New directions on membranes for removal and degradation of emerging pollutants in aqueous systems.

Emerging pollutants (EPs) refer to a group of non-regulated chemical or biological substances that have been recently introduced or detected in the environment. These pollutants tend to exhibit resistance to conventional treatment methods and can persist in the environment for prolonged periods, posing potential adverse effects on ecosystems and human health. As we enter a new era of managing these pollutants, membrane-based technologies hold significant promise in mitigating impact of EPs on the environment and safeguarding human health due to their high selectivity, efficiency, cost-effectiveness and capability for simultaneous separation and degradation. Moreover, these technologies continue to evolve rapidly with the development of new membrane materials and functionalities, advanced treatment strategies, and analyses for effectively treating EPs of more recent concerns. The objective of this review is to present the latest directions and advancements in membrane-based technologies for addressing EPs. By highlighting the progress in this field, we aim to share valuable perspectives with researchers and contribute to the development of future directions in sustainable treatments for EPs.

Quantifying interfacial interactions for improved membrane antifouling: A novel approach using triangulation and surface element integration method.

To gain a thorough understanding of interfacial behaviors such as adhesion and flocculation controlling membrane fouling, it is necessary to simulate the actual membrane surface morphology and quantify interfacial interactions. In this work, a new method integrating the rough membrane morphology reconstruction technology (atomic force microscopy (AFM) combining with triangulation technique), the surface element integration (SEI) method, the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory, the compound Simpson's approach, and the computer programming was proposed. This new method can exactly mimic the real membrane surface in terms of roughness and shape, breaking the limitation of previous fractal theory and Gaussian method where the simulated membrane surface is only statistically similar to the real rough surface, thus achieving a precise description of the interfacial interactions between sludge foulants and the real membrane surface. This method was then applied to assess the antifouling propensity of a polyvinylidene fluoride (PVDF) membrane modified with Ni-ZnO particles (NZPs). The simulated results showed that the interfacial interactions between sludge foulants in a membrane bioreactor (MBR) and the modified PVDF-NZPs membrane transformed from an attractive force to a repulsive force. The phenomenon confirmed the significant antifouling propensity of the PVDF-NZPs membrane, which is highly consistent with the experimental findings and the interfacial interactions described in previous literature, suggesting the high feasibility and reliability of the proposed method. Meanwhile, the original programming code of the quantification was also developed, which further facilitates the widespread use of this method and enhances the value of this work.

Nanovoid-Enhanced Thin-Film Composite Reverse Osmosis Membranes Using ZIF-67 Nanoparticles as a Sacrificial Template.

In this work, nanovoid-enhanced thin-film composite (TFC) membranes have been successfully fabricated using ZIF-67 nanoparticles as the sacrificial template. By incorporating different amounts of ZIF-67 during interfacial polymerization, the resultant TFC membranes can have different degrees of nanovoids after self-degradation of ZIF-67 in water, consequently influencing their physiochemical properties and separation performance. Nanovoid structures endow the membranes with additional passages for water molecules. Thus, all the newly developed TFC membranes exhibit better separation performance for brackish water reverse osmosis (BWRO) desalination than the pristine TFC membrane. The membrane made from 0.1 wt % ZIF-67 shows a water permeance of 2.94 LMH bar-1 and a salt rejection of 99.28% when being tested under BWRO at 20 bar. This water permeance is 53% higher than that of the pristine TFC membrane with the salt rejection well maintained.

Emerging thin-film nanocomposite (TFN) membranes for reverse osmosis: A review.

Thin-film composite (TFC) membranes are the heart of reverse osmosis (RO) processes for desalination and water reuse. In recent years, nanomaterials with high permeability, selectivity and chemical resistance, and low fouling tendency have begun to emerge and be applied in many other fields. This has stimulated the research on novel RO membranes consisting of nanomaterials (non-porous and porous) in their selective layers. Encouraging results have been demonstrated. Herein, the state-of-the-art developments of polyamide thin-film nanocomposite (TFN) membranes for RO processes are summarized since the concept of TFN was introduced in 2007. While it is obvious that nanomaterials could impart exclusive properties, it should also be noted that significant challenges still exist for research and commercialization of TFN membranes, such as selection of proper nanomaterials, prevention of leaching of nanoparticles, and performance and cost analysis before large-scale RO membrane manufacturing. Future research directions are outlined to offer insights for the fabrication of much advanced TFN membranes with optimal interface morphology and separation performance.

