Optical detection of a single rare-earth ion in a crystal.

Rare-earth-doped laser materials show strong prospects for quantum information storage and processing, as well as for biological imaging, due to their high-Q 4f↔4f optical transitions. However, the inability to optically detect single rare-earth dopants has prevented these materials from reaching their full potential. Here we detect a single photostable Pr(3+) ion in yttrium aluminium garnet nanocrystals with high contrast photon antibunching by using optical upconversion of the excited state population of the 4f↔4f optical transition into ultraviolet fluorescence. We also demonstrate on-demand creation of Pr(3+) ions in a bulk yttrium aluminium garnet crystal by patterned ion implantation. Finally, we show generation of local nanophotonic structures and cell death due to photochemical effects caused by upconverted ultraviolet fluorescence of praseodymium-doped yttrium aluminium garnet in the surrounding environment. Our study demonstrates versatile use of rare-earth atomic-size ultraviolet emitters for nanoengineering and biotechnological applications.

Quantum entanglement between an optical photon and a solid-state spin qubit.

Quantum entanglement is among the most fascinating aspects of quantum theory. Entangled optical photons are now widely used for fundamental tests of quantum mechanics and applications such as quantum cryptography. Several recent experiments demonstrated entanglement of optical photons with trapped ions, atoms and atomic ensembles, which are then used to connect remote long-term memory nodes in distributed quantum networks. Here we realize quantum entanglement between the polarization of a single optical photon and a solid-state qubit associated with the single electronic spin of a nitrogen vacancy centre in diamond. Our experimental entanglement verification uses the quantum eraser technique, and demonstrates that a high degree of control over interactions between a solid-state qubit and the quantum light field can be achieved. The reported entanglement source can be used in studies of fundamental quantum phenomena and provides a key building block for the solid-state realization of quantum optical networks.

Repetitive readout of a single electronic spin via quantum logic with nuclear spin ancillae.

Robust measurement of single quantum bits plays a key role in the realization of quantum computation and communication as well as in quantum metrology and sensing. We have implemented a method for the improved readout of single electronic spin qubits in solid-state systems. The method makes use of quantum logic operations on a system consisting of a single electronic spin and several proximal nuclear spin ancillae in order to repetitively readout the state of the electronic spin. Using coherent manipulation of a single nitrogen vacancy center in room-temperature diamond, full quantum control of an electronic-nuclear system consisting of up to three spins was achieved. We took advantage of a single nuclear-spin memory in order to obtain a 10-fold enhancement in the signal amplitude of the electronic spin readout. We also present a two-level, concatenated procedure to improve the readout by use of a pair of nuclear spin ancillae, an important step toward the realization of robust quantum information processors using electronic- and nuclear-spin qubits. Our technique can be used to improve the sensitivity and speed of spin-based nanoscale diamond magnetometers.

Fast-light in a photorefractive crystal for gravitational wave detection.

We demonstrate superluminal light propagation using two frequency multiplexed pump beams to produce a gain doublet in a photorefractive crystal of Ce:BaTiO(3). The two gain lines are obtained by two-wave mixing between a probe field and two individual pump fields. The angular frequencies of the pumps are symmetrically tuned from the frequency of the probe. The frequency difference between the pumps corresponds to the separation of the two gain lines; as it increases, the crystal gradually converts from normal dispersion without detuning to an anomalously dispersive medium. The time advance is measured as 0.28 sec for a pulse propagating through a medium with a 2 Hz gain separation, compared to the same pulse propagating through empty space. We also demonstrate directly anomalous dispersion profile using a modified experimental configuration. Finally, we discuss how anomalous dispersion produced this way in a faster photorefractive crystal (such as SPS: Sn(2)P(2)S(6)) could be employed to enhance the sensitivity-bandwidth product of a LIGO type gravitational wave detector augmented by a White Light Cavity.

Temporal coherence of photons emitted by single nitrogen-vacancy defect centers in diamond using optical Rabi-oscillations.

Photon interference among distant quantum emitters is a promising method to generate large scale quantum networks. Interference is best achieved when photons show long coherence times. For the nitrogen-vacancy defect center in diamond we measure the coherence times of photons via optically induced Rabi oscillations. Experiments reveal a close to Fourier-transform (i.e., lifetime) limited width of photons emitted even when averaged over minutes. The projected contrast of two-photon interference (0.8) is high enough to envisage applications in quantum information processing. We report 12 and 7.8 ns excited state lifetimes depending on the spin state of the defect.

