Removal of Cr(VI) from Wastewater Using Acrylonitrile Grafted Cellulose Extracted from Sugarcane Bagasse.

A highly efficient low-cost adsorbent was prepared using raw and chemically modified cellulose isolated from sugarcane bagasse for decontamination of Cr(VI) from wastewater. First, cellulose pulp was isolated from sugarcane bagasse by subjecting it to acid hydrolysis, alkaline hydrolysis and bleaching with sodium chlorate (NaClO3). Then, the bleached cellulose pulp was chemically modified with acrylonitrile monomer in the presence Fenton's reagent (Fe+2/H2O2) to carry out grafting of acrylonitrile onto cellulose by atom transfer radical polymerization. The developed adsorbent (acrylonitrile grafted cellulose) was analyzed by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). Both raw cellulose and acrylonitrile grafted cellulose were used for chromium removal from wastewater. The effects of metal ion concentration, pH, adsorbent dose and time were studied, and their values were optimized. The optimum conditions for the adsorption of Cr(VI) onto raw and chemically modified cellulose were: metal ion concentration: 50 ppm, adsorbent dose: 1 g, pH: 6, and time: 60 min. The maximum efficiencies of 73% and 94% and adsorption capacities of 125.95 mg/g and 267.93 mg/g were achieved for raw and acrylonitrile grafted cellulose, respectively. High removal efficiency was achieved, owing to high surface area of 79.92 m2/g and functional active binding cites on grafted cellulose. Isotherm and kinetics studies show that the experimental data were fully fitted by the Freundlich isotherm model and pseudo first-order model. The adsorbent (acrylonitrile grafted cellulose) was regenerated using three different types of regenerating reagents and reused thirty times, and there was negligible decrease (19%) in removal efficiency after using it for 30 times. Hence, it is anticipated that acrylonitrile could be utilized as potential candidate material for commercial scale Cr(VI) removal from wastewater.

Progress in the development and use of refrigerants and unintended environmental consequences.

The world has entered into the "fourth-generation" of refrigerants, and it is an undeniable fact that we will continue to encounter several issues in identifying a suitable refrigerant that suits the purpose and poses no harm to the environment. The ever-changing regulations on the use of refrigerants have often posed great challenges to the refrigeration industry and there is a pressing need to develop new refrigerants and develop better equipment to use them. Theoretically, an ideal refrigerant should possess characteristics such as low-global warming potential (GWP), non-toxic, non-flammable, and zero-ozone depletion potential (ODP). In addition, the refrigerants are also expected to have excellent thermodynamic and thermophysical properties. Many new synthetic refrigerants have been reported as alternative refrigerants and have very low atmospheric life as well as low GWP and zero-ODP. However, it is irrefutable that most of the studies that reported the so-called new refrigerants are actually not new. From the invention of R-12 (Dichlorodifluoromethane) in 1930s to the invention of R-1234yf in 2000s, these substances are available for decades even before being recognized as refrigerants. This review attempts to provide chronicles on different aspects of refrigerants such as their progress since their invention in the early 1800s, classification and properties. In addition, concepts such as issues associated with the long-term use of refrigerants, barriers for the inclusion of low-GWP refrigerants, various protocols and accords that have occurred since the inception of refrigerants are also critically discussed.

Development of a novel fungal fluidized-bed reactor for gaseous ethanol removal.

Fluidized bed bioreactors can overcome the limitations of packed bed bioreactors such as clogging, which has been observed in the industrial application for decades. The key to establish a gaseous fluidized bed bioreactor for treatment of volatile organic compounds is to achieve microbial growth on a light packing material. In this study, Two fungal species and two bacterial species were isolated to build a fungal fluidized-bed reactor (FFBR). A light packing material with wheat bran coated on expended polystyrene was used. The FFBR was operated for 65 days for gaseous ethanol removal and obtained elimination capacities of 500-1800 g∙m-3∙h-1 and removal efficiencies of 20-50%. The pressure drops was well controlled with values around 400 Pa∙m-1. Stress tolerant genera including Aureobasidium, Stenotrophomonas and Brevundimonas were dominant. Meyerozyma, whose species were present in an initial inoculated isolate, was detected among the dominant species with 28.70% relative abundance; they were reported to degrade complicated compounds under similarly stressful environments.

Ozonation and Depolymerization of Extracellular Polymeric Substances (EPS) Extracted from a Biofilter Treating Gaseous Toluene.

Low-concentration ozonation was developed as a novel technique to control the excess biomass in volatile organic compound (VOC) biofilters. In order to understand the reaction mechanism between ozone and biomass, the changes in properties of ozone exposed extracellular polymeric substances (EPS) were investigated in this study. EPS was sequestered from the biofilm, obtained from a biofilter treating gaseous toluene, and then it was exposed to gaseous ozone at 272 ± 22 ppm continuously for 12 h. The total organic carbon (TOC) results indicated that low concentration ozone could not mineralize the EPS to carbon dioxide (CO2) completely. The excitation-emission matrix fluorescence spectroscopy (EEM) results demonstrated that ozone preferred to attack the benzene ring and specific amino acid residues (such as tryptophan) on the protein chain. High performance size-exclusion chromatography (HPSEC) results confirmed that the protein molecules were depolymerized after ozone attack, while the molecular weight of polysaccharides was not much affected by ozone. During ozonation, few volatile organic compounds (VOCs), such as carboxylic acids, aldehydes, ketones, benzaldehyde and by-products of toluene, were generated, which confirms a minor change in the TOC concentration of EPS. Results revealed that low concentration ozone can reduce the molecular weight of biofilter EPS which can be a key reason for controlling biomass accumulation. Additionally, this can be used to study the composition of biofilm EPS from biofilters.

Co-occurrence of arsenic and fluoride in the groundwater of Punjab, Pakistan: source discrimination and health risk assessment.

The present study discusses elevated groundwater arsenic (As) and fluoride (F(-)) concentrations in Mailsi, Punjab, Pakistan, and links these elevated concentrations to health risks for the local residents. The results indicate that groundwater samples of two areas of Mailsi, Punjab were severely contaminated with As (5.9-507 ppb) and F(-) (5.5-29.6 ppm), as these values exceeded the permissible limits of World Health Organization (10 ppb for As and 1.5 ppm for F(-)). The groundwater samples were categorized by redox state. The major process controlling the As levels in groundwater was the adsorption of As onto PO4 (3-) at high pH. High alkalinity and low Ca(2+) and Mg(2+) concentrations promoted the higher F(-) and As concentrations in the groundwater. A positive correlation was observed between F(-) and As concentrations (r = 0.37; n = 52) and other major ions found in the groundwater of the studied area. The mineral saturation indices calculated by PHREEQC 2.1 suggested that a majority of samples were oversaturated with calcite and fluorite, leading to the dissolution of fluoride minerals at alkaline pH. Local inhabitants exhibited arsenicosis and fluorosis after exposure to environmental concentration doses of As and F(-). Estimated daily intake (EDI) and target hazard quotient (THQ) highlighted the risk factors borne by local residents. Multivariate statistical analysis further revealed that both geologic origins and anthropogenic activities contributed to As and F(-) contamination in the groundwater. We propose that pollutants originate, in part, from coal combusted at brick factories, and agricultural activities. Once generated, these pollutants were mobilized by the alkaline nature of the groundwater.