Bayesian optimization of nanophotonic electromagnetic shielding with very high visible transparency.

Transparent electromagnetic interference (EMI) shielding is needed in many optoelectronic applications to protect electronic devices from surrounding radiation while allowing for high visible light transmission. However, very high transmission (over 92.5%), high EMI shielding efficiency (over 30 dB) structures have yet to be achieved in the literature. Bayesian optimization is used to optimize different nanophotonic structures for high EMI shielding efficiency (SE) and high visible light transmission (T¯ v i s ). Below 90% average visible light transmission, sandwich structures consisting of high index dielectric/silver/high index dielectric films are determined to be optimal, where they are able to achieve 43.1 dB SE and 90.0% T¯ v i s . The high index of refraction dielectric layers reduce absorption losses in the silver and can be engineered to provide for antireflection through destructive interference. However, for optimal EMI shielding with T¯ v i s above 90%, the reflection losses at the air/dielectric interfaces need to be further reduced. Optimized double sided nanocone sandwich structures are determined to be best where they can achieve 41.2 dB SE and 90.8% T¯ v i s as well as 35.6 dB SE and 95.1% T¯ v i s . K-means clustering is utilized to show the performance of characteristic near-Pareto optimal structures. Double sided nanocone structures are shown to exhibit omnidirectional visible transmission with SE = 35.6 dB and over 85% T¯ v i s at incidence angles of 70 ∘.

Reactive silver inks for antiviral, repellent medical textiles with ultrasonic bleach washing durability compared to silver nanoparticles.

Medical textiles are subject to particularly harsh disinfection procedures in healthcare settings where exposure risks are high. This work demonstrates a fabric treatment consisting of a reactive silver ink and low surface energy PDMS polymer that provides for superhydrophobicity and antiviral properties against enveloped herpes simplex virus stocks even after extended ultrasonic bleach washing. The antiviral properties of reactive silver ink has not been previously reported or compared with silver nanoparticles. The fabric treatment exhibits high static contact angles and low contact angle hysteresis with water, even after 300 minutes of ultrasonic bleach washing. Similarly, after this bleach washing treatment, the fabric treatment shows reductions of infectious virus quantities by about 2 logs compared to controls for enveloped viruses. The use of silver ink provides for better antiviral efficacy and durability compared to silver nanoparticles due to the use of reactive ionic silver, which demonstrates more conformal coverage of fabric microfibers and better adhesion. This study provides insights for improving the wash durability of antiviral silver fabric treatments and demonstrates a bleach wash durable, repellent antiviral treatment for reusable, functional personal protective equipment applications.

Challenges and Prospects of Bio-Inspired and Multifunctional Transparent Substrates and Barrier Layers for Optoelectronics.

Bio-inspiration and advances in micro/nanomanufacturing processes have enabled the design and fabrication of micro/nanostructures on optoelectronic substrates and barrier layers to create a variety of functionalities. In this review article, we summarize research progress in multifunctional transparent substrates and barrier layers while discussing future challenges and prospects. We discuss different optoelectronic device configurations, sources of bio-inspiration, photon management properties, wetting properties, multifunctionality, functionality durability, and device durability, as well as choice of materials for optoelectronic substrates and barrier layers. These engineered surfaces may be used for various optoelectronic devices such as touch panels, solar modules, displays, and mobile devices in traditional rigid forms as well as emerging flexible versions.

Superhemophobic and Antivirofouling Coating for Mechanically Durable and Wash-Stable Medical Textiles.

Medical textiles have a need for repellency to body fluids such as blood, urine, or sweat that may contain infectious vectors that contaminate surfaces and spread to other individuals. Similarly, viral repellency has yet to be demonstrated and long-term mechanical durability is a major challenge. In this work, we demonstrate a simple, durable, and scalable coating on nonwoven polypropylene textile that is both superhemophobic and antivirofouling. The treatment consists of polytetrafluoroethylene (PTFE) nanoparticles in a solvent thermally sintered to polypropylene (PP) microfibers, which creates a robust, low-surface-energy, multilayer, and multilength scale rough surface. The treated textiles demonstrate a static contact angle of 158.3 ± 2.6° and hysteresis of 4.7 ± 1.7° for fetal bovine serum and reduce serum protein adhesion by 89.7 ± 7.3% (0.99 log). The coated textiles reduce the attachment of adenovirus type 4 and 7a virions by 99.2 ± 0.2% and 97.6 ± 0.1% (2.10 and 1.62 log), respectively, compared to noncoated controls. The treated textiles provide these repellencies by maintaining a Cassie-Baxter state of wetting where the surface area in contact with liquids is reduced by an estimated 350 times (2.54 log) compared to control textiles. Moreover, the treated textiles exhibit unprecedented mechanical durability, maintaining their liquid, protein, and viral repellency after extensive and harsh abrasion and washing. The multilayer, multilength scale roughness provides for mechanical durability through self-similarity, and the samples have high-pressure stability with a breakthrough pressure of about 255 kPa. These properties highlight the potential of durable, repellent coatings for medical gowning, scrubs, or other hygiene textile applications.