Factors affecting climate change concern in Pakistan: are there rural/urban differences?

There is a growing interest in studying the determinants of climate change concern, but there are few studies conducted on developing countries like Pakistan. This study has three objectives. Firstly, to find whether there are differences in climate change concern levels between Pakistani citizens residing in rural and urban areas. Secondly, whether climate change concern is influenced by the same or different factors in rural and urban areas. Finally, whether the religious denomination one adheres to plays a role. The 2015 database provided by Pew Research Center, a representative sample of the Pakistani population, is used, and ordered logit models are run by including the independent variables in steps. The main finding is that the place of residency matters: rural residents show higher levels of concern than their urban counterparts. Climate change concern is influenced in both areas of residence by the gender of the respondent: females are more concerned than males. Nonetheless, there are differences in other determinants of climate change concern in rural and urban areas, for example, the education level, which affects mainly rural citizens. The religious denomination affects the concern of rural residents: Sunni Muslims show higher levels of climate change concern than Shi'a Muslims. Recommendations include the implementation of policies aiming to increase the education level in rural areas and the incorporation of courses and curricular or extra-curricular activities that would promote more concern among high school students.

An estimate of the area of occupancy and population size of Brachycephalus tridactylus (Anura: Brachycephalidae) to reassess its conservation status, with a proposal for conservation measures.

BACKGROUND: We are experiencing a global crisis in conservation, which has led to the prioritization of targets, such as nations, regions, and animal groups, which are necessary while resources are disputed. Brazil is a priority not only because of its megadiversity, high rates of endemism, and frequent descriptions of new species but also because of its high levels of deforestation. Among the species groups prioritized for conservation is the anurans (Amphibia: Anura), the population of which is severely declining. One group of anurans is the genus Brachycephalus, which includes 37 endemic species in the Brazilian Atlantic Rainforest. Some of these species have highly restricted distributions (<100 ha). Thirty new species have been described since 2000, and 55.3% of all species are threatened with extinction. Brachycephalus tridactylus was only recently described and remains restricted to its type locality. Because of its reduced geographical distribution (0.41 km2), it has been proposed to be considered as Vulnerable. The objective of this study is to reevaluate the conservation status of Brachycephalus tridactylus and propose conservation measures. METHODS: We searched for new populations during 2016-2020, evaluated in loco impacts and potential impacts on the species' population, and performed an analysis of the density of this population and estimated its size. International Union for Conservation of Nature (IUCN) criteria were used to assess the conservation status of the species. RESULTS: We recorded the species in seven new localities (from 715-1,140 m above sea level) in the state of São Paulo up to 33 km from the type locality of the species (in state of Paraná). We estimated the area of occupancy as 148.44 km2, densities as one calling male per 4.05 m2 and 130.00 m2, and a total population size of 4,429,722 adult individuals. Based on our finding, we proposed three lines of management: (1) formation of fire brigades, (2) management of residents' mules in the conservation unit and surrounding areas, and (3) management of degraded areas. We recommend changing the species' conservation status from Vulnerable to Endangered because of its fragmented distribution and decline in the area of occupancy and in the quality of its habitat. Our results have expanded the species previous geographic distribution and delimited areas without previous records. Our estimates of population density and size are in accordance with those verified for congeners. The conservation of this species benefits the environments and other species that inhabit them, being, therefore, strategic for receiving conservation actions that will spread throughout the ecosystem.

Determinants of renewable energy consumption in Africa.

Although the role that renewable energy consumption plays on economic growth and emissions has been widely studied, there are relatively few papers focusing on the determinants of renewable energy consumption, and only one study focuses on the factors related to the share of renewables in the energy consumption in Africa. This paper contributes to the literature by filling the gap in knowledge by exploring the nexus between the share of renewables in energy consumption and social and economic variables, for a panel consisting of 21 African countries for the period between 1990 and 2013, extending the set of variables and the time span used by a previous study. Estimating a random-effects generalized least squares regression, we find that countries with a higher Human Development Index and a higher gross domestic product per capita have a lower share of renewable energy in the national grid. On the other hand, an increase in foreign direct investment has been found to be related to higher renewable energy integration. The level of democracy, measured by the Freedom House political rights and civil liberties ratings, does not directly affect the integration level of renewable energy sources. The negative relationship between gross domestic product per capita and the share of renewables contradicts previous findings for developed countries. This contradiction and policy implications are discussed in the light of the review of the energy mix of the selected countries.

Crystal structure of di-µ-hydroxido-bis-[aqua-(1,10-phenanthroline-κ(2) N,N')copper(II)] naphthalene-2,6-di-carboxyl-ate hexa-hydrate.

In the title compound, [Cu2(OH)2(C12H8N2)2(H2O)2](C12H6O4)·6H2O, the two hydroxide groups bridge the two Cu(II) cations, forming a centrosymmetric binuclear complex cation, in which the Cu(II) cation is coordinated by a 1,10-phenanthroline (phen) mol-ecule, one water mol-ecule and two bridging hydroxide O atoms in a distorted N2O3 square-pyramidal coordination geometry. The naphthalene-2,6-di-carboxyl-ate anion is also located on an inversion centre. In the crystal, O-H⋯O hydrogen bonds link the cations, anions and lattice water mol-ecules into a three-dimensional supra-molecular architecture. Extensive π-π stacking is observed between the parallel or nearly parallel aromatic rings of adjacent phen ligands and naphthalenedi-carboxyl-ate anions, the centroid-to-centroid distances ranging from 3.4990 (16) to 3.8895 (16) Å.

Strong Direct Magnetic Coupling in a Dinuclear Co(II) Tetrazine Radical Single-Molecule Magnet.

The ligand-centered radical complex [(CoTPMA)2 -µ-bmtz(.-) ](O3 SCF3 )3 ⋅CH3 CN (bmtz=3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine, TPMA=tris-(2-pyridylmethyl)amine) has been synthesized from the neutral bmtz precursor. Single-crystal X-ray diffraction studies have confirmed the presence of the ligand-centered radical. The Co(II) complex exhibits slow paramagnetic relaxation in an applied DC field with a barrier to spin reversal of 39 K. This behavior is a result of strong antiferromagnetic metal-radical coupling combined with positive axial and strong rhombic anisotropic contributions from the Co(II) ions.