Thin film nanocomposite hollow fiber membranes comprising Na+-functionalized carbon quantum dots for brackish water desalination.

We have incorporated Na+-functionalized carbon quantum dots (Na-CQDs) into the polyamide layer via interfacial polymerization reaction and developed novel thin film nanocomposite (TFN) hollow fiber membranes for brackish water desalination. Comparing with the conventional thin film composite (TFC) membranes, the TFN membranes comprising Na-CQDs have a larger effective surface area, thinner polyamide layer and more hydrophilic oxygen-containing groups in the polyamide layer. Besides, the interstitial space among the polyamide chains becomes larger due to the presence of Na-CQDs. As a result, the incorporation of 1 wt% Na-CQDs into the polyamide layer could improve the pure water permeability (PWP) of the membranes from 1.74 LMH/bar to 2.56 LMH/bar by 47.1% without compromising their NaCl rejection of 97.7%. Interestingly, stabilization of the TFN hollow fiber membranes containing 1 wt% Na-CQDs at 23 bar could further promote the PWP to 4.27 LMH/bar and the salt rejection to 98.6% under the same testing conditions due to the deformation of the membranes under a high hydraulic pressure. When using a 2000 ppm NaCl aqueous solution as the feed, the optimal water flux and rejection of the newly developed TFN membranes at 15 bar are 57.65 ±â€¯3.26 LMH and 98.6% ±â€¯0.35% respectively. The Na-CQDs incorporated TFN hollow fiber membranes show promising applications in the field of brackish water desalination.

Applications of carbon quantum dots (CQDs) in membrane technologies: A review.

Carbon quantum dots (CQDs), which are a fascinating class of nanostructured carbons, have recently attracted extensive attention in the field of membrane technologies for their applications in separation processes. This is because they possess two unique advantages. Their productions are facile and inexpensive, while their physicochemical properties such as ultra-small sizes, good biocompatibility, high chemical inertness, tunable hydrophilicity, rich surface functional groups and antifouling characteristics are highly desirable. Leveraging on these, researchers have explored their utilizations in various membrane designs for reverse osmosis (RO), ultrafiltration (UF), nanofiltration (NF), forward osmosis (FO), pressure retarded osmosis (PRO), membrane distillation (MD), and organic solvent nanofiltration (OSN) processes. In particular, CQDs have especially stimulated exploration in the field of water treatment by membrane technologies since biocompatibility of membrane materials is of utmost importance to ensure safety of drinking water. In addition, CQDs are in a favorable position for achieving unprecedented performance of membrane separation processes in water treatment, in the light of substantial efficiency enhancement and antifouling propensity as discovered in recent studies. In this article, we will review the progress in the development of CQD incorporated membranes with discussions on their challenges and perspectives.

Carbon Quantum Dots Grafted Antifouling Membranes for Osmotic Power Generation via Pressure-Retarded Osmosis Process.

Osmotic power generated by pressure-retarded osmosis (PRO) has attracted global attention as a clean, abundant and renewable energy resource. However, the substrates of PRO membranes are particularly prone to fouling because of their direct contact with various foulants in raw water. This leads to a significant decline in power density and impedes the commercialization of PRO technology. In this work, a facile surface modification method has been developed to obtain a new type of nanoparticle functionalized antifouling PRO membranes. Carbon quantum dots (CQDs), with an average size around 3.2 nm, are fabricated from citric acid via a simple method. Subsequently, they are immobilized onto the polydopamine (PDA) layer grafted on the substrate surface of poly(ether sulfone) (PES) membranes via covalent bonding. The bacteria diffusion tests show that the CQD modified PRO membranes possess much enhanced antibacterial activity and antibiofouling propensity. The continuous PRO operations at 15 bar also confirm that the CQD modified membranes exhibit a much higher power density (11.0 vs 8.8 W/m2) and water recovery after backwash (94 vs 89%) than the unmodified ones. This study may open up a new avenue in the fabrication of nanostructure functionalized polymeric membranes for wastewater treatment and osmotic power generation.