MCDA-DEA approach to construct a composite indicator for effluents from WWTPs considering the influence of PPCPs.

Considering current water situation, reuse is an effective solution to meet water demand and reduce pressure on conventional water sources. However, pharmaceutical and personal care products (PPCPs) in effluents from wastewater treatment plants (WWTPs) decrease their quality and suitability. With the aim of identifying and monitoring both the influence of PPCPs and the suitability of effluents to be reused, this study proposes the development of a composite indicator (CI) related to PPCP presence in WWTPs, through the common weight multi-criteria decision analysis (MCDA)-data envelopment analysis (DEA) model. Obtaining a CI for PPCPs is a novel approach in the published literature, showing a new perspective in PPCP management and their influence in wastewater treatment. Furthermore, this study proposes an improvement on MCDA-DEA model which maintains the initial hierarchy obtained for the units analyzed. The development of CI is based on information about the technological, environmental, social, and biological issues of WWTPs. Results show that 4 of the 33 WWTPs analysed had the best CI values, meaning that their effluents have lower environmental impact. The development of a CI related to PPCPs in WWTPs suggests that further steps are needed to manage the WWTP effluents. Hence, the need to implement preventive measures in WWTPs has been shown, even though the removal of PPCPs is not yet part of European law. This work highlights the importance of considering PPCPs as priority pollutants in wastewater management and reuse frameworks, to guarantee low environmental impact and adapt wastewater reuse based on a circular economy approach. HIGHLIGHTS: Emerging contaminants (PPCPs) are used as effluent quality indicators. A composite indicator for PPCPs performance has been developed through MCDA-DEA model. Indicator obtained allow decision makers implementing concrete actions to assess effluent quality. Results show the improvement capacity of the effluents quality through PPCPs removing.

Circular economy and payment for ecosystem services: A framework proposal based on water reuse.

Water scarcity forces the use of non-conventional water sources, to satisfy water demand, such as the effluent of wastewater treatment plants (WWTPs). Water reuse helps to close the urban water cycle and reduce pressure on available water resources, providing a bases for circular economy in the water sector. Under an ecosystem services (ES) point of view, if water reuse is considered the best management option in water scarcity areas, WWTPs are responsible for the ES of provisioning. One of the main requirements for the ES of provisioning is to guarantee the reclaimed water quality due to this water being discharged back into the ecosystem. Hence why removing pollutants, such as pharmaceutical and personal care products (PPCPs), is necessary to reduce the environmental impact of reused water. Considering the lack of legislation about PPCPs in effluents, this study proposes the use of the Payment for Ecosystem Services (PES) approach as an innovative solution to provide reclaimed water without PPCPs considering both the environmental and institutional context and the importance of WWTPs as non-conventional water sources. This study contributes to consider the PES as a water cycle management tool and its suitability to be used to remove PPCPs is highlighted, with the purpose of promoting water reuse in water scarcity areas under circular economy approach.

Identification and correction of congestion in wastewater treatment plants in the Community of Valencia, Spain.

The present work analyses the existence of congestion in a set of wastewater treatment plants (WWTPs) for the first time. The study sample included 47 WWTPs managed by the same operator and located in the Valencia region (eastern Spain). The method of analysis consisted in applying a new statistical model to identify and correct congestion situations based on data envelopment analysis (DEA), which takes into account undesirable outputs and multiple projections. The results showed a strong concentration of congested WWTPs (48.94-57.45%). Furthermore, the necessary corrections to avoid the congestion statuses entailed an average input reduction between 57.03 and 74.13% and an average increase in desirable outputs between 46.08% and 50.08%. In addition, only plant size had a significant relationship with the correction levels. The remaining contextual variables (age, overcapacity and type of water and sludge line) failed to show any significant impact on those corrections. To conclude, policy recommendations to improve the management of WWTPs are put forward, notably improving the management of smaller plants, which concentrate the largest percentage of correction.

Identification of effective parameters for anti-inflammatory concentration in València City's wastewater using fuzzy-set qualitative comparative analysis.

