode optical fiber with a tilted fiber Bragg grating inscribed in the fiber core is proposed and demonstrated. The spectral transmission from these devices is made up of a dense comb of narrowband resonances that can differentiate between localized temperatures rapid changes at the catalyst's surface and those of the environment. By using the gold coating of the fiber as an electrode in an electrochemical reactor and exposing it to light, thermal effects in photo-induced catalysis at the interface can be decoded with a temperature resolution of 0.1 °C and a temporal resolution of 0.1 sec, without perturbing the catalytic operation that is measured simultaneously. As a demonstration, stable and reproducible correlations between the light-to-heat conversion and catalytic activities over time were measured for two different catalysis processes (linear and nonlinear). These kinds of sensing applications are ideally suited to the fundamental qualities of optical fiber sensors, such as their compact size, flexible shape, and remote measurement capability, thereby opening the way for various thermal monitoring in hard-to-reach spaces and rapid catalytic reaction processes.

Plasmon-exciton coupling dynamics and plasmonic lasing in a core-shell nanocavity.

Plasmonic nanolasers based on the spatial localization of surface plasmons (SPs) have attracted considerable interest in nanophotonics, particularly in the desired application of optoelectronic and photonic integration, even breaking the diffraction limit. Effectively confining the mode field is still a basic, critical and challenging approach to improve optical gain and reduce loss for achieving high performance of a nanolaser. Here, we designed and fabricated a semiconductor/metal (ZnO/Al) core-shell nanocavity without an insulator spacer by simple magnetron sputtering. Both theoretical and experimental investigations presented plasmonic lasing behavior and SP-exciton coupling dynamics. The simulation demonstrated the three-dimensional optical confinement of the light field in the core-shell nanocavity, while the experiments revealed a lower threshold of the optimized ZnO/Al core-shell nanolaser than the same-sized ZnO photonic nanolaser. More importantly, the blue shift of the lasing mode demonstrated the SP-exciton coupling in the ZnO/Al core-shell nanolaser, which was also confirmed by low-temperature photoluminescence (PL) spectra. The analysis of the Purcell factor and PL decay time revealed that SP-exciton coupling accelerated the exciton recombination rate and enhanced the conversion of spontaneous radiation into stimulated radiation. The results indicate an approach to design a real nanolaser for promising applications.

Three-Dimensional Core-Shell Nanorod Arrays for Efficient Visible-Light Photocatalytic H2 Production.

Constructing heterostructured nanomaterials with integrating different functional materials into well-oriented nanoarchitectures is an efficacious tactic to obtain high-performance photocatalysts. In this paper, we fabricated three-dimensional ZnO-WS2@CdS core-shell nanorod arrays as visible-light-driven photocatalysts for efficient photocatalytic H2 production. This unique core-shell heterostructure extends visible-light absorption and provides more active sites. More importantly, the ZnO-WS2@CdS nanorod arrays build a beneficial energy level configuration and spatial structure to accelerate the generation, separation, and transfer of the photogenerated electron-hole. On the basis of the synergistic effects, the photocatalytic H2 rate of optimized ZnO-WS2@CdS nanorod arrays achieves 15.12 mmol h-1 g-1 in visible light irradiation, which is 39, 9, and 8 times higher than pure CdS, ZnO-CdS, and CdS-WS2 photocatalysts. The apparent quantum yield is up to 14.92% at 420 nm. Moreover, the core-shell heterostructure photocatalyst can recycle and maintain stability.

Interface control for pure ultraviolet electroluminescence from nano-ZnO-based heterojunction devices.

Realization of pure and stable ultraviolet electroluminescence (UV EL) of ZnO light-emitting diode (LED) is still a challenging issue, due to complicated defects of intrinsic ZnO and the corresponding device interfaces. In this paper, we demonstrated a simple & feasible method to fabricate n-ZnO/AlN/p-GaN heterojunctions light-emitting devices. First, the vertically aligned ZnO nanorods (NRs) have been prepared as high quality active layer, and the nanostructured heterojunction LED arrays were constructed by directly bonding ZnO NRs onto AlN-coated p-GaN wafer. By optimizing the AlN layer thickness to be 20 nm, a strong and pure ultraviolet emission located at 387 nm can be observed. The energy band alignment of n-ZnO/AlN (20 nm)/p-GaN heterojunction LED has been studied by using X-ray photoelectron spectroscopy (XPS), the valence band offset between AlN and GaN was calculated to be 0.34 eV. On the other side, the conduction band offset (as large as 3.28 eV) between AlN and ZnO can block the flow of electrons from ZnO to p-GaN. Thus, electron-hole recombination takes place in the ZnO layer, and a pure UV EL could be observed. Our results provide a significant approach toward future of pure ultraviolet optoelectronic LEDs.