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1.
J Phys Chem Lett ; 15(9): 2542-2549, 2024 Mar 07.
Artículo en Inglés | MEDLINE | ID: mdl-38413398

RESUMEN

Neuromorphic simulation, i.e., the use of electronic devices to simulate the neural networks of the human brain, has attracted a lot of interest in the fields of data processing and memory. This work provides a new method for preparing a 1,3-dimethylimidazolium nitrate ([MMIm][NO3]:H2O) microfluidic memristor that is ultralow cost and technically uncomplicated. Such a fluidic device uses capillaries as memory tubes, which are structurally similar to interconnected neurons by simple solution treatment. When voltage is applied, the transmission of anions and cations in the tube corresponds to the release of neurotransmitters from the presynaptic membrane to the postsynaptic membrane. The change of synaptic weights (plasticity) also can be simulated by the gradual change of conductance of the fluid memristor. The learning process of microfluidic memristors is very obvious, and the habituation and recovery behaviors they exhibit are extremely similar to biological activities, representing its good use for simulating neural synapses.

3.
Nanotechnology ; 26(17): 175705, 2015 May 01.
Artículo en Inglés | MEDLINE | ID: mdl-25850954

RESUMEN

The partially reduced TiO(2) nanotube arrays (TNAs) are prepared via an uncomplicated and low-cost liquid phase reduction strategy using NaBH(4) as the reducing agent. By controlling and adjusting the reduction temperatures from 30 to 90 °C, the reduction treatment can not only change their surface morphology but also introduce oxygen vacancies into them, resulting in an optimized morphology, elevated Fermi-level, reduced effective work function and improved conductivity of the TNAs. Meanwhile, the thermal and long-term stability of oxygen vacancy are also investigated, indicating that the oxygen vacancies retain long-term stability from room temperature up to 150 °C. More interesting, partially reduced TNAs show drastically enhanced field emission (FE) performances including substantially decreased turn-on field from 18.86 to 1.53 V µm(-1), a high current density of 4.00 mA cm(-2) at 4.52 V µm(-1), and an excellent FE stability and repeatability. These very promising results are attributed to the combination of the optimized morphology and introduced oxygen vacancies, which can increase FE sites, reduce effective work function and increase conductivity.

4.
Zhongguo Zhong Yao Za Zhi ; 38(13): 2197-201, 2013 Jul.
Artículo en Chino | MEDLINE | ID: mdl-24079253

RESUMEN

OBJECTIVE: To study the preventive effect of Ganlong capsule on chronic alcoholic hepatic injury in rats and its mechanism. METHOD: The rat chronic hepatic injury model was induced by intragastrically administered with gradient alcohol, once a day for 12 weeks. Efforts were made to detect the content of ALT, AST, TG, CHO, TNF-alpha in rat serum and GSH, SOD, MDA, ADH, Alb in hepatic tissues were detected, conduct a hepatic pathological examination, and pathological injury grading for livers. RESULT: Ganlong capsule could reduce the content of ALT, AST, TG in blood serum, MDA in hepatic tissues (P < 0.05), and enhance the activities of antioxidants such as SOD and GSH in hepatic tissues (P < 0.05). According to the liver histopathological observation, most structures of hepatic lobules in the model group were destroyed, with disordered liver cell cords, diffuse fat empty bubbles of different sizes in cytoplasm, focal necrosis and infiltration of inflammatory cells. All of treatment groups showed alleviation in rat liver injury to varying degrees. CONCLUSION: Ganlong capsule has a significant preventive effect to chronic alcoholic hepatic injury in rats.


Asunto(s)
Hepatopatías Alcohólicas/prevención & control , Animales , Cápsulas , Enfermedad Crónica , Femenino , Glutatión/metabolismo , Hígado/patología , Hepatopatías Alcohólicas/metabolismo , Hepatopatías Alcohólicas/patología , Masculino , Medicina Tradicional China , Ratas , Ratas Sprague-Dawley , Factor de Necrosis Tumoral alfa/sangre
5.
Huan Jing Ke Xue ; 29(4): 1002-6, 2008 Apr.
Artículo en Chino | MEDLINE | ID: mdl-18637353

RESUMEN

In order to enhance the efficiency of anaerobic digestion, the effects of ultrasonic pretreatment, alkaline pretreatment and the combination of these two methods have been studied on sludge disintegration by using multifrequency ultrasonic batch. The results showed that the combining of ultrasonic and alkaline treatment was more effective than alkaline or ultrasonic treatment alone in releasing SCOD and VSS solubilization. The VSS reduction rate was 15.98% with ultrasonic pretreatment alone, 22.12% with alkaline pretreatment alone(NaOH/TS = 0.04). When the sludge was pretreated by the alkaline treatment (NaOH/TS = 0.04) for 24 h followed by ultrasonic vibration for 60 min, and simultaneous ultrasonic (60 min) and alkaline( NaOH/TS = 0.04) treatment, the VSS reduction rate could reach 51.45% and 54.45% respectively. Two distinct phases of hydrolysis were observed. The first phase was a very rapid increase in solubilization, followed by a much slower second phase. According to kinetic analysis for first rapid phase, the simultaneous alkaline and ultrasonic treatment could not only get the highest hydrolysis rate among these methods, but also reduce the pretreatment time in ultrasonic pretreatment and alkaline dose in alkaline treatment.


Asunto(s)
Eliminación de Residuos/métodos , Aguas del Alcantarillado/química , Hidróxido de Sodio/química , Ultrasonido , Anaerobiosis , Reproducibilidad de los Resultados , Factores de Tiempo
6.
J Chem Phys ; 126(23): 234304, 2007 Jun 21.
Artículo en Inglés | MEDLINE | ID: mdl-17600417

RESUMEN

We report in this paper a quantum dynamics study for the reaction H+NH3-->NH2+H2 on the potential energy surface of Corchado and Espinosa-Garcia [J. Chem. Phys. 106, 4013 (1997)]. The quantum dynamics calculation employs the semirigid vibrating rotor target model [J. Z. H. Zhang, J. Chem. Phys. 111, 3929 (1999)] and time-dependent wave packet method to propagate the wave function. Initial state-specific reaction probabilities are obtained, and an energy correction scheme is employed to account for zero point energy changes for the neglected degrees of freedom in the dynamics treatment. Tunneling effect is observed in the energy dependency of reaction probability, similar to those found in H+CH4 reaction. The influence of rovibrational excitation on reaction probability and stereodynamical effect are investigated. Reaction rate constants from the initial ground state are calculated and are compared to those from the transition state theory and experimental measurement.

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