Microwave-Assisted Synthesis of SnO2@ZnIn2S4 Composites for Highly Efficient Photocatalytic Hydrogen Evolution.

This research successfully synthesized SnO2@ZnIn2S4 composites for photocatalytic tap water splitting using a rapid two-step microwave-assisted synthesis method. This study investigated the impact of incorporating a fixed quantity of SnO2 nanoparticles and combining them with various materials to form composites, aiming to enhance photocatalytic hydrogen production. Additionally, different weights of SnO2 nanoparticles were added to the ZnIn2S4 reaction precursor to prepare SnO2@ZnIn2S4 composites for photocatalytic hydrogen production. Notably, the photocatalytic efficiency of SnO2@ZnIn2S4 composites is substantially higher than that of pure SnO2 nanoparticles and ZnIn2S4 nanosheets: 17.9-fold and 6.3-fold, respectively. The enhancement is credited to the successful use of visible light and the facilitation of electron transfer across the heterojunction, leading to the efficient dissociation of electron-hole pairs. Additionally, evaluations of recyclability demonstrated the remarkable longevity of SnO2@ZnIn2S4 composites, maintaining high levels of photocatalytic hydrogen production over eight cycles without significant efficiency loss, indicating their impressive durability. This investigation presents a promising strategy for crafting and producing environmentally sustainable SnO2@ZnIn2S4 composites with prospective implementations in photocatalytic hydrogen generation.

Co-digestion approach for enhancement of biogas production by mixture of untreated napier grass and industrial hydrolyzed food waste.

The co-digestion of untreated Napier grass (NG) and industrial hydrolyzed food waste (FW) was carried out in the batch reactor to investigate the effect of substrate ratios on biogas production performance. Two-stage anaerobic digestion was performed with an initial substrate concentration of 5 g VSadded/L and a Food to Microorganism Ratio (F/M) of 0.84. The 1:1 ratio of the NG and FW showed the optimum performances on biogas production yield with a value of 1,161.33 mL/g VSadded after 60 days of digestion. This was followed by the data on methane yield and concentration were 614.37 mL/g VSadded and 67.29%, respectively. The results were similar to the simulation results using a modified Gompertz model, which had a higher potential methane production and maximum production rate, as well as a shorter lag phase and a coefficient of determination of 0.9945. These findings indicated that the co-digestion of Napier grass and hydrolyzed food waste can enhance biogas production in two-stage anaerobic digestion.