Macromolecular sensing motors from conducting polymers: Polyaniline/methylcellulose composites as stable current sensing supercapacitors.

Sensing motors and supercapacitors are pivotal in empowering smart systems, honing energy management, and facilitating the seamless integration of responsive electronics. Harnessing the electrochemistry of methylcellulose-polyaniline (MC/PANI) composites, this research delves into their potential applications as reactive current sensing supercapacitors with single connectivity. The electrochemical traits of pristine polyaniline (PANI) and MC/PANI composites were analyzed and assessed for their potential applications in sensors and energy storage devices. With a specific capacitance of 300Fg-1, the MC/PANI_B3 composite-based device retained 87.01 % capacitance after 2000 cycles. Besides, based on electrical energy as the sensing parameter, the composite exhibited augmented cathodic and anodic current sensitivity of 8.77 mJmA-1 and -8.86 mJmA-1, respectively. The ameliorated supercapacitor and current sensing parameters of MC/PANI_B3 are ascribed to the percolation threshold content of the conducting phase, which is endowed with optimal hydrogen bond-mediated interactions with methylcellulose (MC), thus confers an expanded chain conformation.

A bis-chalcone based colorimetric probe for the selective detection of bisulfite/sulfite anions: exploring surfactant promoted Michael addition of anions to α, ß-unsaturated ketones.

A probe, (1E,4E)-1,5-di(thiophen-2-yl)penta-1,4-dien-3-one, was developed for rapid, colorimetric, and selective detection of bisulfite/sulfite anions in aqueous solutions. This probe is based on the Michael addition reaction which is favoured in the presence of cationic micellar medium CTAB. CTAB promoted Michael addition is an effective tool to determine SO2 toxicity, which is mainly expressed in terms of collective concentration of bisulfite and sulfite anions. The probe showed high selectivity and sensitivity toward bisulfite and sulfite over other interfering anions, with a detection limit of 0.43 µM and 0.23 µM, respectively. The possible recognition mechanism of the probe and the analyte was illustrated by NMR, HR-MS, IR, and computational analysis. Moreover, this probe showed great potential for the detection of bisulfite/sulfite in real samples, such as crystal sugar and brown sugar.