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1.
Water Sci Technol ; 88(10): 2566-2580, 2023 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-38017678

RESUMEN

In recent years, chemical water treatment equipment has gained significant attention due to its environmental-friendly features, multifunctionality, and broad applicability. Recognizing the limitations of existing chemical treatment equipment, such as challenges in scale removal and the high water content in scale deposits, we propose a novel drum design for both anode and cathode, enabling simultaneous scale suction and dehydration. We constructed a small experimental platform to validate the equipment's performance based on our model. Notably, under the optimal operating parameters, the hardness removal rate for circulating water falls within the range of 19.6-24.46%. Moreover, the scale accumulation rate per unit area and unit time reaches 13.7 g h-1 m-2. Additionally, the energy consumption per unit weight of the scale remains impressively low at 0.16 kWh g-1. Furthermore, the chemical oxygen demand (COD) concentration decreased from an initial 106.0 mg L-1 to a mere 18.8 mg L-1, resulting in a remarkable total removal rate of 82.26%. In conclusion, our innovative electrochemical water treatment equipment demonstrates exceptional performance in scale removal, organic matter degradation, and water resource conservation, offering valuable insights for future research and development in chemical treatment equipment and electrochemical theory.


Asunto(s)
Contaminantes Químicos del Agua , Purificación del Agua , Eliminación de Residuos Líquidos/métodos , Contaminantes Químicos del Agua/química , Oxidación-Reducción , Purificación del Agua/métodos , Electrodos
2.
Materials (Basel) ; 16(14)2023 Jul 20.
Artículo en Inglés | MEDLINE | ID: mdl-37512400

RESUMEN

Intense research efforts are focused on the development of advanced high-entropy alloys intended for premium aerospace components and other applications, where high strength and good formability are crucial. The mechanical properties of these alloys are closely related to the phase transformation, dislocation evolution, and grain size, and these factors are affected by the deformation temperature. The response of the retained austenite to strain-induced martensitic transformation at various temperatures was studied in an advanced Ti68Nb7Ta3Zr4Mo18 (at.%) high-entropy alloy via molecular dynamics simulation. It was found that the Ti68Nb7Ta3Zr4Mo18 alloy changes from a single crystal to a polycrystal during the tensile process, and the transition of the Ti68Nb7Ta3Zr4Mo18 (at.%) high-entropy alloy from the BCC phase to the FCC phase occurs. At high temperatures and low strain rates, grain boundary slip is the main deformation mechanism, and at low temperatures and high strain rates, dislocation slip replaces grain boundary slip as the dominant deformation mechanism, which improves the strength of the alloy. Moreover, when the grain size is too small, the strength of the alloy decreases, which does not satisfy the fine grain strengthening theory and shows an inverse Hall-Petch relationship. This study offers a new compositional window for the additive manufactured lightweight high-strength material categories for various applications including the aerospace industry.

3.
Sensors (Basel) ; 23(1)2023 Jan 02.
Artículo en Inglés | MEDLINE | ID: mdl-36617088

RESUMEN

In the working process of the gas bearings, the unbalanced force of the rotor will increase nonlinearly with the increase in the rotating speed, resulting in an increase in the rotor's vibration amplitude. On the other hand, with the increase in the rotating speed, the hydrodynamic effect will increase, and the nonlinear increase in the gas film force and stiffness will inhibit the increase in the vibration amplitude. In order to deeply study the influence of the unbalanced force and nonlinear gas film force on the vibration amplitude of the ultra-precision aerostatic motorized spindle, taking the double slit throttling gas bearing as an example, according to the equilibrium equation of the rotor under the combined action of gravity, the gas film force, and the unbalanced force, a calculation program based on the finite difference method for solving the rotor's equilibrium position is completed. The calculation results show that: the hydrodynamic effect can significantly increase the bearing capacity and cause the change of the static equilibrium position of the rotor, but the offset amplitude of the static equilibrium position of the rotor gradually slows down with the increase in the rotating speed. The hydrodynamic effect improves the stiffness near the static equilibrium position of the rotor, making the rotor vibration track tend to be more "round". Although the unbalanced force of the rotor increases nonlinearly as the rotating speed increases, the maximum offset between the dynamic equilibrium position and the static equilibrium position of the rotor under the action of the rotating unbalanced force is approximately linear with the rotating speed. Compared with the air supply pressure, the rotor unbalance and rotating speed are the main factors affecting the rotor dynamic equilibrium position offset. This study has a reference role in the in-depth study of the influence of rotating speed and rotor unbalance on the rotor static equilibrium position and dynamic equilibrium position offset, as well as in the design of gas bearings and the prediction of rotor vibration amplitude.

4.
Artículo en Inglés | MEDLINE | ID: mdl-36554838

RESUMEN

The high porosity of medium-coarse sand (MCS) layers in groundwater recharge areas presents a high environmental risk. Sulfamethoxazole (SMX) and trimethoprim (TMP) are two common sulfonamide antibiotics in surface water that have a high propensity to migrate into groundwater. In this study, four biochars were prepared and biochar-amended soil aquifer treatment (SAT) columns were constructed to remove SMX and TMP. Batch experiments demonstrated that the sorption isotherms conformed to the Freundlich model. The maximum adsorptions of biochars prepared at 700 °C were 54.73 and 67.62 mg/g for SMX and 59.3 and 73.38 mg/g for TMP. Electrostatic interaction may be one of the primary mechanisms of adsorption. The column experiments showed that the SMX and TMP removal rate of the biochar-amended SAT was as high as 96%, while that of the MCS SAT was less than 5%. The addition of biochar greatly improved the retention capacity of the pollutants in the MCS layer in the groundwater recharge area and effectively reduced environmental risk.


Asunto(s)
Antibacterianos , Agua Subterránea , Arena , Ríos , Carbón Orgánico , Sulfametoxazol , Sulfanilamida , Sulfonamidas , Suelo , Adsorción
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