Uptake of zinc from the soil to the wheat grain: Nonlinear process prediction based on artificial neural network and geochemical data.

Trace elements in plants primarily derive from soils, subsequently influencing human health through the food chain. Therefore, it is essential to understand the relationship of trace elements between plants and soils. Since trace elements from soils absorbed by plants is a nonlinear process, traditional multiple linear regression (MLR) models failed to provide accurate predictions. Zinc (Zn) was chosen as the objective element in this case. Using soil geochemical data, artificial neural networks (ANN) were utilized to develop predictive models that accurately estimated Zn content within wheat grains. A total of 4036 topsoil samples and 73 paired rhizosphere soil-wheat samples were collected for the simulation study. Through Pearson correlation analysis, the total content of elements (TCEs) of Fe, Mn, Zn, and P, as well as the available content of elements (ACEs) of B, Mo, N, and Fe, were significantly correlated with the Zn bioaccumulation factor (BAF). Upon comparison, ANN models outperformed MLR models in terms of prediction accuracy. Notably, the predictive performance using ACEs as input factors was better than that using TCEs. To improve the accuracy, a two-step model was established through multiple testing. Firstly, ACEs in the soil were predicted using TCEs and properties of the rhizosphere soil as input factors. Secondly, the Zn BAF in grains was predicted using ACE as input factors. Consequently, the content of Zn in wheat grains corresponding to 4036 topsoil samples was predicted. Results showed that 85.69 % of the land was suitable for cultivating Zn-rich wheat. This finding offers a more accurate method to predict the uptake of trace elements from soils to grains, which helps to warn about abnormal levels in grains and prevent potential health risks.

Assessing the impact of mining on cyclic and linear methylsiloxane distribution in Tibetan soils: Source contribution and transport pattern.

The pervasive presence of methylsiloxanes (MSs), comprising linear and cyclic congeners, in the environment poses significant ecological risks, yet the understanding of their transport mechanisms and deposition patterns remains limited. This study analyzed the concentrations of 12 linear-MSs (L3-L14) and 7 cyclic-MSs (D3-D9) in 29 surface soil samples collected across varying altitudes (3726 to 4863 m) near the Jiama mining sector in Tibet, aiming to investigate the distribution and transport dynamics of MSs from the emission source. The distribution of total MS concentration (ranging from 50.1 to 593 ng/g) showed a remarkable correlation with proximity to the mining site, suggesting the emergent source of mining activities for the MSs in the remote environment of the Tibetan Plateau. Employing the innovative model of robust absolute principal component scores-robust geographically weighted regression (RAPCS-RGWR), the analysis predicted that the mining operations contributing 57.1 % of the total soil MSs, would significantly surpass contributions from traffic emissions (14.7 %), residential activities (13.2 %), and the environmental factor of total organic matter content (14.9 %). The Boltzmann equation effectively modeled the distribution pattern of soil MSs, highlighting atmospheric transport and gravitational settling as key distribution mechanisms. However, linear-MSs exhibited longer transport distances than cyclic-MSs and were more profoundly affected by prevailing wind directions, suggesting their differential environmental behaviors and risks. Our study underscored that the mining sector possibly emerged as a significant source of Tibetan MSs, and provided insights into the transport and fate of MSs in remote, high-altitude environments. The findings emphasize the need for targeted pollution control strategies to mitigate the environmental footprint of mining activities in Tibet and similar regions.

Aged polycyclic aromatic hydrocarbons as stratigraphic marker in the Anthropocene: Evidence from Tibetan Lake sediments.

