Recent advancement of nano-biochar for the remediation of heavy metals and emerging contaminants: Mechanism, adsorption kinetic model, plant growth and development.

Even though researches have shown that biochar can improve soil-health and plant-growth even in harsh environments and get rid of harmful heavy metals and new contaminants, it is still not sustainable, affordable, or effective enough. Therefore, scientists are required to develop nanomaterials in order to preserve numerous aquatic and terrestrial species. The carbonaceous chemical known as nano-biochar (N-BC) can be used to get rid of metal contamination and emerging contaminants. However, techniques to reduce hetero-aggregation and agglomeration of nano-biochar are needed that lead to the emergence of emerging nano-biochar (EN-BC) in order to maximise its capacity for adsorption of nano-biochar. To address concerns in regards to the expanding human population and sustain a healthy community, it is imperative to address the problems associated with toxic heavy metals, emerging contaminants, and other abiotic stressors that are threatening agricultural development. Nano-biochar can provide an effective solution for removal of emerging contaminants, toxic heavy metals, and non-degradable substance. This review provides the detailed functional mechanistic and kinetics of nano-biochar, its effectiveness in promoting plant growth, and soil health under abiotic stress. Nonetheless, this review paper has comprehensively illustrated various adsorption study models that will be employed in future research.

Characterization of hypersaline Oklahoma native microalgae cultivated in flowback and produced water: growth profile and contaminant removal.

This work explores the potential of three hypersaline native microalgae strains from Oklahoma, Geitlerinema carotinosum, Pseudanabaena sp., and Picochlorum oklahomensis, for simultaneous treatment of flowback (FW) and produced wastewater (PW) and the production of algal biomass. The quality of wastewater before and after treatment with these microalgae strains was evaluated and a characterization of algal biomass in terms of moisture, volatile matter, fixed carbon, and ash contents was assessed. The experimental results indicated how all the microalgae strains were able to grow in both FW and PW, revealing their potential for wastewater treatment. Although algal biomass production was limited by nutrient availability both in PW and FW, a maximum biomass concentration higher than 1.35 g L-1 were achieved by the three strains in two of the PWs and one of the FWs tested, with Pseudanabaena sp. reaching nearly 2 g L-1. Interestingly, higher specific growth rates were obtained by the two cyanobacteria strains G. carotinosum and Pseudanabaena sp. when cultivated in both PW and FW, compared to P. oklahomensis. The harvested algal biomass contained a significant amount of energy, even though it was significantly reduced by the very high salt content. The energy content fell within the recommended range of 16-17 MJ kg-1 for biomass as feedstock for biofuels. The algal treatment resulted in the complete removal of ammonia from the wastewater and a significant reduction in contaminants, such as nitrate, phosphate, boron, and micronutrients like zinc, manganese, and iron.

A state-of-art review on the redox activity of persistent free radicals in biochar.

Biochar-bound persistent free radicals (biochar-PFRs) attract much attention because they can directly or indirectly mediate the transformation of contaminants in large-scale wastewater treatment processes. Despite this, a comprehensive top-down understanding of the redox activity of biochar-PFRs, particularly consumption and regeneration mechanisms, as well as challenges in redox activity assessment, is still lacking. To tackle this challenge, this review outlines the identification and determination methods of biochar-PFRs, which serve as a prerequisite for assessing the redox activity of biochar-PFRs. Recent developments concerning biochar-PFRs are discussed, with a main emphasis on the reaction mechanisms (both non-free radical and free radical pathways) and their effectiveness in removing contaminants. Importantly, the review delves into the mechanism of biochar-PFRs regeneration, triggered by metal cations, reactive oxygen species, and ultraviolet radiations. Furthermore, this review thoroughly explores the dilemma in appraising the redox activity of biochar-PFRs. Components with unpaired electrons (particular defects and metal ions) interfere with biochar-PFRs signals in electron paramagnetic resonance spectra. Scavengers and extractants of biochar-PFRs also inevitably modify the active ingredients of biochar. Based on these analyses, a practical strategy is proposed to precisely determine the redox activity of biochar-PFRs. Finally, the review concludes by presenting current gaps in knowledge and offering suggestions for future research. This comprehensive examination aims to provide new and significant insights into the redox activity of biochar-PFRs.

