Using predictive models unravel the potential of titanium oxide-loaded activated carbon for the removal of leachate ammoniacal nitrogen.

The TiO2 nanocomposite efficiency was determined under optimized conditions with activated carbon to remove ammoniacal nitrogen (NH3-N) from the leachate sample. In this work, the facile impregnation and pyrolysis synthesis method was employed to prepare the nanocomposite, and their formation was confirmed using the FESEM, FTIR, XRD, and Raman studies. In contrast, Raman phonon mode intensity ratio ID/IG increases from 2.094 to 2.311, indicating the increase of electronic conductivity and defects with the loading of TiO2 nanoparticles. The experimental optimal conditions for achieving maximum NH3-N removal of 75.8% were found to be a pH of 7, an adsorbent mass of 1.75 mg/L, and a temperature of 30 °C, with a corresponding time of 160 min. The experimental data were effectively fitted with several isotherms (Freundlich, Hill, Khan, Redlich-Peterson, Toth, and Koble-Corrigan). The notably elevated R2 value of 0.99 and a lower ARE % of 14.61 strongly support the assertion that the pseudo-second-order model compromises a superior depiction of the NH3-N reduction process. Furthermore, an effective central composite design (CCD) of response surface methodology (RSM) was employed, and the lower RMSE value, precisely 0.45, demonstrated minimal disparity between the experimentally determined NH3-N removal percentages and those predicted by the model. The subsequent utilization of the desirability function allowed us to attain actual variable experimental conditions.

A comprehensive review on anaerobic digestion with focus on potential feedstocks, limitations associated and recent advances for biogas production.

With the escalating energy demand to accommodate the growing population and its needs along with the responsibility to mitigate climate change and its consequences, anaerobic digestion (AD) has become the potential approach to sustainably fulfil our demands and tackle environmental issues. Notably, a lot of attention has been drawn in recent years towards the production of biogas around the world in waste-to-energy perspective. Nevertheless, the progress of AD is hindered by several factors such as operating parameters, designing and the performance of AD reactors. Furthermore, the full potential of this approach is not fully realised yet due the dependence on people's acceptance and government policies. This article focuses on the different types of feedstocks and their biogas production potential. The feedstock selection is the basic and most important step for accessing the biogas yield. Furthermore, different stages of the AD process, design and the configuration of the biogas digester/reactors have been discussed to get better insight into process. The important aspect to talk about this process is its limitations associated which have been focused upon in detail. Biogas is considered to attain the sustainable development goals (SDG) proposed by United Nations. Therefore, the huge focus should be drawn towards its improvements to counter the limitation and makes it available to all the rural communities in developing countries and set-up the pilot scale AD plants in both developing and developed countries. In this regard, this article talks about the improvements and futures perspective related to the AD process and biogas enhancement.