Polycyclic aromatic hydrocarbons (PAHs) were supposed to serve as combustion marker reflecting the past energy use, but it was unclear whether their sediment records in the Anthropocene were "weathered" due to aging-induced formation of bound residues. In this study, the total concentration of PAHs (the sum of rapid desorption, slow desorption, and bound residue fractions) were determined in four dated sediment cores from eastern to central Tibet using multi-step sequential extraction method. The total 16 PAH concentrations were 11.8, 13.5, 18.9, and 29.4 ng/g dw (in average) in the Co Ngoin, Pung Co, Ahung Co, and Putok lakes, respectively. The stratigraphic records and estimated source contributions of PAHs in different areas of Tibet exhibited a coherent change in the mid-20th century in response to the Holocene-Anthropocene transition. The sediment PAHs also displayed a comparable pattern when the bound residue fraction was not accounted for, suggesting their effective retainability under natural aging conditions. This may be elucidated by the enduring forward and back conversions between slow desorption and bound residue fractions, which manifested similar time-dependent variations across PAH congeners. The distinct conversion tendencies of different congeners were predicted by the binding affinity of congeners to surface/inner regions of organic matter using molecular docking simulations. Our findings demonstrate the persistence of sediment PAH records under natural aging and validate the use of PAH documentary evidence for investigating the Anthropocene.

Primary emissions or environmental persistence contribute to the present DDTs: Evidence from sediment records in Tibetan lakes.

Dichlorodiphenyltrichloroethane (DDT) compounds are still circulating the global environment even though the technical DDT has been restricted in agriculture since the last century. The persistent presence of DDTs worldwide remains uncertain, as it is unclear whether their existence is primarily due to ongoing use or the prolonged persistence in soils and sediments that result in continuous reemission into the atmosphere. The present study applied a sequential extraction procedure to determine the DDT concentrations in rapid desorption, slow desorption, and bound residue fractions in the dated sediment cores from distinct regions of Tibet. The temporal variation of total DDTs (sum of three fractions) in sediments from southern and eastern Tibet respectively revealed the different DDT usage histories in India and China mainland. Nevertheless, the current application volumes of DDT-containing products in these regions were found to decrease significantly. The reversible transformations among three fractions of DDTs with aging time was observed along sediment profile, including the back conversion from bound residue. This process may be the key driver to prolong the half-life of sediment p,p'-DDT, resulting in the persistence of secondary sources of this persistent organic pollutant in the global environment for a longer duration than previously expected.

Aging affects isomer-specific occurrence of dechlorane plus in soil profiles: A case study in a geographically isolated landfill from the Tibetan Plateau.

Two major structural isomers in commercial dechlorane plus (DP) mixtures, anti-DP and syn-DP, generally displayed varied desorption and partitioning efficiencies in soils, which may be linked to their different aging rates. However, the molecular parameters that govern the degree of aging and its associated effects on the occurrence of DP isomers have not been comprehensively investigated. In this study, the relative abundance of rapid desorption concentration (Rrapid) was measured for anti-DP, syn-DP, anti-Cl11-DP, anti-Cl10-DP, Dechlorane-604 (Dec-604), and Dechlorane-602 (Dec-602) at a geographically isolated landfill area in the Tibetan Plateau. The Rrapid values were used as an indicator of aging degree, exhibiting a close correlation with the three-dimension conformation of the molecules for the dechlorane series compounds. This observation suggested that planar molecules may have a greater tendency to accumulate in the condensed phase of organic matter and undergo more rapid aging. The fractional abundances and dechlorinated products of anti-DP were found to be predominantly controlled by the aging degree of DP isomers. The multiple nonlinear regression model indicated that differences in aging between anti-CP and syn-DP were primarily driven by the total desorption concentration and soil organic matter content. Aging plays a significant role in both the transport processes and metabolism of DP isomers and should be taken into account to refine the assessment of their environmental behaviors.

Spatial distribution and quantitative source identification of nutrients and beneficial elements in the soil of a typical suburban area, Beijing.

