The Zn1-xPbxCr2Se4-Single Crystals Obtained by Chemical Vapour Transport-Structure and Magnetic, Electrical, and Thermal Properties.

Monocrystalline chalcogenide spinels ZnCr2Se4 are antiferromagnetic and semiconductor materials. They can be used to dope or alloy with related semiconducting spinels. Therefore, their Pb-doped display is expected to have unique properties and new potential applications. This paper presents the results of dc and ac magnetic measurements, including the critical fields visible on the magnetisation isotherms, electrical conductivity, and specific heat of the ZnCr2S4:Pb single crystals. These studies showed that substituting the diamagnetic Pb ion with a large ion radius for the Zn one leads to strong short-range ferromagnetic interactions in the entire temperature range and spin fluctuations in the paramagnetic region at Hdc = 50 kOe.

Effect of CrossFit Training on Physical Fitness of Kickboxers.

Background: Kickboxing is a combat sport that is complex in technique, tactics, and movement structure, and requires an adequate level of motor skills as a foundation for activities during competitions. General physical fitness, defined as the effect of the externalization of motor skills, is the basis for athletic training regardless of the sport. The aim of this study was to determine the effect of modified training based on the principles of CrossFit on the development of general physical fitness in a group of kickboxers compared to a control group. Methods: The study was experimental in nature and was conducted in a group of 60 kickboxers, divided into experimental and control groups. Participants were selected by purposive sampling, and the criteria were training experience, sports skill level (minimum class 1 athletes), and consent to participate in the experiment. The intervention in the study group involved the introduction of CrossFit-based training into a conventional kickboxing training program. General and special physical fitness of the athletes were diagnosed. Results: Statistically significant differences were found in general fitness in terms of abdominal strength (p < 0.001), pull-ups (p < 0.001), dynamometric measurement of handgrip force (p < 0.001) (kg), clap push-ups (p < 0.001), standing long jump (p < 0.001), shuttle run (p < 0.001), sit-and-reach (p < 0.001), and tapping (p < 0.001). Furthermore, changes in special fitness were also demonstrated for the special kickboxing fitness test (SKFT) (p < 0.02), the total number of punches (p < 0.001), punching speed (p < 0.001), and hip turning speed (p < 0.001). There was also a correlation between characteristics of general fitness and special fitness (p < 0.001). Conclusions: The experimental training program based on the principles of CrossFit training had a positive effect on the general and special kickboxing physical fitness.

Effect of Gd3+ Substitution on Thermoelectric Power Factor of Paramagnetic Co2+-Doped Calcium Molybdato-Tungstates.

A series of Co2+-doped and Gd3+-co-doped calcium molybdato-tungstates, i.e., Ca1-3x-yCoyxGd2x(MoO4)1-3x(WO4)3x (CCGMWO), where 0 < x ≤ 0.2, y = 0.02 and represents vacancy, were successfully synthesized by high-temperature solid-state reaction method. XRD studies and diffuse reflectance UV-vis spectral analysis confirmed the formation of single, tetragonal scheelite-type phases with space group I41/a and a direct optical band gap above 3.5 eV. Magnetic and electrical measurements showed insulating behavior with n-type residual electrical conductivity, an almost perfect paramagnetic state with weak short-range ferromagnetic interactions, as well as an increase of spin contribution to the magnetic moment and an increase in the power factor with increasing gadolinium ions in the sample. Broadband dielectric spectroscopy measurements and dielectric analysis in the frequency representation showed a relatively high value of dielectric permittivity at low frequencies, characteristic of a space charge polarization and small values of both permittivity and loss tangent at higher frequencies.

Study of the Structure, Magnetic, Thermal and Electrical Characterisation of ZnCr2Se4: Ta Single Crystals Obtained by Chemical Vapour Transport.

The new series of single-crystalline chromium selenides, Ta-doped ZnCr2Se4, was synthesised by a chemical vapour transport method to determine the impact of a dopant on the structural and thermodynamic properties of the parent compound. We present comprehensive investigations of structural, electrical transport, magnetic, and specific heat properties. It was expected that a partial replacement of Cr ions by a more significant Ta one would lead to a change in direct magnetic interactions between Cr magnetic moments and result in a change in the magnetic ground state and electric transport properties of the ZnCr2-xTaxSe4 (x = 0.05, 0.06, 0.07, 0.08, 0.1, 0.12) system. We found that all the elements of the cubic system had a cubic spinel structure; however, the doping gain linearly increased the ZnCr2-xTaxSe4 unit cell volume. Doping with tantalum did not significantly change the semiconductor and magnetic properties of ZnCr2Se4. For all studied samples (0 ≤ x ≤ 0.12), an antiferromagnetic order (AFM) below TN~22 K was observed. However, a small amount of Ta significantly reduced the second critical field (Hc2) from 65 kOe for x = 0.0 (ZnCr2Se4 matrix) up to 42.2 kOe for x = 0.12, above which the spin helical system changed to ferromagnetic (FM). The Hc2 reduction can lead to strong competition among AFM and FM interactions and spin frustration, as the specific heat under magnetic fields H < Hc2 shows a strong field decrease in TN.

