RESUMO
In this research, we established an enhanced aerobic biological method utilizing a high-density bacterial flora for the treatment of low-biochemical plating parts washing wastewater. The elucidation of pollutant removal mechanisms was achieved through a comprehensive analysis of changes in sludge characteristics and bacterial community structure. The results demonstrated that throughout the operational period, the organic load remained stable within the range of 0.01-0.02 kgCOD/kgMLSS·d, the BOD5/COD ratio increased from 0.004 mg/L to 0.33 mg/L, and the average removal rates for key pollutants, including COD, NH4+-N, and TN, reached 98.13%, 99.86%, and 98.09%. MLSS concentration remained at 7627 mg/L, indicating a high-density flora. Notably, Proteobacteria, Bacteroidota, and Acidobacteriota, which have the ability to degrade large organic molecules, had been found in the system. This study affirms the efficacy of the intensive aerobic biological method for treating low-biochemical plating washing wastewater while ensuring system stability.
Assuntos
Poluentes Ambientais , Águas Residuárias , Eliminação de Resíduos Líquidos/métodos , Reatores Biológicos/microbiologia , Nitrogênio/análise , Esgotos/química , Bactérias/metabolismo , Poluentes Ambientais/análiseRESUMO
Based on the theory of nitrogen and phosphorus removal and technical requirements, a micro-pressure double-cycle bioreactor coupled with membrane components was used to treat municipal wastewater. The method realized the simultaneous removal of organic matter, nitrogen, and phosphorus in the same reactor and had the characteristics of membrane bioreactor process. Results showed that the average removal efficiency of COD, NH+4-N, TN, and TP were 93.74%, 95.1%, 71.85%, and 81.03%, respectively. During operation, Proteobacteria and Bacteroidetes were the main dominant bacteria, and they had complete nitrogen and phosphorus metabolic pathways. Owing to the low protein content in the mixture, the design of film placement in the micro-precipitation zone was conducive to alleviating the membrane pollution caused by the accumulation of protein, thereby improving the effluent quality and extending the service life of the membrane components.
Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Esgotos/microbiologia , Eliminação de Resíduos Líquidos/métodos , Reatores Biológicos , Nitrogênio , FósforoRESUMO
The study proposed a method for determining total nitrogen (TN) content in activated sludge by ultrasound pre-treatment assisted wet method. Based on the single-factor experiment, with the TN content as the response value, the response surface methodology was employed to examine the individual and interactive effects of three factors: the dilution multiple of the sludge mixture, ultrasonic time, and ultrasonic power. At the same time, the physico-chemical parameters and the digestion-oxidation parameters were optimised. The results indicated that the optimal parameters were as follows; sludge dilution multiple of 225 times, stirring rate of 400 r/min, ultrasonic time of 22â minutes, ultrasonic power of 720 W, and optimal added volume of potassium persulfate at 8â mL with a digestion time of 40â minutes. The relative standard deviation (RSD) for the parallel determination of TN in sludge samples using ultrasonic pre-treatment assisted wet method was ≤2.77%, with a spike recovery rate of 98.49-101.43%. The method, ultrasonic pre-treatment assisted wet method to determine TN concentration in activated sludge, was simpler to operate, more accurate.
RESUMO
To solve the deterioration of effluent caused by low temperature in urban sewage treatment plant in cold areas, a new type of reactor was proposed, the biochemical environmental and low-temperature operating characteristics of the reactor were studied. Through analysis of flow simulation and dissolved oxygen (DO) distribution when the aeration rate was 0.6â m3/h, it showed that there were many different DO environments in the reactor at the same time, which provided favourable conditions for various biochemical reactions. The operation test showed that the average effluent removal rate of COD, TN, NH4+-N and TP was 92.53%, 74.57%, 89.61% and 96.04%, respectively. And there were a variety of functional bacteria related to nitrogen and phosphorus removal in the system, most of them with strong adaptability at low temperatures. Among the dominant microorganisms, Flavobacterium and Rhodobacter were related to denitrification, Aeromonas and Thiothrix were related to phosphorous removal. Denitrifying phosphorus removal was the main way of phosphorus removal. Picrust2 results showed that the reactor operated well at low temperature, and the regional difference distribution of nitrification genes further confirmed the existence of functional zones in the reactor. The results showed that the Micro-pressure Double-cycle reactor worked well at low temperature, which provided a new idea and way for the upgrading of urban sewage treatment plants in cold areas.
