Green approach for the fabrication of a ternary nanocatalyst (Ag-ZnONPs@Cy) for visible light-induced photocatalytic reduction of nitroarenes to aminoarenes.

In recent times, the incorporation of metal oxide nanoparticles with organic dyes has piqued the interest of numerous researchers due to their diverse applications under visible light instead of UV radiation. This investigation employed a three-step methodology to fabricate cyanidin-sensitized silver-doped zinc oxide nanoparticles (Ag-ZnO@Cy). Initially, cyanidin dye was extracted from fresh black mulberry fruit, followed by the eco-friendly synthesis of Ag-ZnO nanoparticles (Ag-ZnONPs). The successful integration of the prepared cyanidin dye with Ag-ZnONPs was achieved through a straightforward, environmentally benign, and cost-efficient procedure. The resultant ternary composite underwent comprehensive characterization and confirmation utilizing various techniques, such as SEM, FT-IR, EDX, DRS, elemental mapping, and XRD. The experimental results for Ag-ZnONPs@Cy demonstrated that the nanocrystalline wurtzite exhibited spherical shapes with an average crystal size of 27.42 nm. Moreover, the photocatalytic activity of the synthesized Ag-ZnONPs@Cy was meticulously investigated under blue LED light irradiation. This inquiry encompassed examinations of catalyst amount, regeneration, stability, reusability, and the influence of light source on the hydrogenation of nitroarenes to the corresponding aminoarenes. The findings shed light on the potential of this composite for diverse photocatalytic applications.

Emerging developments in dye-sensitized metal oxide photocatalysis: exploring the design, mechanisms, and organic synthesis applications.

In the present day, the incorporation of environmentally conscious practices in the realm of photocatalysis holds a prominent position within the domain of organic synthesis. The imperative to tackle environmental issues linked to catalysts that cannot be recycled, generation of waste, byproducts, and challenges in achieving reaction selectivity during organic synthesis are more crucial than ever. One potential solution involves the integration of recyclable nanomaterials with light as a catalyst, offering the possibility of achieving sustainable and atom-efficient transformations in organic synthesis. Metal oxide nanoparticles exhibit activation capabilities under UV light, constituting a small percentage (4-8%) of sunlight. However, this method lacks sufficient environmental friendliness, and the issue of electron-hole recombination poses a significant hurdle. To tackle these challenges, multiple approaches have been proposed. This comprehensive review article focuses on the efficacy of dyes in enhancing the capabilities of heterogeneous photocatalysts, offering a promising avenue to overcome the constraints associated with metal oxides in their role as photocatalysts. The article delves into the intricate design aspects of dye-sensitized photocatalysts and sheds light on their mechanisms in facilitating organic transformations.

Green nanocomposite: fabrication, characterization, and photocatalytic application of vitamin C adduct-conjugated ZnO nanoparticles.

Recently, the conjugation of metal oxide nanoparticles with organic moieties has attracted the attention of many researchers for various applications. In this research, the green and biodegradable vitamin C was employed in a facile and inexpensive procedure to synthesize the vitamin C adduct (3), which was then blended with green ZnONPs to fabricate a new composite category (ZnONPs@vitamin C adduct). The morphology and structural composition of the prepared ZnONPs and their composites were confirmed by several techniques: Fourier-transform infrared (FT-IR) spectroscopy, field-emission scanning electron microscopy (FE-SEM), UV-vis differential reflectance spectroscopy (DRS), energy dispersive X-ray (EDX) analysis, elemental mapping, X-ray diffraction (XRD) analysis, photoluminescence (PL) spectroscopy, and zeta potential measurements. The structural composition and conjugation strategies between the ZnONPs and vitamin C adduct were revealed by FT-IR spectroscopy. The experimental results for the ZnONPs showed that they possessed a nanocrystalline wurtzite structure with quasi-spherical particles with a polydisperse size ranging from 23 to 50 nm, while the particle size appeared greater in the FE-SEM images (band gap energy of 3.22 eV); after loading with the l-ascorbic acid adduct (3), the band gap energy dropped to 3.06 eV. Later, under solar light irradiation, the photocatalytic activities of both the synthesized ZnONPs@vitamin C adduct (4) and ZnONPs, including the stability, regeneration and reusability, catalyst amount, initial dye concentration, pH effect, and light source studies, were investigated in detail in the degradation of Congo red dye (CR). Furthermore, an extensive comparison between the fabricated ZnONPs, composite (4), and ZnONPs from previous studies was performed to gain insights to commercialize the catalyst (4). Under optimum conditions, the photodegradation of CR after 180 min was 54% for ZnONPs and 95% for the ZnONPs@l-ascorbic acid adduct. Moreover, the PL study confirmed the photocatalytic enhancement of the ZnONPs. The photocatalytic degradation fate was determined by LC-MS spectrometry.