An assessment of potential pesticide transmission, considering the combined impact of soil texture and pesticide properties: A meta-analysis.

Pesticides are widely employed as a cost-effective means of reducing the impacts of undesirable plants and animals. The aim of this paper is to develop a risk ranking of transmission of key pesticides through soil to waterways, taking into account physico-chemical properties of the pesticides (soil half-life and water solubility), soil permeability, and the relationship between adsorption of pesticides and soil texture. This may be used as a screening tool for land managers, as it allows assessment of the potential transmission risks associated with the use of specified pesticides across a spectrum of soil textures. The twenty-eight pesticides examined were differentiated into three groups: herbicides, fungicides and insecticides. The highest risk of pesticide transmission through soils to waterways is associated with soils containing <20% clay or >45% sand. In a small number of cases, the resulting transmission risk is not influenced by soil texture alone. For example, for Phenmedipham, the transmission risk is higher for clay soils than for silt loam. The data generated in this paper may also be used in the identification of critical area sources, which have a high likelihood of pesticide transmission to waterways. Furthermore, they have the potential to be applied to GIS mapping, where the potential transmission risk values of the pesticides can be layered directly onto various soil textures.

An Investigation into the Growth of Lolium perenne L. and Soil Properties Following Soil Amendment with Phosphorus-Saturated Bauxite Residue.

Reuse options for bauxite residue include treatment of phosphorus (P)-enriched wastewaters where the P-saturated media offers fertiliser potential. However, few studies have assessed the impact on soil properties. Two types of spent P-saturated bauxite residue were applied to soil and compared to conventional superphosphate fertiliser as well as a control soil. Soil physico-chemical properties, worm Eisenia fetida L. choice tests, and Lolium perenne L. growth and elemental uptake were examined. Comparable biomass and plant content for L. perenne in the P-saturated bauxite residue treatments and those receiving superphosphate, indicated no phytotoxic effects. E. fetida L. showed a significant preference for the control soil (58 %± 2.1%) over the amended soils, indicating some form of salt stress. Overall, P-saturated bauxite residue was comparable to the superphosphate fertiliser in terms of the plant performance and soil properties, indicating the potential recycling of P from wastewaters using bauxite residue as a low-cost adsorbent.

Climate-induced changes in the suitable habitat of cold-water corals and commercially important deep-sea fishes in the North Atlantic.

The deep sea plays a critical role in global climate regulation through uptake and storage of heat and carbon dioxide. However, this regulating service causes warming, acidification and deoxygenation of deep waters, leading to decreased food availability at the seafloor. These changes and their projections are likely to affect productivity, biodiversity and distributions of deep-sea fauna, thereby compromising key ecosystem services. Understanding how climate change can lead to shifts in deep-sea species distributions is critically important in developing management measures. We used environmental niche modelling along with the best available species occurrence data and environmental parameters to model habitat suitability for key cold-water coral and commercially important deep-sea fish species under present-day (1951-2000) environmental conditions and to project changes under severe, high emissions future (2081-2100) climate projections (RCP8.5 scenario) for the North Atlantic Ocean. Our models projected a decrease of 28%-100% in suitable habitat for cold-water corals and a shift in suitable habitat for deep-sea fishes of 2.0°-9.9° towards higher latitudes. The largest reductions in suitable habitat were projected for the scleractinian coral Lophelia pertusa and the octocoral Paragorgia arborea, with declines of at least 79% and 99% respectively. We projected the expansion of suitable habitat by 2100 only for the fishes Helicolenus dactylopterus and Sebastes mentella (20%-30%), mostly through northern latitudinal range expansion. Our results projected limited climate refugia locations in the North Atlantic by 2100 for scleractinian corals (30%-42% of present-day suitable habitat), even smaller refugia locations for the octocorals Acanella arbuscula and Acanthogorgia armata (6%-14%), and almost no refugia for P. arborea. Our results emphasize the need to understand how anticipated climate change will affect the distribution of deep-sea species including commercially important fishes and foundation species, and highlight the importance of identifying and preserving climate refugia for a range of area-based planning and management tools.

The use of rapid, small-scale column tests to determine the efficiency of bauxite residue as a low-cost adsorbent in the removal of dissolved reactive phosphorus from agricultural waters.

Bauxite residue, the by-product produced in the alumina industry, is a potential low-cost adsorbent in the removal of phosphorus (P) from aqueous solution, due to its high composition of residual iron oxides such as hematite. Several studies have investigated the performance of bauxite residue in removing P; however, the majority have involved the use of laboratory "batch" tests, which may not accurately estimate its actual performance in filter systems. This study investigated the use of rapid, small-scale column tests to predict the dissolved reactive phosphorus (DRP) removal capacity of bauxite residue when treating two agricultural waters of low (forest run-off) and high (dairy soiled water) phosphorus content. Bauxite residue was successful in the removal of DRP from both waters, but was more efficient in treating the forest run-off. The estimated service time of the column media, based on the largest column studied, was 1.08 min g-1 media for the forest run-off and 0.28 min g-1 media for the dairy soiled water, before initial breakthrough time, which was taken to be when the column effluent reached approximately 5% of the influent concentration, occurred. Metal(loid) leaching from the bauxite residue, examined using ICP-OES, indicated that aluminium and iron were the dominant metals present in the treated effluent, both of which were above the EPA parametric values (0.2 mg L-1 for both Al and Fe) for drinking water.