Source identification and quality monitoring of soil nutrients and beneficial elements (NBEs) are crucial for agricultural production and environmental protection. In this study, grid sampling (223 topsoil samples and 223 subsoil samples) was carried out in the Tongzhou District of Beijing. The concentration level of representative NBEs (N, P, K, Ca, Mg, Se, V, Ge, Mn, Zn) and some typical soil properties representing indicators (total organic carbon, TFe2O3, Al2O3/SiO2, and pH) in soils and their spatial distribution were analyzed. The major sources contributing to these NBEs were assessed by principal component analysis (PCA), redundancy analysis (RDA), and positive matrix factorization (PMF) analysis. The results suggested that the soil parent material contributed 40.09-69.84% to Zn, V, Ge, Mn, F, and K in soils; the local external source contributed 54.89-75.04% to N, Se, and TOC; and the hydrous system contributed 40.67-77.31% to Ca and Mg. The enrichment degree of each NBE was calculated using the standardized concentration ratio method. These indices exhibited the influence and mixing process of different sources on the target NBEs in topsoils. The individual concentrations of the target NBEs and the combined concentrations of N, P, and K were used to evaluate the soil quality. Our study estimated the relative contributions from dominant sources to NBEs in soils from a typical suburban area, providing a basis for agricultural activities and environmental protection.

Release of phthalate esters from a local landfill in the Tibetan Plateau: Importance of soil particle-size specific association.

High loads of phthalate esters (PAEs) in background regions can be directly attributed to the local sources, and their association with soil particles may determine the environment behaviors. However, little is known about the particle-size specific distributions of PAEs in soils from point source to the surroundings. In this study, 12 PAE congeners were measured in clay (< 2 µm), silt (2-63 µm) and sand fractions (63-250 µm) from surficial soils and soil profiles (0-200 cm) around the Lhasa landfill. The total concentrations of PAEs in bulk soils varied from 0.44 to 22.3 µg/g, with a dominance of bis(2-ethylhexyl) phthalate (DEHP). The clay-sorbed PAEs exhibited a decreasing trend with the increasing distance from landfill. This distribution pattern was well described by the Gaussian air pollution model, suggesting the airborne particles/gaseous transport of clay-sorbed PAEs. The Boltzmann equation explained the spatial variation of silt-sorbed PAEs, reflecting the atmospheric dispersion of silt-sorbed PAEs. In comparison, the sand-sorbed PAEs in surrounding soils showed downslope accumulation possibly due to the aeolian transport of sand particles. Half-life of the most abundant PAE congener DEHP was assumed based on the soil inventories from observed concentration and the Level III fugacity model simulations, and the results indicated significant longer half-life of DEHP in deeper soils (~24,000 h) than in surficial soils (5500 h). This study elucidates that the distribution and fate of soil PAEs would depend on their association with particles in the source area, and the relative stability of DEHP in deeper soils would further increase PAE inventory in soil compartment.

Polycyclic aromatic hydrocarbons in sedimentary cores of Tibetan Plateau: Influence of global warming on cold trapping.

Cold condensation is an important pathway for polycyclic aromatic hydrocarbons (PAHs) depositing at remote alpine lakes after long-range atmospheric transportation. However, in the context of global warming, the obvious temperature rise in the Tibetan Plateau (TP) might have an impact on the air deposition of PAHs by controlling the extent of cold condensation. To investigate the influence of rising temperatures on the atmospheric deposition of PAHs, two dated sedimentary cores from Pumoyum Co Lake (PC) and Selin Co Lake (SC) were collected, respectively and concentrations of 16 individual PAHs were measured. In both PC and SC, the total concentration of 16 PAHs presented relatively lower levels in four historical periods of "hot anomaly" including 1973-1975, 1988-1989, 1998-1999, and 2006-2007. This indicated that the hot temperatures might restrict the atmospheric deposition of PAHs. Besides, the results of the principal component analysis did discriminate those "hot anomalies". As the temperature kept increasing in TP, for low molecular weight PAHs and high molecular weight PAHs, the influence of rising temperatures on the cold condensation was different. Therefore, it was identified that the effect of global warming on the environmental fate of POPs cannot be neglected, especially in alpine regions like TP.

Short-chain chlorinated paraffins in soils indicate landfills as local sources in the Tibetan Plateau.