Generation of single optical plasmons in metallic nanowires coupled to quantum dots.

Control over the interaction between single photons and individual optical emitters is an outstanding problem in quantum science and engineering. It is of interest for ultimate control over light quanta, as well as for potential applications such as efficient photon collection, single-photon switching and transistors, and long-range optical coupling of quantum bits. Recently, substantial advances have been made towards these goals, based on modifying photon fields around an emitter using high-finesse optical cavities. Here we demonstrate a cavity-free, broadband approach for engineering photon-emitter interactions via subwavelength confinement of optical fields near metallic nanostructures. When a single CdSe quantum dot is optically excited in close proximity to a silver nanowire, emission from the quantum dot couples directly to guided surface plasmons in the nanowire, causing the wire's ends to light up. Non-classical photon correlations between the emission from the quantum dot and the ends of the nanowire demonstrate that the latter stems from the generation of single, quantized plasmons. Results from a large number of devices show that efficient coupling is accompanied by more than 2.5-fold enhancement of the quantum dot spontaneous emission, in good agreement with theoretical predictions.

Quantum register based on individual electronic and nuclear spin qubits in diamond.

The key challenge in experimental quantum information science is to identify isolated quantum mechanical systems with long coherence times that can be manipulated and coupled together in a scalable fashion. We describe the coherent manipulation of an individual electron spin and nearby individual nuclear spins to create a controllable quantum register. Using optical and microwave radiation to control an electron spin associated with the nitrogen vacancy (NV) color center in diamond, we demonstrated robust initialization of electron and nuclear spin quantum bits (qubits) and transfer of arbitrary quantum states between them at room temperature. Moreover, nuclear spin qubits could be well isolated from the electron spin, even during optical polarization and measurement of the electronic state. Finally, coherent interactions between individual nuclear spin qubits were observed and their excellent coherence properties were demonstrated. These registers can be used as a basis for scalable, optically coupled quantum information systems.

Quantum optics with surface plasmons.

We describe a technique that enables strong, coherent coupling between individual optical emitters and guided plasmon excitations in conducting nanostructures at optical frequencies. We show that under realistic conditions optical emission can be almost entirely directed into the plasmon modes. As an example, we describe an application of this technique involving efficient generation of single photons on demand, in which the plasmon is efficiently outcoupled to a dielectric waveguide.

Coherent dynamics of coupled electron and nuclear spin qubits in diamond.

Understanding and controlling the complex environment of solid-state quantum bits is a central challenge in spintronics and quantum information science. Coherent manipulation of an individual electron spin associated with a nitrogen-vacancy center in diamond was used to gain insight into its local environment. We show that this environment is effectively separated into a set of individual proximal 13C nuclear spins, which are coupled coherently to the electron spin, and the remainder of the 13C nuclear spins, which cause the loss of coherence. The proximal nuclear spins can be addressed and coupled individually because of quantum back-action from the electron, which modifies their energy levels and magnetic moments, effectively distinguishing them from the rest of the nuclei. These results open the door to coherent manipulation of individual isolated nuclear spins in a solid-state environment even at room temperature.

Quantum lithography with classical light.

We show how to achieve subwavelength diffraction and imaging with classical light, previously thought to require quantum fields. By correlating wave vector and frequency in a narrow band, multiphoton detection process that uses Doppleron-type resonances, we show how to achieve arbitrary focal and image plane patterning with classical laser light at submultiples of the Rayleigh limit, with high efficiency, visibility, and spatial coherence. A frequency-selective measurement process thus allows one to simulate, semiclassically, the path-number correlations that distinguish a quantum entangled field.

Demonstration of a multiwave coherent holographic beam combiner in a polymeric substrate.

We demonstrate an efficient coherent holographic beam combiner (CHBC) that uses angle multiplexing of gratings in a thick polymeric substrate. Our experimental results compare well with the theoretical model based on the coupled-wave theory of multiwave mixing in a passive medium. A CHBC of this type may prove useful in producing a high-power laser by combining amplified beams produced by splitting a master oscillator. Furthermore, the ability to angle multiplex a large number of beams enables a CHBC to be used in multiple-beam interferometry applications as a high-precision surface sensor.