Wastewater Treatment Using Membrane Bioreactor Technologies: Removal of Phenolic Contaminants from Oil and Coal Refineries and Pharmaceutical Industries.

Huge amounts of noxious chemicals from coal and petrochemical refineries and pharmaceutical industries are released into water bodies. These chemicals are highly toxic and cause adverse effects on both aquatic and terrestrial life. The removal of hazardous contaminants from industrial effluents is expensive and environmentally driven. The majority of the technologies applied nowadays for the removal of phenols and other contaminants are based on physio-chemical processes such as solvent extraction, chemical precipitation, and adsorption. The removal efficiency of toxic chemicals, especially phenols, is low with these technologies when the concentrations are very low. Furthermore, the major drawbacks of these technologies are the high operation costs and inadequate selectivity. To overcome these limitations, researchers are applying biological and membrane technologies together, which are gaining more attention because of their ease of use, high selectivity, and effectiveness. In the present review, the microbial degradation of phenolics in combination with intensified membrane bioreactors (MBRs) has been discussed. Important factors, including the origin and mode of phenols' biodegradation as well as the characteristics of the membrane bioreactors for the optimal removal of phenolic contaminants from industrial effluents are considered. The modifications of MBRs for the removal of phenols from various wastewater sources have also been addressed in this review article. The economic analysis on the cost and benefits of MBR technology compared with conventional wastewater treatments is discussed extensively.

Water self-purification via electron donation effect of emerging contaminants arousing oxygen activation over ordered carbon-enhanced CoFe quantum dots.

The release of emerging contaminants (ECs) into aquatic environments poses a significant risk to global water security. Advanced oxidation processes (AOPs), while effective in removing ECs, are often resource and energy-intensive. Here, we introduce a novel catalyst, CoFe quantum dots embedded in graphene nanowires (CoFeQds@GN-Nws), synthesized through anaerobic polymerization. It uniquely features electron-rich and electron-poor micro-regions on its surface, enabling a self-purification mechanism in wastewater. This is achieved by harnessing the internal energy of wastewater, particularly the bonding energy of pollutants and dissolved oxygen (DO). It demonstrates exceptional efficiency in removing ECs at ambient temperature and pressure without the need for external oxidants, achieving a removal rate of nearly 100.0%. The catalyst's structure-activity relationship reveals that CoFe quantum dots facilitate an unbalanced electron distribution, forming these micro-regions. This leads to a continuous electron-donation effect, where pollutants are effectively cleaved or oxidized. Concurrently, DO is activated into superoxide anions (O2•-), synergistically aiding in pollutant removal. This approach reduces resource and energy demands typically associated with AOPs, marking a sustainable advancement in wastewater treatment technologies.

Replacing traditional pretreatment in one-step UF with natural short-distance riverbank filtration: Continuous contaminants removal and TMP increase relief.

Scientists have been focusing on applying more natural processes instead of industrial chemicals in drinking water treatment to achieve the purpose of carbon emissions reduction. In this study, we shortened the infiltration range of riverbank filtration, a natural water purification process, to form the short-distance riverbank filtration (sRBF) which retained its ability in water quality improvement and barely influenced the groundwater environment, and integrated it with ultrafiltration (UF) to form a one-step sRBF-UF system. This naturalness-artificiality combination could realize stable contaminants removal and trans-membrane pressure (TMP) increase relief for over 30 days without dosing chemicals. Generally, both sRBF and UF played the important role in river water purification, and the interaction between them made the one-step sRBF-UF superior in long-term operation. The sRBF could efficiently remove contaminants (90 % turbidity, 60 % total nitrogen, 30 % ammonia nitrogen, and 25 % total organic carbon) and reduce the membrane fouling potential of river water under its optimum operation conditions, i.e., a hydraulic retention time of 48 h, an operation temperature of 20 °C, and a synergistic filter material of aquifer and riverbank soil. Synergistic adsorption, interception, and microbial biodegradation were proved to be the mechanisms of contaminants and foulants removal for sRBF. The sequential UF also participated in the reduction of impurities and especially played a role in intercepting microbial metabolism products and possibly leaked microorganisms from sRBF, assuring the safety of product water. To date, the one-step sRBF-UF was a new attempt to combine a natural process with an artificial one, and realized a good and stable product quality in long-term operation without doing industrial chemicals, which made it a promised alternative for water purification for cities alongside the river.