Background contamination levels of contemporary persistent organic pollutants (POPs) may be elevated due to local discharges, and hence it is of high importance to assess and monitor them in alpine and Polar Regions. This study investigated the role of waste disposal in the Tibetan plateau as the local source of short-chain chlorinated paraffins (SCCPs). SCCPs were determined in soils from the urban landfill and rural dumpsites, with a concentration range of 56.8-1348 ng/g dw. The gradient descent of SCCP levels from Lhasa landfill to the surrounding soils with increasing distances suggested a significant SCCP release from waste disposal. The transport pattern was well fitted by the Boltzmann equation after normalization in terms of soil organic carbon contents. Compared to the landfill cells closed in early years, the recently closed cells contained higher concentrations but lower proportions of the short-chain congener groups, likely reflecting the SCCP use history in Tibet. In open-burning dumpsites, higher SCCP levels and dominance of lighter congener groups indicates that such crude waste treatment process might cause an extra release of volatile SCCPs. This study elucidates local SCCP inputs to the background environment, and demonstrates that both urbanization and badly-managed landfill have been contributing to the presence of contemporary POPs in the Tibetan Plateau.

Unraveling the behaviors and significances of waste biomass ashes as underlying emission sources of soil polycyclic aromatic hydrocarbons in Tibetan Plateau.

Domestic consumption of biomass fuels has been found as a leading source of polycyclic aromatic hydrocarbons (PAHs) in pristine regions. The biomass ashes would serve as both source and vector for PAHs, which may threaten residents' health. However, research focusing on the behaviors of waste biomass ashes acting as emission resources of PAHs is still lacking. In present study, occurrence and fate of PAHs released from disposal biomass ashes in the Tibetan Plateau were investigated by evaluating their patterns and levels in soils at different distances from the Lhasa landfill. Concentrations of 16 PAHs averaged at 1009 ng/g dry weight and 103 ng/g dry weight in landfill cover soils and surrounding soils, respectively. The spatial distributions of PAHs evidenced the local source of biomass ashes in landfill, while the fractionations of PAHs in soils profiles emphasized the post-deposal leaching. Since PAH compositions altered significantly during their transport and sequestration, the rectification factors were suggested to adjust the source diagnostic ratios. In study area, the emission flux of PAHs from waste biomass ashes to soils was 0.93 ton/year; extended to the Tibetan Plateau, the flux was estimated to be 13.1-32.5 ton/year. This study confirmed that waste biomass ashes would represent significant contributions of PAH emissions in this pristine region, which might remarkably exacerbate the total emissions of PAHs in Tibet by more than 25%.

The sedimentary record of polycyclic aromatic hydrocarbons in Yamzho Yumco Lake: evolution of local sources and adsorption dynamic in the Tibetan Plateau.

With the rapid increase in anthropogenic activities, the local emissions of polycyclic aromatic hydrocarbons (PAHs) in background regions, such as the Tibetan Plateau (TP), have attracted great attention. The deposition of PAHs in lake sediments provides a historical evolutionary record of such compounds in these regions. To investigate the evolution of PAHs in the TP, two sedimentary cores from Yamzho Yumco Lake were collected and dated at high resolution, and the concentrations of 16 PAHs and sediment properties were also analyzed. The total concentrations of the 16 PAHs ranged from 6.52 to 57.97 ng/g (dry weight) in YC1 and from 0.91 to 4.57 ng/g (dry weight) in YC2. According to the methods of principal component analysis (PCA) followed by multilinear regression analysis (MLRA), four sources of PAHs in the sediments were qualitatively and quantitatively identified, such as petroleum combustion, petrogenic, coal combustion, and biomass burning. Thus, the historical evolution of PAHs was summarized. In addition, the transported distance from local PAH emission sources was found to greatly affect the composition and concentration of PAHs in sites YC1 and YC2. Specifically, local sources contributed a greater proportion of heavy molecular weight (HMW) PAHs in YC1 and a higher proportion of light-molecular-weight (LMW) PAHs in YC2. Moreover, fine particles (size < 20 µm) were found to play a significant role in adsorbing PAHs in sediments. Furthermore, ∑16PAHs in sediments were linearly correlated with the percentage of fine particles (size < 20 µm). This study provides a first example to investigate the historical evolution of PAH local emission in background regions by using lake sedimentary records, especially in the TP. Specifically, different local sources were identified using the methods of PCA followed by MLRA, and PAHs in TP sediments were predominantly adsorbed by fine particles rather than by total organic carbon (TOC) because the amount of TOC was limited.