Relationships between Training Loads and Selected Blood Parameters in Professional Soccer Players during a 12-Day Sports Camp.

The main purpose of this study is to assess the relations between training loads and selected blood parameters in professional soccer players during a preseason sports camp. Fifteen professional soccer players (age: 24.3 ± 5.25 year; height: 182.6 ± 6.75 cm; weight: 76.4 ± 6.72 kg) participated in the 12-day training camp. All the training sessions and friendly games were accurately analyzed with a GPS system. Blood samples were taken from the players and analyzed before the camp (PRE), in the middle (MID), and one day after the camp (POST). Mean total distance covered by the players during the camp was 85,205 ± 2685 m, high-intensity running 12,454 ± 1873 m, and sprinting 639 ± 219 m. The highest aspartate transaminase (AST), lactate dehydrogenase (LDH), creatine kinase (CK), and C-reactive protein (CRP) values were observed after six days of the camp. The application of intensive training during a 12-day sports camp can be associated with chronic muscle pain with high activity of some blood enzymes (CK, AST) and a high concentration of myoglobin (Mb). During training camps longer than 10 days, it would be necessary to apply, every second or third day, one day of rest, and the training load should not exceed two units every day.

Reaction of the Organisms of Young Football Players to City Smog in the Sports Training.

The essence of a sports training includes not only developing the skills necessary in a chosen sport but also particular care about athlete's health. This issue should be taken into account especially in case of children and youth engaged in sporting activities. In the paper there are issues connected to the control of physical effort abilities in the sports training of young football players and the assessment of the reaction of the body to physical exercise in city smog conditions (the environment of the city of Kraków) and clean air conditions (the environment of the town of Glucholazy). This paper shows that, when assessing physical effort, one can consider not nly the results of physical tests but also the reaction of the body to a given physical load. One should remember that physical load depends not only on the methods used and the range of intensity, but also on the environmental conditions, like the quality of the air. Determining the reaction of the body to physical load (performance tests), taking into account the conditions in which the training takes place, prevents overloading and sets directions for rational sports training. The analysis of the results of the study leads to three main conclusions: (1) The planning of sports training has to consider not only the methods and means of the training but also environmental factors (air pollution); (2) Physical effort in smog conditions should be done with the use of antismog face masks; (3) The arrangement of sports training (particularly for youth) should strictly take into account the environment in which the training takes place.

Dipole Relaxation in Semiconducting Zn2-xMgxInV3O11 Materials (Where x = 0.0, 0.4, 1.0, 1.6, and 2.0).

This paper reports on the electrical and broadband dielectric spectroscopy studies of Zn2-xMgxInV3O11 materials (where x = 0.0, 0.4, 1.0, 1.6, 2.0) synthesized using a solid-state reaction method. These studies showed n-type semiconducting properties with activation energies of 0.147-0.52 eV in the temperature range of 250-400 K, symmetric and linear I-V characteristics, both at 300 and 400 K, with a stronger carrier emission for the matrix and much less for the remaining samples, as well as the dipole relaxation, which was the slowest for the sample with x = 0.0 (matrix) and was faster for Mg-doped samples with x > 0.0. The faster the dipole relaxation, the greater the accumulation of electric charge. These effects were analyzed within a framework of the DC conductivity and the Cole-Cole fit function, including the solid-state density and porosity of the sample. The resistivity vs. temperature dependence was well fitted using the parallel resistor model. Our ab initio calculations also show that the bandgap increased with the Mg content.

Influence of selected auxiliary substances on some physicochemical properties of solid dispersions containing magnesium salts.

In this survey magnesium sails in the form of solid dispersions were studied to examine the interaction of the drug and lecithin or Tego Betain L-7. The results of thermal analysis of solid dispersions containing magnesium adipate Mg[Adip] and compounds of this salt with glycine substituent, and the partition coefficient (logP) of this salts applied for solid dispersion, have been presented in this paper. Lecithin (45% phosphatidylcholine) or Tego Betain L-7 (30% solution of amide betaine) have been added to magnesium salts to obtain a solid dispersion. The influence of auxiliary substances: Tego Betain L-7 and lecithin on physicochemical properties of the examined preparations has been assessed. The results of thermal analysis (DTA, DSC, TG) of magnesium complexes indicated their good thermal resistance up to the temperature of 375 K.