Selective formation of high-valent iron in Fenton-like system for emerging contaminants degradation under near-neutral and high-salt conditions.

In view of the near-neutral and high-salt conditions, the Fenton technology with hydroxyl radicals (HO•) as the main reactive species is difficult to satisfy the removal of trace emerging contaminants (ECs) in pharmaceutical sewage. Here, a layered double hydroxide FeZn-LDH was prepared, and the selective formation of ≡Fe(IV)=O in Fenton-like system was accomplished by the chemical environment regulation of the iron sites and the pH control of the microregion. The introduced zinc can increase the length of Fe-O bond in the FeZn-LDH shell layer by 0.22 Å compared to that in Fe2O3, which was conducive to the oxygen transfer process between ≡Fe(III) and H2O2, resulting in the ≡Fe(IV)=O formation. Besides, the amphoteric hydroxide Zn(OH)2 can regulate the pH of the FeZn-LDH surface microregion, maintaining reaction pH at around 6.5-7.5, which could avoid the quenching of ≡Fe(IV)=O by H+. On the other hand, owing to the anti-interference of ≡Fe(IV)=O and the near-zero Zeta potential on the FeZn-LDH surface, the trace ECs can also be effectively degraded under high-salt conditions. Consequently, the process of ≡Fe(IV)=O generation in FeZn-LDH system can satisfy the efficient removal of ECs under near-neutral and high-salt conditions.

Waste biomass-derived N, P co-doping carbon aerogel-coated CoxFe1-xP with modulated electron density for efficient electrooxidation of contaminants.

Developing low-cost, green, high-performing electrode materials to address environmental pollutants and the energy crisis is significant but challenging. Herein, the bimetallic iron cobalt phosphide coated in waste biomass-derived N, P co-doping carbon (CoxFe1-xP@NPC) is constructed. Furthermore, the active site density and the water decomposition energy barrier of surface-coated NPC are modulated by optimizing the electronic structure of CoxFe1-xP via doping engineering. The Fe-modulated CoxFe1-xP@NPC exhibits a hierarchical porous self-supporting structure and excellent physical & chemical properties with excellent electrooxidation performance, achieving over 95% removal of TCH within 60 min. The density functional theory (DFT) calculations further confirms that N carries more positive charge and P carries more negative charge in the NPC of CoxFe1-xP@NPC with Fe modulation, which can promote the adsorption and dissociation of water molecules. Of note, Co0.75Fe025P@NPC displays a low water dissociation energy barrier to produce ·OH and a high energy barrier to produce O2 than its counterparts. This study offers new insight into controllable modulation of biomass carbon-based composite electrode catalytic activity for high-efficiency degradation of contaminants.

Enhanced simultaneous removal of sulfamethoxazole and zinc (II) in the biochar-immobilized bioreactor: Performance, microbial structures and gene functions.

Biochar-immobilized functional bacteria Bacillus SDB4 was applied for sulfamethoxazole (SMX) and zinc (Zn2+) simultaneous removal in the bioreactor. Under the optimal operating conditions of HRT of 10 h, pH of 7.0, SMX concentration of 10 mg L-1 and Zn2+ concentration of 50 mg L-1, the removal efficiencies of SMX and Zn2+ by the immobilized reactor (IR) were 97.42% and 96.14%, respectively, 20.39% and 30.15% higher than those by free bioreactor (FR). SEM-EDS and FTIR results revealed that the functional groups and light metals on the carrier promoted the biosorption and biotransformation of SMX and Zn2+ in IR. Moreover, the improvement of SMX and Zn2+ removal might be related to the abundance enhancement of functional bacteria and genes. Bacillus SDB4 responsible for SMX and Zn2+ removal was the main strain in IR and FR. Biochar increased the relative abundance of Bacillus from 32.12% in FR to 38.73% in IR and improved the abundances of functional genes (such as carbohydrate metabolism, replication and repair and membrane transport) by 1.82%-11.04%. The correlations among the physicochemical properties, microbial communities, functional genes and SMX-Zn2+ co-contaminant removal proposed new insights into the mechanisms of biochar enhanced microbial removal of antibiotics and heavy metals in biochar-immobilized bioreactors.