Insight into the local source of polybrominated diphenyl ethers in the developing Tibetan Plateau: The composition and transport around the Lhasa landfill.

In the background region of the Tibetan Plateau (TP), the rapid urbanization probably results in the massive generation of persistent organic pollutants (POPs), which lacks monitoring and evaluation. Since landfill could serve as an important sink of the locally used POPs, the analysis of POPs in the Tibetan landfill area might help us to understand the source composition and their transport in the TP. In this study, the concentration variations of polybrominated diphenyl ethers (PBDEs) in five soil profiles and seven surficial sediments around the largest Tibetan landfill were investigated. The total concentrations of PBDEs ranged from 128 to 1219 ng/kg in soils, and from 447 to 7295 ng/kg in sediments. The dominance of nona- and deca-BDEs possibly indicated the wide usage of deca-BDE as flame retardant in the TP. The vertical and spatial distribution patterns of PBDEs within soils plausibly revealed their main transport pathways by atmospheric dispersion and leachate seepage from landfill. Based on principal components analysis and multiple linear regression, these two pathways were estimated to account for 61% and 39% of the total concentrations, respectively. Additionally, the spatial and vertical distributions of octa-to deca-BDEs within soils were significantly influenced by soil particle size. Although the PBDEs inventory in the study area was comparatively low, the rapid urbanization in the TP might dramatically accelerate the PBDE emissions in the future. This study firstly introduced the presence of local PBDEs in the TP, and the inventory already influenced the surrounding environment. Once involved in the regional cycle of the TP, the local source of PBDEs from waste might significantly serve to raise background level resulting otherwise primarily from long-range atmospheric transport.

Organochlorine pesticides in the sedimentary core of the southern Tibetan Plateau: The missing pieces induced by lateral remobilization.

The sedimentary core in remote alpine lakes has been recognized as an ideal proxy to reconstruct the emission and air deposition histories of persistent organic pollutants (POPs). Nevertheless, POPs formerly stored in a catchment might also contribute to the variation in the lake sediment by lateral remobilization. In this study, to reveal the relative importance of lateral remobilization, we measured the vertical profiles and isomeric ratios of dichlorodiphenyltrichloroethanes (DDTs), hexachlorocyclohexanes (HCHs) and endosulfan in a dated sedimentary core collected from Lake Yamzho Yumco in the southern Tibetan Plateau. In addition to the flux peaks in the 1970s corresponding to the heavy atmospheric deposition of DDTs and HCHs, these pollutants' fluxes displayed rebounds in the flood periods, with characteristic low ratios of DDT/DDE (α-/ß-HCH). This might indicate a massive remobilization of "weathered" pesticides from catchment soil to the lake because of strong hydro-dynamics. Moreover, the relative contribution of lateral remobilization to the lake sediment in the past decades was recognized through the correlation between DDT/DDE (α-/ß-HCH) ratios and ∑DDT (∑HCH) fluxes. The results showed that the lateral remobilization contributed to 20-42% of the total fluxes. This study discriminated the air deposition from the contribution of lateral remobilization, which improves current understanding of the vertical POPs profiles in the sedimentary core.

High-resolution sedimentary records of some organochlorine pesticides in Yamzho Yumco Lake of the Tibetan Plateau: Concentration and composition.

Sediment cores from lakes have been used to reconstruct the historic deposition of persistent organic pollutants (POPs), especially in remote alpine areas. To reconstruct the deposition history of organochlorine pesticides (OCPs) in the Tibetan Plateau (TP), two sediment cores from Yamzho Yumco Lake were drilled and dated with high-resolution, from which 23 OCPs were analyzed in greater detail. Regarding several legacy compounds, concentration peaks in the cores were observed in the 1970s, corresponding to the heavy usage of these compounds around the world. In addition, another peak was found at the end of the 1990s, which was explained as the addition of OCPs released from melting glaciers or the cryosphere due to global warming. Furthermore, it was found that the transformation or degradation of OCPs after deposition in the lake was limited by comparing the values of isomeric ratios at different times, such as (DDD+DDE)/∑DDTs, o,p'-DDT/p,p'-DDT and ß-HCH/∑HCHs. Such results ensure that the detected OCPs in the lake sediments really reflect their characteristics at the time of deposition. On the other hand, weak environmental self-purification of the OCPs made them last longer in the TP than in other regions. Reasonably, the fragile ecological environment of the TP would be threatened not only by legacy POPs that remain in the sediments and soils but also by POPs released from melting glaciers or the cryosphere in the next few decades under the influence of global warming. Our research provides an insight into the influence of global warming and glacial melting on the environment of the TP, and further work to gain a better understanding of the environmental processes of POPs in the TP is ongoing.

