Long-Range SECCM Enables High-Throughput Electrochemical Screening of High Entropy Alloy Electrocatalysts at Up-To-Industrial Current Densities.

High-entropy alloys (HEAs), especially in the form of compositional complex solid solutions (CCSS), have gained attention in the field of electrocatalysis. However, exploring their vast composition space concerning their electrocatalytic properties imposes significant challenges. Scanning electrochemical cell microscopy (SECCM) offers high-speed electrochemical analysis on surface areas with a lateral resolution down to tens of nm. However, high-precision piezo positioners often used for the motion of the tip limit the area of SECCM scans to the motion range of the piezo positioners which is typically a few tens of microns. To bridge this experimental gap, the study proposes a long-range SECCM system with a rapid gas-exchange environmental cell for high-throughput electrochemical characterization of 100 mm diameter HEA thin-film material libraries (ML) obtained by combinatorial co-sputtering. Due to the gas-liquid interface at the positioned SECCM droplet on the sample, high-throughput evaluation under industrial current density conditions becomes feasible. This allows the direct correlation between electrocatalytic activity and material composition with high statistical reliability. The multidimensional data obtained accelerates materials discovery, development, and optimization.

Disentangling Electronic and Geometric Effects in Electrocatalysis through Substitution in Isostructural Intermetallic Compounds.

Efficient development of catalytic materials requires knowledge of the decisive parameters defining the catalytic properties. In multicomponent metallic catalysts, these are categorized as electronic and geometric effects, yet they are strongly interrelated. A systematic disentanglement can be achieved by fixing one parameter while altering the other, which becomes possible through the substitution in isostructural intermetallic compounds. This approach enables the evaluation of electronic or geometric contributions both individually and combined. Herein, this is achieved by substitution of indium (three valence electrons) with tin (four valence electrons) in the series In1-xSnxPd2, which allows for a systematic variation of the total number of electrons per unit cell with only a minor variation of the unit cell parameters and thus the evaluation of the electronic effect. Geometric effects were evaluated by substitution of indium with gallium in the Ga1-xInxPd2 series, which allows for a systematic variation of the interatomic distances while maintaining the same number of valence electrons per unit cell and close atomic coordinates. By substituting gallium with tin in the Ga1-xSnxPd2 series, both effects are combined and addressed simultaneously. The activity enhancement of the methanol oxidation reaction on the Ga1-xSnxPd2 series is attributed to the synergy of the combined effects.

Control strategies to improve the low water quality of Souk-Ahras city.

This work reports control strategies of the water quality in the city of Souk-Ahras (east Algeria). With the recent development, rapid population growth, and the consequences of climate change, the capacity of water supply reserves becomes more unpredictable in the long term. This has drastically affected the distributed water quantity. A correlation between bacteriological water analysis and the analysis of pollution indicative physicochemical parameters is developed to replace the slow bacteriological analysis, which takes more than two days, by directly accessible physicochemical analysis to anticipate the case-onset of waterborne diseases. A good correlation is found between different combinations of physicochemical pollution parameters: (Turbidity, Nitrates); (Turbidity, Active chlorine) (nitrates, active chlorine); (Ammonium, Chlorine) and (Turbidity, Ammonium) with Spearman rank coefficients of 0.8657, -0.8602 and -0.8531 -0.8227 et 0.7957 respectively. Besides, long term analysis (over several years) revealed a high correlation of more than 0.92 between the analysis of pollution indicative physicochemical parameters and bacteriological analysis. The EPANET software is used to simulate the hydraulic behaviour of the network system over an extended period within pressurized and pressure-deficient conditions. The simulation results of several supply scenarios of daily drinking water pressure in the city center area show that 62% of drinking water distribution system is supplied with a steep slope (80 m), 10% with unsatisfactory pressure and only 23% with acceptable pressure (1-80 m). Therefore, the high working pressure at the mesh, and the interruptions of the water supply are factors that can lead to the occurrence of cross-connection cases. This diagnosis of the defects in the water supply system is combined with a statistical data analysis of physicochemical parameters to set up an effective sampling strategy that takes into account the frequency of analysis and the areas at risk to prevent the risk of waterborne diseases.

Challenging the Durability of Intermetallic Mo-Ni Compounds in the Hydrogen Evolution Reaction.

Molybdenum-nickel materials are catalysts of industrial interest for the hydrogen evolution reaction (HER). Well-characterized surfaces of the single-phase intermetallic compounds Ni7Mo7, Ni3Mo, and Ni4Mo were subjected to accelerated durability tests (ADTs) and thorough characterization to unravel whether crystallographic ordering affects the activity. Their intrinsic instability leads to molybdenum leaching, resulting in higher specific surface areas and nickel-enriched surfaces. These are more prone to form Ni(OH)2 layers, which leads to deactivation of the Mo-Ni materials. The crystal structure of the intermetallic compounds has, due to the intrinsic instability of the materials in alkaline media, no effect on the activity. Ni7Mo7, identified earlier as durable, proves to be highly unstable in the applied ADTs. The results show that the enhanced activity of unsupported bulk Mo-Ni electrodes can solely be ascribed to increased specific surface areas.

Synthesis and Catalytic Properties of Modified Electrodes by Pulsed Electrodeposition of Pt/PANI Nanocomposite.

In this study, the modification of glassy carbon electrodes by potentiostatic pulsed deposition of platinum nanoparticles and potentiostatic pulsed polymerization of polyaniline nanofibers was investigated. During the preparation of the nano-composite materials, the control of the potentiostatic pulsed deposition and potentiostatic pulsed polymerization parameters, such as pulse potential, pulse width time, duty cycle, and platinum precursor concentration allowed the optimization of the size, shape, and distribution of the deposited Pt nanoparticles. It is noteworthy that the polymerization method, cyclic voltammetry method, or potentiostatic pulsed polymerization method show an important effect in the morphology of the deposited polyaniline (PANI) film. The obtained modified electrodes, with highly uniform and well dispersed platinum nanoparticles, exhibit good electrocatalytic properties towards methanol oxidation.