Unravelling the signatures of submarine groundwater discharge and seawater intrusion along the coastal plains of Odisha, India: a multi-proxy approach.

Submarine Groundwater Discharge (SGD) and Seawater Intrusion (SWI) are two contrary hydrological processes that occur across the land-sea continuum and understanding their nature is essential for management and development of coastal groundwater resource. Present study has attempted to demarcate probable zones of SGD and SWI along highly populated Odisha coastal plains which is water stressed due to indiscriminate-exploitation of groundwater leading to salinization and fresh groundwater loss from the alluvial aquifers. A multi-proxy investigation approach including decadal groundwater level dynamics, LANDSAT derived sea surface temperature (SST) anomalies and in-situ physicochemical analysis (pH, EC, TDS, salinity and temperature) of porewater, groundwater and seawater were used to locate the SGD and SWI sites. A total of 340 samples for four seasons (85 samples i.e., 30 porewater, 30 seawater and 25 groundwater in each season) were collected and their in-situ parameters were measured at every 1-2 km gap along ~ 145 km coastline of central Odisha (excluding the estuarine region). Considering high groundwater EC values (> 3000 µS/cm), three probable SWI and low porewater salinities (< 32 ppt in pre- and < 25 ppt in post-monsoons), four probable SGD zones were identified. The identified zones were validated with observed high positive hydraulic gradient (> 10 m) at SGD and negative hydraulic gradient (< 0 m) at SWI sites along with anomalous SST (colder in pre- and warmer in post-monsoon) near probable SGD locations. This study is first of its kind along the Odisha coast and may act as initial basis for subsequent investigations on fresh-saline interaction along the coastal plains where environmental integrity supports the livelihood of coastal communities and the ecosystem.

Impacts of climate change and coastal salinization on the environmental risk of heavy metal contamination along the odisha coast, India.

Climate change-mediated rise in sea level and storm surges, along with indiscriminate exploitation of groundwater along populous coastal regions have led to seawater intrusion. Studies on groundwater salinization and heavy metal contamination trends are limited. Present study investigated the heavy metal contamination, associated risks and provided initial information on the impacts of groundwater salinization on heavy metals along the coastal plains of Odisha, India. Total 50 groundwater samples (25 each in post- and pre-monsoon) were collected and analysed. Concentrations of Fe (44%), Mn (44%), As (4%) and Al (4%) in post-monsoon and Fe (32%), Mn (32%), As (4%), B (8%) and Ni (16%) in pre-monsoon exceeded Bureau of Indian Standards (BIS) drinking water limits. High concentrations of heavy metals (Fe, Sr, Mn, B, Ba, Li, Ni and Co) and high EC (>3000 µS/cm) indicated that the groundwater-seawater mixing process has enhanced the leaching and ion exchange of metallic ions in central part of the study area. Multivariate statistical analysis suggested leaching process, seawater intrusion and agricultural practices as the main heavy metal sources in the groundwater. 4% of samples in post- and 16% in pre-monsoon represented high heavy metal pollution index (HPI). Pollution indices indicated the central and south-central regions are highly polluted due to saline water intrusion and high agricultural activities. Ecological risks in the groundwater systems found low (ERI <110) in both seasons. Children population found more susceptible to health risks than adults. Hazard index (HI > 1) has shown significant non-carcinogenic risks where Fe, Mn, As, B, Li and Co are the potential contributors. Incremental lifetime cancer risk (ILCR >1.0E-03) has suggested high carcinogenic risks, where As and Ni are the major contributors. The study concluded that groundwater salinization could increase the heavy metal content and associated risks. This would help policymakers to take appropriate measures for sustainable coastal groundwater management.