Assuntos
Desnitrificação , Purificação da Água , Esgotos , Eliminação de Resíduos Líquidos/métodos , Temperatura , Reatores Biológicos/microbiologia , Nitrificação , Fósforo , Nitrogênio , OxigênioRESUMO
Transient organic load shocks have an important influence on the removal of pollutants and the content and composition of extracellular polymeric substances (EPS). This study was based on a micro-pressure reactor (MPR) with the influent COD concentration as the variable, while different operating conditions were controlled by adjusting the aeration rate. The effect of single-cycle transient organic loading shocks on EPS and pollutant removal and the correlation between their changes were investigated. The results showed that COD removal was unaffected under the shock, and the effect of nitrogen and phosphorus removal decreased. As the incoming carbon source increased, the EPS content at shock increased, with the polysaccharide (PS) content being the most affected. As aeration increased, the effect of organic load shock on EPS and pollutant removal decreased. Under different aeration conditions, PS contributed to denitrification and anaerobic phosphorus release during transient organic load shocks, and protein (PN) contributed to aerobic phosphorus uptake. The reduction in PS and PN relative to the pre-shock caused by the shock resulted in the EPS exhibiting a favourable effect on COD removal and an inhibitory effect on the effectiveness of nitrogen and phosphorus removal.
Assuntos
Matriz Extracelular de Substâncias Poliméricas , Esgotos , Reatores Biológicos , Nitrogênio , Fósforo , Desnitrificação , Eliminação de Resíduos LíquidosRESUMO
This study aimed to propose a segmented influent method to inhibit sludge bulking. The sludge bulking phenomenon was observed in a A2/O coupled system treating municipal wastewater under low temperature (15 ± 0.5)°C. Adopting the segmented inlet water process, the distribution ratio of the inlet flow in the anaerobic zone and the aerobic zone were 2:1 and 1:1, the sludge bulking phenomenon was suppressed. The sludge loading rate (F/M) analysis showed that the F/M of the anaerobic zone with single-point inflow was only 0.15â kg COD·(kg MLSS·d)-1, which was prone to induce sludge bulking. However, the F/M concentration gradient of the system under segmented inlet water conditions was obvious, which could inhibit the sludge bulking caused by low F/M. The effluent removal results showed that the system had high removal rates of COD, NH4+-N, TN, and TP at a flow distribution ratio of 2:1, with average removal rates of 88.85% ± 2.94%, 91.26% ± 6.68%, 76.60% ± 5.60%, and 96.80% ± 2.17%, respectively. This study confirmed that the segment inlet method inhibited sludge bulking, while the flow distribution ratio of 2:1 also ensured efficient pollutant removal capacity of the system.
Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Eliminação de Resíduos Líquidos/métodos , Baías , Temperatura , Reatores BiológicosRESUMO
A municipal wastewater treatment plant plays an important role in treating urban sewage and reducing the quantity of pollutants discharged into rivers. However, the energy consumption of the municipal wastewater treatment industry is large. High energy consumption indirectly produces ecological damage, accelerates the energy crisis, and increases carbon emissions. For energy conservation and emission reduction in wastewater treatment plants, it is first necessary to identify the main factors influencing energy consumption. Electricity consumption accounts for more than 80% of the energy consumption of wastewater treatment plants. Wastewater quantity and wastewater quality have become the key influencing factors of energy conservation and consumption reduction in wastewater treatment plants. In this study, a municipal wastewater treatment plant in Northeast China was selected as the research object, and the measured data, such as air temperature, wastewater quantity, wastewater quality, and electricity consumption of the plant from 2017 to 2020 were statistically analyzed to explore the influences of temperature and wastewater quantity and wastewater quality indicators of influent and effluent on energy consumption. Firstly, the range of influent quantity in the wastewater treatment plant was large. The influent quantity in summer was high because some rainwater entered the sewage treatment plant. In winter, average daily electricity consumption (ADEC) was higher than that in summer. The relationship between ADEC and the wastewater quantity showed a positive correlation, and ADEC slowly increased with the increase in wastewater quantity. Electricity consumption per unit of wastewater (UEC) was negatively correlated with the wastewater quantity, but the correction coefficient in winter was larger than that in summer. Secondly, the ranges of chemical oxygen demand (CODCr) and ammonia nitrogen in influent were large, and the ranges of CODCr and ammonia nitrogen in effluent were small. Influent CODCr concentration was negatively correlated with influent ammonia nitrogen concentration. ADEC increased slightly with the increase in influent CODCr concentration. In winter, the increasing trend of ADEC with the influent CODCr concentration was higher than that in the summer. The increasing trend of UEC with the increase in influent COD concentration in summer was more significant than that in winter. Thirdly, influent CODCr in 11.6% of the samples exceeded the corresponding designed value, and influent ammonia nitrogen concentration in 41.4% of the samples exceeded the corresponding designed value. Effluent CODCr in 10.6% of the samples exceeded the First Level Class B standard in "Discharge Standard of Pollutants for Municipal Wastewater Treatment Plants (GB18918-2002)", and unqualified CODCr in 94% of the effluent samples was ascribed to the unqualified ammonia nitrogen concentration in the influent samples. The electricity consumption level under abnormal conditions was higher than that under normal conditions. Fourthly, ADEC was positively correlated with the average daily CODCr reduction. The correction coefficient of ADEC with average daily CODCr reduction was greater in winter than that in summer. Fifthly, the average electricity consumption per unit of wastewater was close to the national average energy consumption, displaying the characteristics of high energy consumption in winter and low energy consumption in summer. The correlation analysis results of unit electricity consumption and temperature showed that when it was below 0 °C, the lower the temperature, the higher the electricity consumption. In Northeast China, the influences of seasons and temperatures on the electricity consumption of sewage plants were obvious. Accordingly, it is necessary to implement the diversion of rainwater and sewage, reduce the discharge of unqualified wastewater from enterprises, and take thermal insulation measures in winter. In addition, activated sludge microorganisms suitable for a low temperature area and the optimal scheduling of sewage pipe networks can also improve the operation and management of sewage treatment plants.
Assuntos
Poluentes Ambientais , Purificação da Água , Águas Residuárias/química , Esgotos/química , Amônia/análise , Purificação da Água/métodos , Nitrogênio/análise , China , Eletricidade , Poluentes Ambientais/análise , Eliminação de Resíduos Líquidos/métodosRESUMO
To reveal the mechanisms of enhanced biological nitrogen and phosphorus removal by denitrifying phosphorus removal in a Micro-pressure swirl reactor (MPSR), this study used a MPSR to treat municipal wastewater and enriched denitrifying phosphate accumulating organisms (DPAOs) by using its alternating anaerobic-anoxic-aerobic environment. The coupling of denitrification phosphorus removal (DPR) and simultaneous nitrification endogenous denitrification phosphorus removal (SNEDPR) was achieved in MPSR, and the average removal rates of COD, NH4+-N, TN and TP were 91.57%, 98.51%, 85.88%, 96.08% respectively. The results of the batch experiments showed that DPAOs activity in the low dissolved oxygen (DO) and high DO zones were 70.5% and 74.3%. The results of intracellular carbon source conversion patterns, microbial assays and functional gene prediction indicated that Flavobacterium and Dechloromonas dominated the DPR process in the low DO zone. Based on these findings, nutrient removal pathways within the MPSR were integrated.
