1.
J Am Chem Soc
; 134(47): 19358-61, 2012 Nov 28.
Artículo
en Inglés
| MEDLINE
| ID: mdl-23151262
RESUMEN
A novel nucleophilic substitution reaction at the nitrogen of arylsulfonamides by means of phosphide anions has been described. This reaction allows for the efficient transformation of arylsulfonamides into synthetically valuable phosphamides, amines, and a variety of protected amines.
Asunto(s)
Amidas/química , Arilsulfonatos/química , Nitrógeno/química , Fosfinas/química , Aminas/síntesis química , Aminas/química , Aniones/química , Dimetoato/síntesis química , Dimetoato/química , Estructura Molecular , Teoría Cuántica
2.
Bioorg Khim
; 31(1): 96-102, 2005.
Artículo
en Ruso
| MEDLINE
| ID: mdl-15787220
RESUMEN
The preparation conditions for dichlorophosphinylphosphorimidic trichloride were optimized. It was used in the synthesis of esters of imidodiphosphoric acid. The interaction of the trichloride with amines resulted in the corresponding amidodiphosphates rather than in the expected amides of imidodiphosphoric acid.