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1.
Inorg Chem ; 61(43): 17115-17122, 2022 Oct 31.
Artículo en Inglés | MEDLINE | ID: mdl-36256887

RESUMEN

A quaternary compound with the composition Mo3ReRuC is obtained in a previously unexplored MoReRu-Mo2C system. According to X-ray structural analysis, Mo3ReRuC crystallizes in the noncentrosymmetric space group P4132 [cubic ß-Mn-type structure, a = 6.8107(1) Å]. Below 7.7 K, Mo3ReRuC becomes a bulk type-II superconductor with an upper critical field close to the Pauli paramagnetic limit. The specific heat data give a large normalized jump ΔCp/γTc = 2.3 at Tc, which points to a strongly coupled superconducting state. First-principles calculations show that its electronic states at the Fermi level are mainly contributed by Mo, Re, and Ru atoms and strongly increased by the spin-orbit coupling. Our finding suggests that the intermediate phase between alloys and carbides may be a good place to look for ß-Mn-type noncentrosymmetric superconductors.

2.
J Phys Condens Matter ; 31(18): 185701, 2019 May 08.
Artículo en Inglés | MEDLINE | ID: mdl-30721896

RESUMEN

In this article, the structure, transport and magnetic properties were studied in details for EuMn0.8Sb2 crystals with the orthorhombic structure and Mn deficiencies. It was found that the temperature dependence of the resistivity exhibits a metallic behavior in the whole measuring temperature range, different from that in the crystals without Mn deficiencies. A large positive magnetoresistance (MR) (∼127% at 2 K and ∼25% at 300 K, in 9 T field) was observed, which can be ascribed to the combination of semiclassical MR and quantum limit MR of Dirac electrons. We also observed the high mobility of the carriers and large magnetothermopower effect at low temperatures, and two magnetic transitions emerging at ∼24 K and ∼10 K, respectively, corresponding to the antiferromagnetic ordering and canted arrangement of the Eu moments. Our findings shed new light on the intrinsic properties of EuMn0.8Sb2 and demonstrate the existence of Dirac fermions.

3.
Sci Rep ; 7(1): 1634, 2017 05 09.
Artículo en Inglés | MEDLINE | ID: mdl-28487572

RESUMEN

The so-called Dirac materials such as graphene and topological insulators are a new class of matter different from conventional metals and (doped) semiconductors. Superconductivity induced by doing or applying pressure in these systems may be unconventional, or host mysterious Majorana fermions. Here, we report a successfully observation of pressure-induced superconductivity in an antiferromagnetic Dirac material BaMnBi2 with T c of ~4 K at 2.6 GPa. Both the higher upper critical field, µ 0 H c2(0) ~ 7 Tesla, and the measured current independent of T c precludes that superconductivity is ascribed to the Bi impurity. The similarity in ρ ab (B) linear behavior at high magnetic fields measured at 2 K both at ambient pressure (non-superconductivity) and 2.6 GPa (superconductivity, but at the normal state), as well as the smooth and similar change of resistivity with pressure measured at 7 K and 300 K in zero field, suggests that there may be no structure transition occurred below 2.6 GPa, and superconductivity observed here may emerge in the same phase with Dirac fermions. Our findings imply that BaMnBi2 may provide another platform for studying SC mechanism in the system with Dirac fermions.

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