RESUMO
This study aimed to propose a novel air-lift multi-stage circulating integrated bioreactor (AMCIB) to treat urban sewage. The AMCIB combined the reaction zone and sedimentation zone, the alternating circulation of activated sludge in separate aerobic and anaerobic environments facilitates the enrichment of HN-AD bacteria. The preliminary study showed that AMCIB had high removal efficiencies for COD, NH4+-N, TN and TP under high dissolved oxygen (DO) concentration conditions, with average removal rates of 93.21 %, 96.04 %, 75.06 % and 94.30 %, respectively. IlluminaMiSeq sequencing results showed that the system successfully cultured heterotrophic nitrification-aerobic denitrification (HN-AD) functional bacteria (Pseudomonas, Acinetobacter, Aeromonas) that played a crucial role in sewage treatment, and Tetrasphaera was the central phosphorus removing bacteria in the system. Functional gene predictions showed that the HN-AD played a dominant role in the system.
Assuntos
Nitrificação , Nitrogênio , Aerobiose , Bactérias/genética , Bactérias Aeróbias , Reatores Biológicos/microbiologia , Desnitrificação , Processos Heterotróficos , Nitrogênio/análise , Oxigênio , Fósforo , Esgotos/microbiologiaRESUMO
Electroplating sludge is a hazardous waste produced in large quantities in the electroplating industry during production. It is rich in heavy metal resources and can be recovered as value-added heavy metal products. To recover Zn in electroplating sludge, Fe/Al/Ca impurities were effectively removed as hematite, boehmite, and calcium sulfate, respectively, via a facile hydrothermal method with reduction of nitric acid by addition of glucose. After the sludge was dissolved in nitric acid, the generated solution contained 6.1 g/L of Zn, 2.2 g/L of Fe, 2.5 g/L of Al, and 2.9 g/L of Ca. First, approximately 100% Fe was extracted as hematite nanoparticles containing 94.6 wt% Fe2O3 after the solution was treated at 190 °C for 6 h. Second, when the temperature was elevated to 270 °C, nearly 99% Al was isolated as boehmite particles containing 95.2 wt% Al2O3. Third, more than 98% Ca was removed as anhydrite, which contained 95.9 wt% CaSO4, by adding sulfuric acid. During the steps, the total loss of Zn was less than 3%, and 5.75 g/L of residual Zn was recovered as zincite containing 92.2 wt% ZnO by adjusting the pH to 8. The dissolved Fe, Al, and Ca impurities were successfully removed as purified hematite, boehmite, and anhydrite, respectively, through the stepwise separation method by adjusting reaction temperatures and pH. The high content of Zn in the electroplating sludge was finally purified as zincite.
Assuntos
Metais Pesados , Esgotos , Galvanoplastia , Reciclagem , ZincoRESUMO
This study aimed to propose a new type of micro-pressure swirl reactor (MPSR) to treat urban sewage. The MPSR could form a stable swirl in the reactor, and realized the coexistence of anaerobic, anoxic, and aerobic zones in a single aeration tank. The pilot study showed that MPSR achieved high removal efficient of SS, COD, NH4+-N, TN, TP under the conditions of drastic fluctuation in influent quality and temperature, and the average removal rate were 88.58%, 93.32%, 94.47%, 73.19%, 96.16%. The relative high abundance of Thermomonas, Thaurea, and Dechloromonas, etc, guaranteed the denitrification efficiency of the MPSR, and Dechloromonas was the main phosphorus removal bacteria in the system. The study confirmed the rationality of the structural design of the MPSR, and it was excellent in sewage treatment and stability.