Effect of a Permanganate-Bearing Reactive Oxidant on Flocs in Electrocoagulation: Transformations and Interfacial Interactions.

The electrocoagulation/ultrafiltration (ECUF) process is expected to address the issues of current wastewater increments and complex water reuse. However, the underlying mechanism associated with flocs remains unclear in the ECUF system, especially in the upgraded permanganate-bearing ECUF (PECUF) system. Herein, flocs and their formation, response to organic matter (OM), and interfacial features in the PECUF process were systematically explored. Results demonstrated that permanganate contributed to the rapid start-up of the coagulation process by forming MnO2 and blocking the ligand-metal charge transfer process between adsorbed Fe(II) and solid-phase Fe(III). The response of flocs to natural OM (NOM) exhibited obvious time- and particle size-dependent characteristics. Based on this, the optimal NOM adsorption window was found to be in the interval of 5-20 min, whereas the optimal NOM removal window was located at the 20-30 min interval. Furthermore, the extended Derjaguin-Landau-Verwey-Overbeek theory revealed the underlying principle of the PECUF module for optimizing UF performance. On the one hand, it reduced the inherent resistance of the cake layer by modifying the colloidal solution, which guaranteed a small drop (15%) in initial flux. On the other hand, it enhanced the repulsive force among suspended particles to achieve a long-term antifouling effect. This study may provide insights into the selection and performance control of on-demand assembly modules in decentralized water treatment systems.

Recycling of wet grinding industry effluent using effective Microorganisms™ (EM).

A considerable volume of effluent released from the food processing industries, after the extensive use in the products manufacturing and industrial process. Effluents, either without treatment or with improper treatment, released out from the industries would severely damage the environment and human health. An investigation was done by recycling the effluent samples, collected from the wet grinding industry, Madurai, India, which was determined with an acidic pH (5.93), high turbidity (160.78 NTU), high BOD (62.4 mg/l) and COD (274.38 mg/l) and a significantly higher quantity of starch (115.81 mg/l). Biological wastewater treatment method was chosen in this experiment on the basis of the biodegradability index of effluent (3.21-10.75). The main goal of this study was to evaluate the effectiveness of wastewater treatment in a prototype STP utilizing the Effective Micro-organisms™ Consortium application. The US EPA International Water Quality Standards and the Water Quality Index were used to compare the water quality of the recycled effluent with and without the EM application. The effluent from the EM consortium treatment was found to have acceptable levels of pH (7.38), salinity (1.94 ppt) and Conductivity (4.05 mS); and a declining trend found in TDS (1.81 ppt), BOD (24.4 mg/l) and COD (148.83 mg/l) level when the effluent treated using EM. Removal effectiveness of EM significant reduce in the treated effluents starch (85.15%), sulphate (78.42), phosphate (79.60), nitrogen (65.54%), and turbidity (82.73%) level were observed. Which was shown to be comparatively better than employing without EM treatment. This research substantially intends to the best practices, towards sustainable industries through Cleaner Production Mechanism.

A review: Manganese-driven bioprocess for simultaneous removal of nitrogen and organic contaminants from polluted waters.

