Ozone sensitivity regimes vary at different heights in the planetary boundary layer.

The sensitivity of tropospheric ozone (O3) to its precursors volatile organic compounds (VOCs) and nitrogen oxides (NOX) determines the emission reduction strategy for O3 mitigation. Due to the lack of comprehensive vertical measurements of VOCs, the vertical distribution of O3 sensitivity regimes has not been well understood. O3 precursor sensitivity determined by ground-level measurements has been generally used to guide O3 control strategy. Here, to precisely diagnose O3 sensitivity regimes at different heights in the planetary boundary layer (PBL), we developed a vertical measurement system based on an unmanned aerial vehicle platform to conduct comprehensive vertical measurements of VOCs, NOX and other relevant parameters. Our results suggest that the O3 precursor sensitivity shifts from a VOC-limited regime at the ground to a NOX-limited regime at upper layers, indicating that the ground-level O3 sensitivity cannot represent the situation of the whole PBL. We also found that the state-of-the-art photochemical model tends to underestimate oxygenated VOCs at upper layers, resulting in overestimation of the degree of VOCs-limited regime. Therefore, thorough vertical measurements of VOCs to accurately diagnose O3 precursor sensitivity is in urgent need for the development of effective O3 control strategies.

Vertically Resolved Aerosol Chemistry in the Low Boundary Layer of Beijing in Summer.

Air quality in Beijing has been improved significantly in recent years; however, our knowledge of the vertically resolved aerosol chemistry in summer remains poor. Here, we carried out comprehensive measurements of aerosol composition, gaseous species, and aerosol optical properties on a meteorological tower in Beijing in summer and compared with those measured in winter. Our results showed that aerosol liquid water (ALW) contributing approximately 50% of the total mass with higher values aloft played a crucial role in aerosol formation. Particularly, the higher nitrate concentration in city aloft than at the ground level during daytime was mainly due to the enhanced gas-particle partitioning driven by ALW and particle acidity. The vertical profiles of organic aerosol (OA) factors varied more differently in the urban boundary layer. Although the ubiquitous decreases in primary OA with the increase in height were mainly due to the influences of local emissions and vertical convection, the vertical differences in oxygenated OA between summer and winter may be related to the photochemical processing of different biogenic and anthropogenic volatile organic compounds. The single-scattering albedo, brown carbon, and absorption Ångstrom exponent of aerosol particles also presented different vertical profiles between day and night due to the vertical changes in aerosol chemistry.

External Validity of Calibrated Measurements from a Laser-Projection Transnasal Fiberoptic High-Speed Videoendoscopy System.

OBJECTIVE: Evidence-based practice and precision medicine can significantly benefit from the ability to perform calibrated spatial measurements (eg, mm) from endoscopic images. However, calibrated measurements are not readily available from laryngeal images. Laser-projection endoscopes can provide the required information for performing calibrated spatial measurements, but their applications require a process known as calibration. During calibration, a set of benchtop recordings are used to determine the effect of confounding factors of spatial measurements, and also to learn their proper compensation strategies. Calibration benchtop recordings are acquired from flat surfaces and at a perpendicular imaging angle which is significantly different from in-vivo situations, where a three-dimensional (3D) surface gets recorded at a semi-unknown imaging angle. The aim of this study was to quantify changes in calibrated vertical and horizontal measurement accuracies as we move from the controlled condition of calibration to more realistic and uncontrolled settings. METHOD: A flat surface was positioned in front of a calibrated laser-projection transnasal fiberoptic endoscope at different working distances and imaging angles. Calibrated vertical and horizontal measurement errors were computed from each condition. Multiple linear regression analyses were used to quantify the dependence of vertical and horizontal measurement errors on the imaging angle and working distance. Next, a 3D-printed surface was positioned in front of the laser-projection endoscope at different working distances. Calibrated vertical and horizontal measurement errors were computed from each condition and then they were compared to measurement errors from a flat surface positioned at comparable working distances. RESULTS: The outcome of analyses supported a significant effect of imaging angle on calibrated vertical measurement accuracy, while no significant effect of imaging angle on calibrated horizontal measurement accuracy was established. Additionally, the result of multiple linear regression analyses showed that the coefficient of imaging angle was two times larger than the working distance, which further highlights the significant effect of imaging angle on vertical measurement accuracy. Comparing the magnitude of calibrated vertical and horizontal measurement errors between the 3D surface and a flat surface suggested a significant effect of surface topology on calibrated measurement accuracies. CONCLUSIONS: The mean percent magnitude of error of vertical and horizontal measurement errors from the 3D surface were respectively around 6% and 11%, at most working distances, which are acceptable for many applications. However, the significant effect of imaging angle and surface topology on measurement errors highlights the need for further research on these confounding factors. It also suggests that significant improvements in measurement accuracies may be achieved if these factors are properly accounted for during the calibration process. Last but not least, this study highlights the need for the evaluation of laser-projection endoscopes in uncontrolled and more realistic settings. Specifically, evaluations of laser-projection endoscopes in very controlled settings could significantly overestimate their accuracies and hence it will not represent their actual performances during in-vivo data acquisitions.

Accuracy of computerized vertical measurements on digital orthopantomographs: posterior mandibular region.

OBJECTIVES: Orthopantomographs are commonly used for diagnosis in clinical dentistry. Although the manufacturers claim a constant magnification effect, the reliability of measuring dimensions on the panoramic radiographs is not clear. The aim of this study was to evaluate the accuracy of measuring vertical dimensions in the posterior mandibular area on digital orthopantomographs. MATERIALS AND METHODS: A retrospective survey of 20 orthopantomographs with unrestored implants (only with cover screw) in the mandibular posterior region (molars and premolars) was conducted. All radiographs were taken using the same machine by skilled technicians. Two examiners were asked to measure the vertical dimension of the implants seen on the radiographs viewed using two differently sized display screens. Inter-examiner and intra-examiner reliability tests were performed. Differences between the measured length and the actual length using each screen type were compared. RESULTS: High coefficients of reliability were observed on intra- and inter-examiner correlation. The overall reliability of measuring the vertical dimensions of implants between both examiners for the large screen and the small screen were 97.4% (Cronbach's alpha 0.993) and 94.0% (Cronbach's alpha 0.984), respectively. There were no significant differences between the errors seen with either the large screen or the small screen, when each of them was compared to the original length (P = 0.146). CONCLUSION: This study shows that vertical dimensions in the posterior mandibular region (molar and premolars) can be reliably measured on an orthopantomograph using a calibrated machine and special software.

Accuracy of linear vertical measurements in posterior mandible on panoramic view.

BACKGROUND: One of the most frequent concerns encountered in dental implant treatments is inadequate pre-operative planning. Panoramic radiographs are readily accessible and cost efficient. The aim of this study is to assess the accuracy of vertical measurements in mandibular molar and premolar region on panoramic radiography. MATERIALS AND METHODS: Panoramic radiographs were made of a partially edentulous sheep mandible mounted in acryl. Measurements collected from the computer-generated images were compared to measurements made directly on the cross-sectioned hemi-mandibles using t-test. P < 0.05 was considered significant. RESULTS: The results show that panoramic image is overestimated in predicting the linear measurements in posterior mandible. By applying the magnification factor of 1.29 the difference became insignificant. CONCLUSION: It seems rational to use panoramic radiography for pre-surgical implant assessment of posterior mandible if a true magnification factor is applied.