A promising approach for the removal of hexavalent and trivalent chromium from aqueous solution using low-cost biomaterial.

Heavy metal pollution is an enduring environmental challenge that calls for sustainable and eco-friendly solutions. One promising approach is to harness discarded plant biomass as a highly efficient environmental friendly adsorbents. In this context, a noteworthy study has spotlighted the employment of Euryale ferox Salisbury seed coat (E.feroxSC) for the exclusion of trivalent and hexavalent chromium ions. This study aims to transform discarded plant residue into a novel, environmentally friendly, and cost-effective alternative adsorbent, offering a compelling alternative to more expensive adsorption methods. By repurposing natural materials, we can contribute to mitigating heavy-metal pollution while promoting sustainable and economically viable solutions in environmental remediation. The effect of different parameters, i.e., chromium ions' initial concentration (5-25 mg L-1), solution pH (2-7), adsorbent dosage (0.2-2.4 g L-1), contact time (20-240 min), and temperature (298-313 K), were investigated. E.feroxSC proved highly effective, achieving 96.5% removal of Cr(III) ions at pH 6 and 97.7% removal of Cr(VI) ions at pH 2, with a maximum biosorption capacity of 18.33 mg/g for Cr(III) and 13.64 mg/g for Cr(VI), making it a promising, eco-friendly adsorbent for tackling heavy-metal pollution. The adsorption process followed the pseudo-second-order kinetic model, aligning well with the Langmuir isotherm, exhibited favorable thermodynamics, and was characterized as feasible, spontaneous, and endothermic with physisorption mechanisms. The investigation revealed that E.feroxSC effectively adsorbed Cr(VI) which could be rejuvenated in a basic solution with minimal depletion in its adsorption capacity. Conversely, E.feroxSC's adsorption of Cr(III) demanded rejuvenation in an acidic milieu, exhibiting comparatively less efficient restoration.

Entrapment behaviours of trivalent and hexavalent chromium from aqueous medium using edible alkali-derived activated carbon of Eichhornia crassipes (water hyacinth).

The study examines the adsorption capabilities of an environmentally friendly activated carbon derived from a novel activating agent, i.e., an edible alkali prepared from black gram plant ash, for the removal of Cr(III) and Cr(VI) ions from an aqueous environment. The results of the systematic research show impressive removal efficiencies of 95.12% for Cr(III) ions and 99.6% for Cr(VI) ions. The kinetics and equilibrium data of the adsorption process confirm to the pseudo-second-order kinetics and Freundlich isotherm model. The thermodynamic analysis reveals the adsorption process as feasible and spontaneous across the temperature range of 298-313 K. The mechanism entails electrostatic attraction and adsorption of Cr(III) and Cr(VI) ions on oppositely charged surfaces and the participation of oxygen-containing functional groups on WHAC-BGA surface in the reduction of Cr(VI) to Cr(III). This study provides valuable insights for optimizing strategies to combat chromium contamination in water sources, offering a sustainable solution with the potential for real-world application.

Regulation of secondary growth by poplar BLADE-ON-PETIOLE genes in Arabidopsis.

BLADE-ON-PETIOLE (BOP) genes are essential regulators of vegetative and reproductive development in land plants. First characterized in Arabidopsis thaliana (Arabidopsis), members of this clade function as transcriptional co-activators by recruiting TGACG-motif binding (TGA) basic leucine zipper (bZIP) transcription factors. Highly expressed at organ boundaries, these genes are also expressed in vascular tissue and contribute to lignin biosynthesis during secondary growth. How these genes function in trees, which undergo extensive secondary growth to produce wood, remains unclear. Here, we investigate the functional conservation of BOP orthologs in Populus trichocarpa (poplar), a widely-used model for tree development. Within the poplar genome, we identified two BOP-like genes, PtrBPL1 and PtrBPL2, with abundant transcripts in stems. To assess their functions, we used heterologous assays in Arabidopsis plants. The promoters of PtrBPL1 and PtrBPL2, fused with a ß-glucuronidase (GUS) reporter gene showed activity at organ boundaries and in secondary xylem and phloem. When introduced into Arabidopsis plants, PtrBPL1 and PtrBPL2 complemented leaf and flower patterning defects in bop1 bop2 mutants. Notably, Arabidopsis plants overexpressing PtrBPL1 and PtrBPL2 showed defects in stem elongation and the lignification of secondary tissues in the hypocotyl and stem. Finally, PtrBPL1 and PtrBPL2 formed complexes with TGA bZIP proteins in yeast. Collectively, our findings suggest that PtrBPL1 and PtrBPL2 are orthologs of Arabidopsis BOP1 and BOP2, potentially contributing to secondary growth regulation in poplar trees. This work provides a foundation for functional studies in trees.

Visible light photocatalytic degradation of methylene blue and rhodamine B over silver-doped titanium dioxide nanocomposites supported on Fuller's earth.