Water pollutants, such as nitrate and organics have received much attention for their harms to ecological environment and human health. The redox transformation between Mn(Ⅱ) and Mn(Ⅳ) for nitrogen and organics removal have been recognized for a long time. Mn(Ⅱ) can act as inorganic electron donor to drive autotrophic denitrification so as to realize simultaneous removal of Mn(Ⅱ), nitrate and organic pollutants. Mn oxides (MnOx) also play an important role in the adsorption and degradation of some organic contaminants and they can change or create new oxidation pathways in the nitrogen cycle. Herein, this paper provides a comprehensive review of nitrogen and organic contaminants removal pathways through applying Mn(Ⅱ) or MnOx as forerunners. The main current knowledge, developments and applications, pollutants removal efficiency, as well as microbiology and biochemistry mechanisms are summarized. Also reviewed the effects of factors such as the carbon source, the environmental factors and operation conditions have on the process. Research gaps and application potential are further proposed and discussed. Overall, Mn-based biotechnology towards advanced wastewater treatment has a promising prospect, which can achieve simultaneous removal of nitrogen and organic contaminants, and minimize sludge production.

Greywater treatment in SBR-SND reactor - optimization of hydraulic retention time, volumetric exchange ratio and sludge retention time.

In this study, simultaneous nitrification and denitrification-sequencing batch reactor (SND-SBR) process was investigated to treat greywater. The effect of three process parameters, including hydraulic retention time (HRT), volumetric exchange ratio (VER) and sludge retention time (SRT), was optimised using a 23 full factorial design. The statistic model was developed for two response variables, i.e. chemical oxygen demand (COD) and ammonia (NH3-N) removal. The optimum conditions were 6.8 h HRT (anaerobic/aerobic/anoxic: 1.77 h/2.77 h/2.27 h), 0.7 VER and 7.94 d SRT, which resulted in 93.9% COD and 84.6% NH3-N removal efficiency. SRT was the most significant factor, followed by HRT and VER for COD and NH3-N removal. The interaction effect of VER and SRT was significant in COD removal. On the other hand, the interaction effects of HRT-VER and HRT-SRT were significant in NH3-N removal. The removal efficiencies of 89.6 ± 1.1% and 83.7 ± 2.3% were observed for TKN and TN, respectively, in the optimised SND-SBR system. NH3-N removal was obtained via nitrate pathway in the SND-SBR system. The PO43--P removal of 74.2 ± 3.4% was obtained via aerobic phosphorus uptake and post anoxic denitrification at the optimal condition. To enhance PO43--P removal, adsorption (using corn cob adsorbent) was integrated with SBR by adding the optimum adsorbent dose (0.5 g/L). The PO43--P removal efficiency in the SBR-adsorption system was found to be 80 ± 1.5%. The biodegradation of emerging contaminants (ECs) was also carried out in the SND-SBR system, and the results showed removal rate of 58.9 ± 2.3% benzophenone-3 (BP) and 80.1 ± 2.2% anionic surfactant (AS).

Prediction of organic contaminant rejection by nanofiltration and reverse osmosis membranes using interpretable machine learning models.

Efficiency improvement in contaminant removal by nanofiltration (NF) and reverse osmosis (RO) membranes is a multidimensional process involving membrane material selection and experimental condition optimization. It is unrealistic to explore the contributions of diverse influencing factors to the removal rate by trial-and-error experimentation. However, the advanced machine learning (ML) method is a powerful tool to simulate this complex decision-making process. Here, 4 traditional learning algorithms (MLR, SVM, ANN, kNN) and 4 ensemble learning algorithms (RF, GBDT, XGBoost, LightGBM) were applied to predict the removal efficiency of contaminants. Results reported here demonstrate that ensemble models showed significantly better predictive performance than traditional models. More importantly, this study achieved a compelling tradeoff between accuracy and interpretability for ensemble models with an effective model interpretation approach, which revealed the mutual interaction mechanism between the membrane material, contaminants and experimental conditions in membrane separation. Additionally, feature selection was for the first time achieved based on the aforementioned model interpretation method to determine the most important variable influencing the contaminant removal rate. Ultimately, the four ensemble models retrained by the selected variables achieved distinguished prediction performance (R2adj = 92.4 %-99.5 %). MWCO (membrane molecular weight cut-off), McGowan volume of solute (V) and molecular weight (MW) of the compound were demonstrated to be the most important influencing factors in contaminant removal by the NF and RO processes. Overall, the proposed methods in this study can facilitate versatile complex decision-making processes in the environmental field, particularly in contaminant removal by advanced physicochemical separation processes.