Demonstration of a simple technique for determining the M/# of a holographic substrate by use of a single exposure.

We propose and demonstrate a simple technique for determining the M/# parameter of a holographic recording material. In this method, divergent object and reference beams are used to produce a spatially varying index modulation. One can analyze the resultant diffraction pattern to find M/# by using only a single grating; existing techniques require many gratings.

Observation of ultraslow and stored light pulses in a solid.

We report ultraslow group velocities of light in an optically dense crystal of Pr doped Y2SiO5. Light speeds as slow as 45 m/s were observed, corresponding to a group delay of 66 micros. Deceleration and "stopping" or trapping of the light pulse was also observed. These reductions of the group velocity are accomplished by using a sharp spectral feature in absorption and dispersion that is produced by resonance Raman excitation of a ground-state spin coherence.

Long distance, unconditional teleportation of atomic states via complete Bell state measurements.

We propose a scheme for creating and storing quantum entanglement over long distances. Optical cavities that store this long-distance entanglement in atoms could then function as nodes of a quantum network, in which quantum information is teleported from cavity to cavity. The teleportation is conducted unconditionally via measurements of all four Bell states, using a novel method of sequential elimination.

Raman-excited spin coherences in nitrogen-vacancy color centers in diamond.

Raman-excited spin coherences were experimentally observed in nitrogen-vacancy (N-V) diamond color centers by means of nondegenerate four-wave mixing and electromagnetically induced transparency. The maximal absorption suppression was found to be 17%, which corresponds to 70% of what is possible given the random geometric orientation of the N-V center in diamond. In the context of quantum computing in solids, this level of transparency represents efficient preparation of quantum bits, as well as the ability to perform arbitrary single-quantum-bit rotations.

Enhancement of four-wave mixing and line narrowing by use of quantum coherence in an optically dense double-? solid.

We have demonstrated enhanced nondegenerate four-wave mixing by use of a resonant probe in a double- ? system consisting of an optically dense spectral hole-burning solid. The observed probe diffraction efficiency is ~16% in amplitude at 6 K, which is higher than for an off-resonant probe in a ? -type scheme. We have also observed two-photon coherence line narrowing, which has potential application to high-resolution spectroscopy.

Enhanced nondegenerate four-wave mixing owing to electromagnetically induced transparency in a spectral hole-burning crystal.

We have demonstrated electromagnetically induced transparency (EIT) in an inhomogeneously broadened spectral hole-burning system of Pr(3+)-doped Y(2)SiO(5) at 6 K. We have also shown enhancement of four-wave mixing under conditions of reduced absorption. This demonstration opens the possibilities of pursuing EIT applications such as high-resolution optical image processing and optical data storage in solids.

Turbulence-aberration correction with high-speed high-gain optical phase conjugation in sodium vapor.

Optical aberrations that are due to high-speed turbulence in the aero-optical regime are corrected with optical phase conjugation based on coherent population trapping in sodium vapor. Experimental measurements of an unheated, forced helium jet in air have demonstrated aberration correction by a factor of 7.8 at a forcing frequency of 18kHz with an optical power gain of 32.

Distortion-free gain and noise correlation in sodium vapor with four-wave mixing and coherent population trapping.

We observed optical gain as great as 30 with nearly distortion-free beam propagation in optically dense sodium vapor, using four-wave mixing. Moreover, 15-dB classical noise correlations were seen in the amplified probe and conjugate beams. To achieve this performance in such a strongly absorbing medium, one must suppress unwanted absorption and self-focusing effects. This is accomplished with coherent population trapping.

Efficient and fast optical phase conjugation by use of two-photon-induced gratings in the orientation of angular momentum.

Optical phase conjugation (OPC) is of interest for many applications. The generation of squeezed light, phase-conjugate mirrors, optical correlation, and turbulence correction would all benefit from improved OPC performance. Using Zeeman sublevels and cross-circularly polarized light in rubidium vapor, we demonstrate an OPC process that uses very low power (30 mW) but is still very fast (60 ns) and efficient (gain of 20). This process is generic enough to be applicable to almost any resonant medium.