Silver-doped-titanium dioxide nanoparticles supported on Fuller's earth, prepared by the sol-gel method, were characterized with XRD, TGA, zeta potential, SEM, EDX, TEM, XPS, photoluminescence and UV-DRS measurements. The material, Ag-TiO2-Fuller's earth (AgTF), was tested for photocatalytic activity concerning the degradation of rhodamine B (RhB) and methylene blue (MB) in aqueous solution under visible light irradiation with pH, catalyst dosage, and dye concentration as the process variables. The degradation kinetics indicated pseudo-first-order kinetics with rate constant of (i) 0.55 min-1with 0.12 gL-1AgTF loading, 10-5 M MB at pH 9, and (ii) 0.53 min-1 with 0.08 g L-1 AgTF loading, 5 × 10-5 M RhB at pH 8. The methylene blue degradation was maximum (98.66%) for AgTF loading of 0.12 g L-1 while the maximum RhB degradation (96.34%) was attained with AgTF loading of 0.08 g L-1. With 5 × 10-6M MB concentration, the degradation achieved was 98% in 45 min and 100% in 60 min. One hundred per cent degradation of the dye, RhB (1 × 10-6 M) could be achieved in 30 min with 0.08 g L-1 AgTF at pH 8. The use of Fuller's earth, a cheap, abundant and large surface area support, increases the adsorbability of the dye on the catalyst surface and hence promotes the degradation. The catalyst could be removed easily from the reaction mixture and reused for up to five cycles without any significant decrease in activity. Scavengers such as triethanolamine (TEOA), p-benzoquinone (BQ) and isopropyl alcohol (IPA) were utilized to get some insight into the photocatalysis mechanism.

Efficacious Sorption Capacities for Pb(II) from Contaminated Water: A Comparative Study Using Biowaste and Its Activated Carbon as Potential Adsorbents.

Heavy-metal pollution is a persevering environmental menace, which demands the necessity of its removal by green and ecofriendly adsorbents. To combat this problem, discarded plant biomass can be used as an efficient substitute. Herein, a comparative study has been highlighted for the removal of Pb2+ ions using Euryale ferox Salisbury seed coat and its activated carbon, which is prepared by a first-time-reported activating agent that is a novel and non-hazardous bioresource. The batch investigation revealed a 99.9% removal efficiency of Pb(II) by the activated carbon compared to Euryale ferox Salisbury seed coat, which shows only an 89.5% removal efficiency at neutral pH. The adsorption mechanism is mainly a multilayered process, which involves electrostatic, van der Waals, and hydrogen bonding interactions. The adsorption equilibrium, kinetic, and thermodynamic studies were examined for the biosorbents, which revealed the adsorption process to be feasible, spontaneous, and exothermic with both physisorption and chemisorption adsorption mechanisms. The desorption study asserted the reusability of both the biosorbents to a maximum of three cycles.

Condensation Product of p-anisaldehyde and L-phenylalanine: Fluorescent "on-off" Sensor for Cu2+ and IMPLICATION Logic Gate.

(Z)-2-(4-methoxybenzylideneamino)-3-phenylpropanoic acid (L) synthesized by condensation of p-anisaldehyde and L-phenylalanine acts as selective fluorescent as well as voltammetric sensor for Cu2+ in 2:1 (v/v) CH3OH:H2O. The fluorescence intensity of L (λmax 425 nm) is quenched ca. 65% by Cu2+. Metal ions - Li+, Na+, K+, Al3+, Cu2+, Zn2+, Cd2+, Hg2+, Mn2+, Ni2+ and Pb2+ do not interfere. The binding constant and the detection limits were calculated to be 0.56 × 102 M-1 and 10-6 M respectively. DFT and TDDFT calculations confirmed 2:1 binding stoichiometry between L and Cu2+ obtained from fluorescence data. The interaction between L and Cu2+ is reversible for many cycles with respect to ethylenediamine tetraacetate anion (EDTA2-) which results in IMPLICATION logic gate.

Clade I TGACG-Motif Binding Basic Leucine Zipper Transcription Factors Mediate BLADE-ON-PETIOLE-Dependent Regulation of Development.

Lateral organs formed by the shoot apical meristem (SAM) are separated from surrounding stem cells by regions of low growth called boundaries. Arabidopsis (Arabidopsis thaliana) BLADE-ON-PETIOLE1 (BOP1) and BOP2 represent a class of genes important for boundary patterning in land plants. Members of this family lack a DNA-binding domain and interact with TGACG-motif binding (TGA) basic Leu zipper (bZIP) transcription factors for recruitment to DNA. Here, we show that clade I bZIP transcription factors TGA1 and TGA4, previously associated with plant defense, are essential cofactors in BOP-dependent regulation of development. TGA1 and TGA4 are expressed at organ boundaries and function in the same genetic pathways as BOP1 and BOP2 required for SAM maintenance, flowering, and inflorescence architecture. Further, we show that clade I TGAs interact constitutively with BOP1 and BOP2, contributing to activation of ARABIDOPSIS THALIANA HOMEOBOX GENE1, which is needed for boundary establishment. These studies expand the functional repertoire of clade I TGA factors in development and defense.