Assuntos
Desnitrificação , Esgotos , Reatores Biológicos , Nitrogênio , Fósforo , Projetos Piloto , Eliminação de Resíduos LíquidosRESUMO
A micro-pressure swirl reactor (MPSR) was developed for carbon and nitrogen removal of wastewater, in which dissolved oxygen (DO) gradient and internal circulation could be created by setting the aerators along one side of the reactor, and micro-pressure could be realized by sealing most of the top cap and increasing the outlet water level. In this study, velocity and DO distribution in the reactor was measured, removal performance treating high-concentration wastewater was investigated, and the main functional microorganisms were analyzed. The experiment results indicated that there was stable swirl flow and spatial DO gradient in MPSR. Operated in sequencing batch reactor mode, distinct biological environments spatially and temporally were created. Under the average influent condition of chemical oxygen demand (COD) concentration of 2,884 mg/L and total nitrogen (TN) of 184 mg/L, COD removal efficiency and removal loading was 98% and 1.8 kgCOD/(m3·d) respectively, and TN removal efficiency and removal loading reached up to 90% and 0.11 kgTN/(m3·d) respectively. With efficient utilization of DO and simpler configuration for simultaneous nitrification and denitrification, the MPSR has the potential of treating high-concentration wastewater at lower cost.
Assuntos
Nitrogênio , Águas Residuárias , Análise da Demanda Biológica de Oxigênio , Reatores Biológicos , Desnitrificação , Nitrificação , Eliminação de Resíduos LíquidosRESUMO
Groundwater treatment sludge is a Fe/Mn-bearing waste that is mass produced in groundwater treatment plant. In this study, sludge was converted to a magnetic adsorbent (MA) by adding ascorbate. The sludge was weakly magnetised in the amorphous form with Fe and Mn contents of 28.8% and 8.1%, respectively. After hydrothermal treatment, Fe/Mn oxides in the sludge was recrystallised to siderite and rhodochrosite, with jacobsite as the intermediate in the presence of ascorbate. With an increment in ascorbate dosage, the obtained magnetic adsorbent had a significant increase in chromate adsorption but a decrease in magnetisation. When the Mascorbate/MFe molar ratio was 10, the produced MA-10 was a dumbbell-shaped nanorod with a length of 2-5 µm and a diameter of 0.5-1 µm. This MA-10 showed 183.2 mg/g of chromate adsorption capacity and 2.81 emu/g of magnetisation. The mechanism of chromate adsorption was surface coprecipitation of the generated Cr3+ and Fe3+/Mn4+ from redox reaction between chromate and siderite/rhodochrosite on MA-10, separately. This study demonstrated an efficient recycling route of waste sludge from groundwater treatment to produce MA for treating chromate-bearing wastewater.
Assuntos
Cromatos/química , Magnetismo , Nanotubos/química , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/química , Adsorção , Carbonatos/química , Compostos Férricos/química , Ferro/química , Cinética , Manganês/química , Oxirredução , Óxidos/químicaRESUMO
Mn-containing sludge from groundwater treatment was converted to magnetic particles (MPs) via a one-step hydrothermal method using sodium ascorbate (SA) as the reductant. The MPs were characterized by X-ray diffraction spectroscopy, Mössbauer spectroscopy, X-ray fluorescence spectroscopy, magnetometry and Gran titration and the results showed that magnetic jacobsite was obtained as an intermediate product in transformation of Fe/Mn oxides to siderite and rhodochrosite. When the molar ratio of SA to Mn in the sludge was two, the produced MPs-2 contained a mixture of ferrihdyrite, hematite, jacobsite and Si/Al oxides, and could magnetize at 2.4 emu/g. Ferrihydrite content in MPs decreased with increase of the SA/Mn molar ratio, leading to decrease of the surface sites concentration (Hs). Thus, MPs-2 contained optimized Hs of 6.7â¯mmoL/g and a desirable adsorption capacity of Cu(II) (73.1â¯mg/g). The adsorption isotherms of MPs-2 on Cu(II) complied with the Langmuir model and the adsorption kinetics fitted well with the pseudo-second-order model. The major mechanism of adsorption was cationic exchange of the coordinated H and Na ions on MPs-2 surface sites with the Cu(II) ions. This study was the first time to report preparation of MPs by recycling Mn-containing sludge, which could be used as a high-capacity and low-cost adsorbent in treatment of heavy metal-containing wastewater.