BiPO4-coated carbon microtube electrodes: preparation and characterization of their properties and electrocatalytic degradation of methylene blue.

Bismuth phosphate (BiPO4), a very attractive candidate for organics electrodegradation, harbors tremendous potential on removing contaminants from water. Here, four carbon microtube electrodes were prepared from corncob, each coated with BiPO4 by a different method to study the electrodegradation of methylene blue (MB). A thorough insight into the composite features of four electrodes was characterized. Better reversibility and electrocatalytic activity of the fourth electrode (BCC4) prepared by digital signal generator was presented with a current density of 5.71 mA cm-2 at a potential of 1.6 V vs Ag/AgCl. The electrochemical impedances and actual lifetime of BCC4 were 125 Ω and 833 h, respectively. The effectiveness of each kind of BiPO4/carbon electrode was preliminarily evaluated by analyzing the actual conversion rate of the MB concentration, which confirms MB electrodegradation by the BiPO4/carbon electrode was mainly dominated by the hydroxyl radical oxidation. The mass transfer rate was increased by carbon microtube; thereby, electrocatalysis of BiPO4/carbon electrode increased as revealed by an increase in the MB degradation rate. The rate constants k obtained for the degradation of MB by BiPO4/carbon electrode at 20 â„ƒ was 0.0046 mM-1 s-1, which was 11 times than that of BiPO4. The diffusion layer was decreased by carbon microtube, resulting in MB electrodegradation rate increased. The BiPO4 coated on the surface of the carbon microtube electrodes strengthened their electrocatalytic performance, which shed new light on effective selection of suitable carbon electrode for degradation of organics. Therefore, BiPO4/carbon electrode could be potentially applied in the electrodegradation of organic pollutants.

Integrating Reactive Chlorine Species Generation with H2 Evolution in a Multifunctional Photoelectrochemical System for Low Operational Carbon Emissions Saline Sewage Treatment.

Conventional wastewater treatment plants (WWTPs) suffer from high carbon emissions and are inefficient in removing emerging organic pollutants (EOPs). Consequently, we have developed a low operational carbon emissions multifunctional photoelectrochemical (PEC) system for saline sewage treatment to simultaneously remove organic pollutants, ammonia, and bacteria, coupled with H2 evolution. A reduced BiVO4 (r-BiVO4) photoanode with enhanced PEC properties, ascribed to constructing sufficient oxygen vacancies and V4+ species, was synthesized for the aforementioned technique. The PEC/r-BiVO4 process could treat saline sewage to meet local WWTPs' discharge standard in 40 min at 2.0 V vs Ag/AgCl and completely degrade carbamazepine (one of EOPs), coupled with 633 µmol of H2 production; 93.29% reduction in operational carbon emissions and 77.82% decrease in direct emissions were achieved by the PEC/r-BiVO4 process compared with large-scale WWTPs, attributed to the restrained generation of CH4 and N2O. The PEC system activated chloride ions in sewage to generate numerous reactive chlorine species and facilitate •OH production, promoting contaminants removal. The PEC system exhibited operational feasibility at varying pH and total suspended solids concentrations and has outstanding reusability and stability, confirming its promising practical potential. This study proposed a novel PEC reaction for reducing operational carbon emissions from saline sewage treatment.

Insights into mechanisms governing the passive removal of inorganic contaminants from acid mine drainage using permeable reactive barrier.