The current literature about pharmaceutical and personal care compounds (PPCPs) focuses on identifying their concentration and toxicological risk both in surface water and in wastewater. However, the influence of urban areas (population ageing, income level, hospitals and others) has not yet been analysed. Knowing how a population (and its facilities) affects PPCPs' presence in wastewater is important to identify the conditions that are responsible for their presence. In this work, the influence of water consumption, population ageing, income level, hospitals and nursing homes on the anti-inflammatory concentration have been analysed. To fill the gap between the quantitative data on PPCPs' concentration and the qualitative reasoning of the influence of urban areas on the anti-inflammatory concentration, the use of fuzzy-set qualitative comparative analysis (fsQCA) is proposed. The fsQCA results are presented as recipes that show the different causal combinations of conditions that explain the presence of anti-inflammatories in wastewater. Using fsQCA for urban wastewater management with the aim of explaining the presence of anti-inflammatories in wastewater treatment plants (WWTPs) is a novelty in the literature. The results obtained here show the influence of water consumption (WATCON), hospitals (HOSP) and population ageing (POPAG) as the main conditions for the anti-inflammatory concentration in Valèncian wastewater. Specifically, these conditions are present in all the recipes obtained with consistency of 99%. Through the results obtained, it would be possible to identify that HOSP are the main facilities that discharge anti-inflammatories into urban wastewater. Hence, the necessity of preventive measures to avoid the anti-inflammatory discharge into water bodies has been showed. Furthermore, under a methodological point of view, this work highlights the eligibility of fsQCA as a wastewater cycle management tool.

Efficiency of wastewater treatment facilities: The influence of scale economies.

The water cycle, from catchment to discharge, is a sector that involves an important investment and operation and maintenance costs. In particular, sewage treatment is a challenge for governments because they are having to consider economic, environmental, and social aspects. Within the European Union, implementation of Directive 91/271/EEC is responsible for the location of wastewater treatment facilities in the territory, due to the requirement that all urban areas must have this infrastructure to reduce the environmental impact of treated water in water bodies. Different sizes of municipalities affect the design of each wastewater treatment plant (WWTP) and cause variations in the operation process. The presence of scale economies in this sector has a significant influence on the efficiency of the wastewater treatment process and has a direct impact on the operational costs. Based on the pursuit of economic and environmental efficiency, this analysis extends the scope of the current literature because it recommends a specific, population equivalent (p.e.) range for which it would be suitable to achieve efficiency in wastewater treatment facilities-shedding light on the open debate about scale economies in WWTPs.

Monetary valuation of salicylic acid, methylparaben and THCOOH in a Mediterranean coastal wetland through the shadow prices methodology.

The presence of pharmaceutical and personal care products and drugs of abuse (PPCPs) in wastewater treatment plants (WWTPs) indicates discharge of the effluent may not be suitable for the ecological balance of water ecosystems, such as wetlands. These PPCPs degrade water quality, considered as an ecosystem service (ES), provoking serious environmental impacts. Assessing the monetary value of PPCPs can be used as a proxy for environmental status of the ES of water quality (ESWQ). Considering PPCPs as non-desirable outputs of WWTPs, the shadow prices methodology has been implemented using directional distance function to measure the environmental avoided cost of removing salicylic acid (SA), methylparaben (MP), and THCOOH from WWTPs effluents discharged to Albufera Natural Park (Spain). The SA shows the highest shadow price (138.16 €/µg), followed by THCOOH (48.15 €/µg), and MP (30.66 €/µg). These values are interpreted as the environmental cost that would be avoided if SA, MP, and THCOOH were removed from WWTPs effluents. The non-parametric tests show that wastewater treatment technology, together with population equivalent (as a proxy of the size of urban areas) and seasonality are factors that influence shadow prices obtained. The approach used in this study highlights the use of PPCPs as status indicators of ESWQ quantified in monetary units. As a way to synthesize the essential concepts to implement the shadow prices approach, this study proposes a flow diagram to represent the relationship between all the factors involved in this work. The use of shadow prices methodology proves that removing SA, MP, and THCOOH is associated with a measurable improvement in the ESWQ of Albufera Natural Park. The findings of this study will be useful for plant managers in order to make decisions about the removal of PPCPs in WWTPs effluents.