Assuntos
Água Subterrânea , Esgotos , Adsorção , Concentração de Íons de Hidrogênio , Íons , Cinética , ManganêsRESUMO
With increasing awareness of reduction of energy and CO2 footprint, more waste is considered recyclable for generating value-added products. Here we reported the negatively-valued iron mud, a waste from groundwater treatment plant, was successfully converted into magnetic adsorbent. Comparing with the conventional calcination method under the high temperature and pressure, the synthesis of the magnetic particles (MPs) by Fe2+/Fe3+ coprecipitation was conducted at environment-friendly condition using ascorbic acid (H2A) as reduction reagent and nitric acid (or acid wastewater) as leaching solution. The MPs with major component of Fe3O4 were synthesized at the molar ratio (called ratio subsequently) of H2A to Fe3+ of iron mud ≥ 0.1; while amorphous ferrihydrite phase was formed at the ratio ≤ 0.05, which were confirmed by vibrating sample magnetometer (VSM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). With the ratio increased, the crystalline size and the crystallization degree of MPs increased, and thus the Brunauer-Emmett-Teller (BET) surface and the cation-exchange capacity (CEC) decreased. MPs-3 prepared with H2A to Fe3+ ratio of 0.1 demonstrated the highest methylene blue (MB) adsorption of 87.3 mg/g and good magnetic response. The adsorption of MB onto MPs agreed well with the non-linear Langmuir isotherm model and the pseudo-second-order model. Pilot-scale experiment showed that 99% of MB was removed by adding 10 g/L of MPs-3. After five adsorption-desorption cycles, MPs-3 still showed 62% removal efficiency for MB adsorption. When nitric acid was replaced by acid wastewater from a propylene plant, the synthesized MPs-3w showed 3.7 emu/g of saturation magnetization (Ms) and 56.7 mg/g of MB adsorption capacity, 2.8 times of the widely used commercial adsorbent of granular active carbon (GAC). The major mechanism of MPs adsorption for MB was electrostatic attraction and cation exchange. This study synthesized a magnetic adsorbent from the negatively-valued iron mud waste by using an environment-friendly coprecipitation method, which had a potential for treatment of dye wastewater.
Assuntos
Ferro , Azul de Metileno , Águas Residuárias/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Adsorção , Troca Iônica , Ferro/química , Ferro/isolamento & purificação , Cinética , Magnetismo , Reciclagem/métodos , Eletricidade Estática , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/químicaRESUMO
A novel micro-pressure swirl reactor (MPSR) was designed and applied to treat domestic wastewater at low temperature by acclimating microbial biomass with steadily decreasing temperature from 15 to 3 °C. Chemical oxygen demand (COD) was constantly removed by 85% and maintained below 50 mg L-1 in the effluent during the process. When the air flow was controlled at 0.2 m3 h-1, a swirl circulation was formed in the reactor, which created a dissolved oxygen (DO) gradient with a low DO zone in the center and a high DO zone in the periphery for denitrification and nitrification. 81% of total nitrogen was removed by this reactor, in which ammonium was reduced by over 90%. However, denitrification was less effective because of the presence of low levels of oxygen. The progressively decreasing temperature favored acclimation of psychrophilic bacteria in the reactor, which replaced mesophilic bacteria in the process of treatment.