The emerging source of polycyclic aromatic hydrocarbons from mining in the Tibetan Plateau: Distributions and contributions in background soils.

The Tibetan Plateau (TP) serves as the background for persistent organic pollutants around the world. In addition to outside sources, local sources greatly contribute to the environment of the TP in recent decades. Mining activity could serve as an emerging source of polycyclic aromatic hydrocarbons (PAHs), although this issue has been neglected in the TP until now. To investigate the distributions and contributions of PAHs transported from mining activity, forty-one surface soil samples along six sampling directions were collected at a regular distance from the Jiama mining area (JMA) of the TP at altitudes between 3726 and 4863m. The total concentration of 16 PAHs was 52.34±22.58ng/g. The result of the source identification suggested that mining activity represented the primary source for heavy molecular weight (HMW) PAHs in soils, while light molecular weight (LMW) and middle molecular weight (MMW) PAHs were contributed by multiple sources. For HMW PAHs, the concentrations and proportions decreased logarithmically with transport distance from the JMA. Furthermore, the transport distance of HMW PAHs was found to be affected by the prevailing wind direction. In addition to transport from the source area, the distributions of LMW and MMW PAHs were also influenced by the altitude. In the impact area of Jiama mining activity, the soil mass inventory was estimated to be 6.4±0.8tons for HMW PAHs. In future decades, HMW PAHs emitted from Jiama mining activity are projected to exceed 5% of the annual local emission in the TP. Our study evidenced that Tibetan mining activity serves as an important emerging source of PAHs, which would be transported within the TP and threaten the fragile ecosystem of the TP.

Evidence for persistent organic pollutants released from melting glacier in the central Tibetan Plateau, China.

Glacier alluvial deposits record persistent organic pollutants (POPs) not only derived from the atmospheric deposition but also from the release of glacial melting. The evidence for melting glacier in the Tibetan Plateau (TP) as a secondary source of pollutants is introduced through investigating the concentration of organochlorine pesticides (OCPs) in four deposited profiles collected at the edge of the Changwengluozha glacier. Two concentration peaks were observed for dichlorodiphenyltrichloroethanes (DDTs) and hexachlorocyclohexanes (HCHs) in the past century. The first peak was observed in the 1970s, corresponding with the heavy usage of HCHs and DDTs in the surrounding countries and regions. The second one was in 2000 when the production and usage of DDTs and HCHs were strictly limited, which possibly indicated a significant release from melting glacier. This result was further supported by the enantiomeric fraction values for α-HCH and o,p'-DDT. On the other hand, the dramatic increase of polycyclic aromatic hydrocarbons (PAHs) from atmospheric deposition, which was associated with the socioeconomic development in Tibet, shaded the release of PAHs from melting glacier. This study reveals not only the air deposition history of legacy POPs but also a substantial release of OCPs from glacier to the adjacent environment. Our research supports the hypothesis that the melting glacier in the TP represents a secondary source of OCPs, which is consistent with the findings in the Alps glaciers.

One century of air deposition of hydrocarbons recorded in travertine in North Tibetan Plateau, China: Sources and evolution.

