Accessibility of Motion Capture as a Tool for Sports Performance Enhancement for Beginner and Intermediate Cricket Players.

Motion Capture (MoCap) has become an integral tool in fields such as sports, medicine, and the entertainment industry. The cost of deploying high-end equipment and the lack of expertise and knowledge limit the usage of MoCap from its full potential, especially at beginner and intermediate levels of sports coaching. The challenges faced while developing affordable MoCap systems for such levels have been discussed in order to initiate an easily accessible system with minimal resources.

Investigation of Pozzolanic Properties of Sugarcane Bagasse Ash for Commercial Applications.

The ideal climatic and environmental conditions for sugarcane cultivation are present all year round in the tropical island of Sri Lanka. Given the annual sugar consumption of the nation, a significant amount of sugarcane bagasse ash (SCBA), a by-product with no intended commercial use but potential environmental and health risks, is produced. Numerous studies have been conducted recently to assess the viability of using SCBA as a pozzolanic material in structural applications. The purpose of this study is to evaluate the microstructure of SCBA samples from three sugar manufacturing facilities in Sri Lanka to identify the pozzolanic capacities. Several quantitative and qualitative characterization techniques have been utilized for the investigations. While maintaining the American Society for Testing and Materials (ASTM) 618 specification as the standard for pozzolanic properties, a comparative investigation of the attributes of samples from each location was conducted. Beyond that, the relationship between the SCBA generation process parameters and their impact on the properties of SCBA have been identified. Finally, the SCBA source of the Pelwatte unit has been identified as the ideal source for the pozzolanic material from the three locations, considering quality and the extent of additional treatments required before use. Other prospective areas of research on SCBA and its potential applications have been recognized.

Excited-State Dynamics of Room-Temperature Phosphorescent Organic Materials Based on Monobenzil and Bisbenzil Frameworks.

Room-temperature phosphorescent (RTP) materials have been attracting tremendous interest, owing to their unique material characteristics and potential applications for state-of-the-art optoelectronic devices. Recently, we reported the synthesis and fundamental photophysical properties of new RTP materials based on benzil, i.e., fluorinated monobenzil derivative and fluorinated and non-fluorinated bisbenzil derivative analogues [Yamada, S. et al., Beilstein J. Org. Chem. 2020, 16, 1154-1162.]. To deeply understand their RTP properties, we investigated the excited-state dynamics and photostability of the derivatives by means of time-resolved and steady-state photoluminescence spectroscopies. For these derivatives, clear RTP emissions with lifetimes on the microsecond timescale were identified. Among them, the monobenzil derivative was found to be the most efficient RTP material, showing both the longest lifetime and highest amplitude RTP emission. Time-resolved photoluminescence spectra, measured at 77 K, and density functional theory calculations revealed the existence of a second excited triplet state in the vicinity of the first excited singlet state for the monobenzil derivative, indicative of the presence of a fast intersystem crossing pathway. The correlation between the excited state dynamics, emission properties, and conformational flexibility of the three derivatives is discussed.

Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules.

Pure organic phosphorescent molecules are attractive alternatives to transition-metal-complex-based phosphores for biomedical and technological applications owing to their abundance and nontoxicity. This article discloses the design, synthesis, and photophysical properties of fluorinated benzil and bisbenzil derivatives as potential pure organic room-temperature phosphorescent molecules. These compounds were separately converted from the corresponding fluorinated bistolanes via PdCl2-catalyzed oxidation by dimethyl sulfoxide, while nonfluorinated bistolane provided the corresponding bisbenzil derivatives exclusively in a similar manner. Intensive investigations of the photophysical properties of the benzil and bisbenzil derivatives in toluene at 25 °C showed both fluorescence with a photoluminescence (PL) band at a maximum wavelength (λPL) of around 400 nm and phosphorescence with a PL band at a λPL of around 560 nm. Interestingly, intersystem crossing effectively caused fluorinated benzils to emit phosphorescence, which may arise from immediate spin-orbit coupling involving the 1(n, π)→3(π, π) transition, unlike the case of fluorinated or nonfluorinated bisbenzil analogues. These findings offer a useful guide for developing novel pure organic room-temperature phosphorescent materials.

Selective adsorption of atomic hydrogen on a h-BN thin film.

The adsorption of atomic hydrogen on hexagonal boron nitride (h-BN) is studied using two element-specific spectroscopies, i.e., near-edge x-ray absorption fine structure (NEXAFS) spectroscopy and x-ray photoelectron spectroscopy (XPS). B K-edge NEXAFS spectra show a clear change in the energy region of the π* band before and after reaction with atomic deuterium. On the other hand, N K-edge NEXAFS spectra show only a little change. B 1s XPS spectra show a distinct component at the low binding energy side of a main component, while N 1s XPS spectra show peak broadening at the high binding energy side. These experimental results are analyzed by the discrete variational Xα method with a core-hole effect and are explained by a model in which hydrogen atoms are preferentially adsorbed on the B sites of h-BN. Based on the experimental and theoretical results, we propose a site-selective property of BN material on adsorption of atomic hydrogen.