Assuntos
Análise da Demanda Biológica de Oxigênio , Reatores Biológicos/microbiologia , Nitrogênio/isolamento & purificação , Pressão , Temperatura , Águas Residuárias/química , Amônia/análise , Bactérias/metabolismo , Biodegradação Ambiental , Biodiversidade , Eletroforese em Gel de Gradiente Desnaturante , Nitratos/análise , Nitritos/análise , Oxigênio/análise , Fatores de Tempo , Eliminação de Resíduos LíquidosRESUMO
Increasingly, environmental regulations are demanding more exacting chemical oxygen demand (COD) and nitrogen removal from wastewater, which come at a high economic cost. A very simple novel bioreactor, the micro-pressure swirl reactor (MPSR), can improve the dissolution and distribution of oxygen by the introduced micro-pressure swirl. Comparison with a conventional sequencing batch reactor (SBR) over 76 days of operation showed that this method can enhance simultaneous COD and nitrogen removal. By installing an aeration diffuser on one side of the two-dimensional MPSR, a swirl formed in the bioreactor that extended the retention time of the air bubbles. This unique flow regime, combined with the micro-pressure caused by the elevated water surface at the bubble outflow point, resulted in a higher level of dissolved oxygen (DO) in the MPSR. Aerobic and anaerobic zones that created appropriate conditions for simultaneous COD and nitrogen removal also formed in the MPSR. As the organic loading rate increased from 0.29 to 1.68 g COD/(L · day) over the test period, the COD removal efficiencies of the MPSR were generally 10-20 % greater than those of the SBR. In particular, the total nitrogen (TN) removal efficiencies of the MPSR and SBR were 40-50 and 20-35 %, respectively, whereas the TN concentrations in the MPSR effluent were always around 10 mg/L lower than those of the SBR. Further, because of the unique DO distribution, the bacterial species in the MPSR were more diverse and contributed to enhanced TN removal.
Assuntos
Reatores Biológicos , Meios de Cultura/química , Oxigênio/análise , Purificação da Água/métodos , Aerobiose , Análise da Demanda Biológica de Oxigênio , Nitrogênio/metabolismoRESUMO
Iron sludge, produced from filtration and backwash of groundwater treatment plant, has long been considered as a waste for landfill. In this study, iron sludge was reused to synthesize Fe3O4 magnetic particles (MPs) by using a novel solvothermal process. Iron sludge contained abundant amounts of silicon, iron, and aluminum and did not exhibit magnetic properties. After treatment for 4h, the amorphous Fe in iron sludge was transformed into magnetite Fe3O4, which could be easily separated from aqueous solution with a magnet. The prepared particles demonstrated the intrinsic properties of soft magnetic materials and could aggregate into a size of 1 µm. MPs treated for 10h exhibited excellent magnetic properties and a saturation magnetization value of 9 emu/g. The obtained particles presented the optimal adsorption of methylene blue under mild conditions, and the maximum adsorption capacity was 99.4 mg/g, which was higher than that of granular active carbon. The simple solvothermal method can be used to prepare Fe3O4 MPs from iron sludge, and the products could be applied to treatment of dyeing wastewater.
Assuntos
Água Subterrânea , Magnetismo , Azul de Metileno/química , Esgotos , Adsorção , Microscopia Eletrônica de Varredura , Nitrogênio/química , Espectroscopia Fotoeletrônica , Espectroscopia de Mossbauer , Difração de Raios XRESUMO
Phosphorus is the restrictive factor of water eutrophication and phosphorus removal is the key point to control this phenomenon. It's also important to recover phosphorus resource from wastewater. Crystallization method was used to treat and recycle high concentration phosphorus wastewater, the selection of organic solvent, influence of volume ratio of organic solvent and wastewater, precipitation time and stirring speed on the production of crystal and its structure was investigated. Experimental results indicate that, with ethanol as extractant, under the condition of volume ratio of ethanol to wastewater being 1.5:1 and stirring speed about 200 r/min, crystal precipitated fast with fine crystal shape and purity, phosphorus removal efficiency more than 85% was obtained.