The characteristic distribution patterns of hydrocarbons have been used for fingerprinting to identify their sources. The historical air depositions of hydrocarbons recorded in natural media help to understand the evolution of the air environment. Travertine is a natural acceptor of air deposition that settles on the ground layer by layer. To reconstruct the historical air environment of hydrocarbons in the North Tibetan Plateau (NTP), a unique background region, twenty-seven travertine samples were collected systematically from a travertine column according to its precipitated year. For each sample, the precipitated year was dated while n-alkanes and polycyclic aromatic hydrocarbons (PAHs) were determined. Based on source identification, the air environment of hydrocarbons in the past century was studied for the region of NTP. Before World War II, the anthropogenic sources of hydrocarbons showed little influence on the air environment. During World War II and China's War of Liberation, hydrocarbons increased significantly, mainly from the use of fossil fuels. Between 1954 and 1963, hydrocarbons in the air decreased significantly because the sources of petroleum combustion decreased. From the mid-1960s through the end of the 1990s, air hydrocarbons, which mainly originated from biomass burning, increased gradually because agriculture and animal husbandry were developing steadily in Tibet and China. From the late 1990s, hydrocarbons in the atmosphere increased rapidly due to the rapid increase of tourism activities, which might increase hydrocarbon emissions from traffic. The reconstruction of the historical air hydrocarbons in NTP clearly reflects the evolution of the region and global development.

Concentration and chiral signature of chlordane in soils and sediments of the Central Tibetan Plateau, China: Transformation in the surficial process.

The fraction of trans-chlordane (TC) in chlordane was used to indicate racemic degradation while the enantiomer fractions (EFs) indicated enantioselective depletion. In 44 soils of the Central Tibetan Plateau, the fractions of TC ranged from 0.368 to 0.411. The EFs ranged from 0.174 to 0.696 for TC and from 0.483 to 0.672 for cis-chlordane (CC). (-) enantiomer excess (ee) was found to be 80.0% in the soils for TC and (+) ee was 86.5% for CC. The fraction of TC changed with the clay content while the EFs changed with the soil organic carbon. Meanwhile, the fractions of TC and the EFs were determined for the surficial sediments in Yamzhog Yumco Lake, which were compared with those in the soils at its catchment area. The composition and chiral signature of chlordane did not vary between soils and sediments. Our results will help to elucidate the transformation of chlordane in soils and in surficial transport.

Polycyclic aromatic hydrocarbons in soils of the central Tibetan Plateau, China: Distribution, sources, transport and contribution in global cycling.

Forty-four soil samples were collected across the central Tibetan Plateau (CTP) at altitudes between 3711 m and 5352 m, and their polycyclic aromatic hydrocarbons (PAHs) contents were measured to be from 0.43 to 26.66 ng/g. The main sources of PAHs were identified for each of four sub-areas, and their concentrations in soils were determined to be mainly influenced by local sources. Along a 600 km sampling trajectory from Lhasa, which served as the biggest local source, the concentrations of PAHs decreased logarithmically with increasing distances from the source. Meanwhile, the fractional proportions of PAHs were observed to change logarithmically according to the transport distances. Conclusively, PAHs from local sources were transported within the CTP and dominated PAHs concentrations in the soils, but few of them were transported outside the CTP. In global cycling, the soils in the CTP mainly serve as background and a "sink" for PAHs.

Polybrominated diphenyl ethers in surface soils near the Changwengluozha Glacier of Central Tibetan Plateau, China.

Forty-two congeners of polybrominated diphenyl ethers (PBDEs) were detected for each of 27 surface-soil samples collected at an area near the Changwengluozha Glacier in the Central Tibetan Plateau (CTP), a remote background area at altitude from 5080 to 5217 m. The total concentrations of BDEs in soils ranged from 15.3 to 248.0 ng/kg, which were found to be positively correlated with the clay contents in the soil. In addition to adsorption, the clay was found to serve as a catalyst for the debromination of PBDEs in soils. Three pieces of evidence confirmed that the clay was significantly correlated with the debrominating transformation from the higher brominated congeners to the less brominated congeners. The transforming rate was found to be increased 3.5% with a 10% increase in clays. Debromination is an important way for highly brominated congeners to transform into lighter brominated congeners that are more toxic. This study first provided the direct field evidences for clays contributing to the debromination of PBDEs, and elucidated the importance of it in PBDEs' environmental fate.