RESUMO
Effectively utilizing deep red to near-infrared (DR-NIR) phosphors to achieve the optimal performance of NIR phosphor-converted white LEDs (DR-NIR pc-wLEDs) is currently a research hotspot. In this study, an optical model of DR-NIR pc-wLEDs with virtual multilayer fluorescent films was established based on the Monte Carlo ray-tracing method. Different gradient distributions of the particles were assigned within the fluorescent film to explore their impact on the optical performance of pc-LEDs. The results show that, for the case with single-type particles, distributing more DR-NIR particles far from the blue LED chip increased the overall radiant power. The distribution of more DR-NIR particles near the chip increased the conversion ratio from blue to DR-NIR light. The ratio of the 707 nm fluorescence emission intensity to the 450 nm excitation light intensity increased from 1:0.51 to 1:0.28. For multiple-type particles, changes in the gradient distribution resulted in dual-nature changes, leading to a deterioration in the color rendering index and an increase in the correlated color temperature, while also improving the DR-NIR band ratio. The reabsorption caused by the partial overlap between the excitation band of the DR-NIR particles and the emission band of the other particles enhanced the radiant power at 707 nm. Distributing DR-NIR phosphor particles closer to the chip effectively amplified this effect. The proposed model and its results provide a solution for the forward design of particle distributions in fluorescent films to improve the luminous performance of DR-NIR pc-wLEDs.
RESUMO
Slot die coating is a widely used technique for the production of high accuracy films. One of the main challenges in slot die coating processes is determining the optimal range of operating parameters to prevent defects, such as bubbles, in high-viscosity films. In this study, both simulation and experimental methods were used to investigate the changes in the upstream meniscus under various coating parameters. Two types of air entrainment processes were considered, dominated by fluid inertia and viscous force. The formation of anticlockwise and clockwise vortex flows near the bottom of the upstream meniscus was found to alter the apparent dynamic contact angle of the upstream meniscus, leading to fluctuations in the apparent dynamic contact angle within a range of 70°-75° to 135°-140°. These fluctuations eventually resulted in air entrainment. This research is important for improving the quality and efficiency of slot die coating processes.
RESUMO
The vacuum method is a widely adopted technique for eliminating bubbles from polymers containing particles. To investigate the influence of bubbles on the behavior of particles and the concentration distribution in high-viscosity liquids under negative pressure, experimental and numerical methods have been employed. The experimental findings demonstrated a positive correlation between the diameter and rising velocity of bubbles and the negative pressure. As the negative pressure increased from - 10 kPa to - 50 kPa, the position of the region where the particles were concentrated in the vertical direction was elevated. Furthermore, when the negative pressure exceeded - 50 kPa, the particle distribution became sparse and layered locally. The Lattice Boltzmann method (LBM) integrated with the discrete phase model (DPM) was utilized to investigate the phenomenon, and the outcomes revealed that rising bubbles have an inhibitory effect on particle sedimentation, and the extent of inhibition was determined by the negative pressure. In addition, vortexes generated by differences in the rising velocity between bubbles resulted in a particle distribution that was sparse and layered locally. This research provides a reference for achieving desired particle distributions using a vacuum defoaming approach and should be further studied to extend its applicability to suspensions containing particles with different viscosities.