The permeable reactive barrier has been deemed as the most prudent and pragmatic way to passively manage and remediate acid mine drainage (AMD). Herein, insights into mechanisms governing the removal of inorganic contaminants from AMD using a permeable reactive barrier (PRB), i.e. pervious concrete, were reported. In particular, the effects of varying dosages, i.e., 6, 10, 30, and 60 g, of cementitious materials comprising CEM I 52.5R with or without fly ash, hydrated lime, and gypsum were evaluated whilst the fate of chemical species was underpinned using the state-of-the-art analytical techniques, along with PHREEQC geochemical modelling. The role of gypsum, a product formed from the interaction of PRB with AMD in heavy metals attenuation was also elucidated. Findings revealed cementitious materials to play an indispensable role in the removal of inorganic contaminants from AMD. Furthermore, alkalinity from used materials increases the pH (i.e. pH ≥ 12.5) of AMD leading to the precipitation of chemical species. Specifically, the efficacy registered the following sequence: Lime ≥ CEM I ≥ 30%FA ≥ Gypsum with ≥99 for Al and Fe except for Gypsum which attained ≥98 while the performance for Zn removal registered the following sequence, 97 ≥ 98 ≥ 88.8 ≥ 45% for CEM I ≥ Lime ≥30%FA ≥ Gypsum, respectively. Chemical species exist as divalent, trivalent, oxyanions, and other complexes in solution as predicted by PHREEQC. Moreover, they were removed as metal hydroxides, oxyhydrosulphates, and gypsum hence corroborating findings from XRD, SEM-EDS, and FTIR results. Mechanisms which were responsible for the removal of chemical species were precipitation, adsorption, co-adsorption, co-precipitation, ion exchange, and complexation. Henceforth, this study explicitly demonstrated mechanisms that underpin the removal of inorganic contaminants from AMD using PRB and findings from this study will be used to develop effective PRB for the management of acid mine drainage and the receiving environment.

Strategies to enhance the reactivity of zero-valent iron for environmental remediation: A review.

Application of zero-valent iron (ZVI) has become one of the most promising innovative technologies for the remediation of environmental pollutants. However, ZVI may suffer from the low intrinsic reactivity toward refractory pollutants, which seriously restricts its practical application in fields. Therefore, strategies have been developing to enhance the reactivity of ZVI. Until now, the most commonly used strategies include pretreatment of ZVI, synthesis of highly-active ZVI-based materials and additional auxiliary measures. In this review, a systematic and comprehensive summary of these commonly used strategies has been conducted for the following purposes: (1) to understand the fundamental mechanisms of the selected approaches; (2) to point out their advantages and shortcomings; (3) to illustrate the main problems of their large-scale application; (4) to forecast the future trend of developing ZVI technologies. Overall, this review is devoted to providing a fundamental understanding on the mechanism for enhancing the reactivity of ZVI and facilitating the practical application of ZVI technologies in fields.

Treatment efficiency of synthetic urban runoff by low-cost mineral materials under various flow conditions and in the presence of salt: Possibilities and limitations.

Urban runoff belongs to important carriers of pollutants that during infiltration can accumulate in the soil/water environment. One of the protection solutions may be the enhancement of infiltration systems by horizontal permeable treatment zones. The article presents the results of column tests carried out in order to determine (1) the influence of the hydraulic loading rate on the dynamic capacities of selected reactive materials: low-cost mineral materials (zeolite, limestone sand, halloysite) and reference material (activated carbon), and control soils (topsoil and Vistula sand) against Zn, NH4+ and PO43-, and (2) remobilization of contaminants under the influence of salt (NaCl 5 g/L) present in synthetic runoff water. The research has revealed that the most useful for the removal of zinc ions was limestone sand (>4.36 mg/g), of orthophosphates - halloysite (2.29 mg/g on the average), and of ammonium ions - zeolite (2.75 mg/g on the average). The control soils were characterized by low ability to immobilize the contaminants tested. In addition, increase in the hydraulic loading rate of synthetic runoff water reduced the dynamic capacity of materials to a variable degree depending on the material applied and the contamination removed (by 24% for limestone sand-PO43- system to 95% for activated carbon-NH4+ system). The presence of NaCl caused significant leaching of ammonium ions from zeolite and halloysite filter beds (up to 99.3%), and phosphates from the activated carbon filter bed (up to 41.3%). All tracer contaminants tested leached intensively from the Vistula sand filter bed, while only ammonium ions leached from the topsoil filter bed. It seems justified to support the performance of infiltration systems by layers of: limestone sand, to enhance the processes of heavy metal precipitation and ammonium ion volatilization by increasing the pH, and halloysite for the sorption of phosphates.