Characterization and isolation method of Gigantochloa scortechinii (Buluh Semantan) cellulose nanocrystals.

This study explored the impact of sodium hydroxide and benzoylation treatment on the production of cellulose nanocrystals from Semantan bamboo (Gigantochloa scortechinii). Bamboo cellulose nanocrystals (BCNs) were obtained via acid hydrolysis, with the effectiveness of an isolation method and chemical treatments demonstrated in removing non-cellulosic constituents. X-ray diffraction analysis revealed a crystalline cellulose II structure for benzoylated BCN (B) and a crystalline cellulose I structure for NaOH-treated BCN (S), with BCN (S) exhibiting a higher crystallinity index (80.55 %) compared to BCN (B) (67.87 %). The yield of BCN (B) (23.68 ± 1.10 %) was higher than BCN (S) (20.65 ± 2.21 %). Transmission electron microscopy images showed a mean diameter of 7.95 ± 2.79 nm for BCN (S) and 9.22 ± 3.38 nm for BCN (B). Thermogravimetric analysis indicated lower thermal stability for BCN (B) compared to BCN (S), with charcoal residues at 600 °C of 31.06 % and 22 %, respectively. Zeta potential values were -41.60 ± 1.97 mV for BCN (S) and -21.80 ± 2.54 mV for BCN (B). Gigantochloa scortechinii holds significant potential for sustainable and eco-friendly applications in the construction, furniture, and renewable energy industries. These findings highlight the versatility and potential of BCNs derived from Gigantochloa scortechinii for various applications.

Fatigue and Impact Properties of Kenaf/Glass-Reinforced Hybrid Pultruded Composites for Structural Applications.

To address the weight, cost, and sustainability associated with fibreglass application in structural composites, plant fibres serve as an alternative to reduce and replace the usage of glass fibres. However, there remains a gap in the comprehensive research on plant fibre composites, particularly in their durability for viable structural applications. This research investigates the fatigue and impact properties of pultruded kenaf/glass-reinforced hybrid polyester composites tailored for structural applications. Utilising kenaf fibres in mat form, unidirectional E-glass fibre direct roving yarns, and unsaturated polyester resin as key constituents, pultruded kenaf/glass hybrid profiles were fabricated. The study reveals that pultruded WK/UG alternate specimens exhibit commendable fatigue properties (18,630 cycles at 60% ultimate tensile strength, UTS) and fracture energy (261.3 kJ/m2), showcasing promise for moderate load structural applications. Notably, the pultruded 3 WK/UG/3WK variant emerges as a viable contender for low-load structural tasks recorded satisfactory fatigue properties (10,730 cycles at 60% UTS) and fracture energy (167.09 kJ/m2). Fatigue failure modes indicate that the stress applied is evenly distributed. Ductile failures and delaminations during impact test can be attributed to damping and energy absorbing properties of kenaf fibres. Moreover, incorporating kenaf as a hybrid alternative demonstrates substantial reductions in cost (35.7-50%) and weight (9.6-19.1%). This research establishes a foundation for advancing sustainable and efficient structural materials and highlights the significant role of materials design in shaping the future of engineering applications.

Thermal degradation, visco-elastic and fire-retardant behavior of hybrid Cyrtostachys Renda/kenaf fiber-reinforced MWCNT-modified phenolic composites.

Natural fibers have emerged as a potential alternate to synthetic fibers, because of their excellent performance, biodegradability, renewability and sustainability. This research has focused on investigating the thermal, visco-elastic and fire-retardant properties of different hybrid Cytostachys Renda (CR)/kenaf fiber (K) (50/0; 35/ 15, 25/25, 15/ 35, 0/50)-reinforced MWCNT (multi-walled carbon nanotubes)-modified phenolic composites. The mass% of MWCNT-modified phenolic resin was maintained 50 mass% including 0.5 mass% of MWCNT. In order to achieve homogeneous dispersion ball milling process was employed to incorporate the MWCNT into phenolic resin (powder). Thermal results from thermogravimetric analysis and differential scanning calorimetric analysis revealed that the hybrid composites (35/15; 35 mass% CR and 15 mass% K) showed higher thermal stability among the composite samples. Visco-elastic results revealed that kenaf fiber-based MWCNT-modified composites (0/50; 0 mass% CR and 50 mass% K) exhibited higher storage and loss modulus due to high modulus kenaf fiber. Fire-retardant analysis (UL-94) showed that all the composite samples met H-B self-extinguishing rating and exhibited slow burning rate according to limiting oxygen index (LOI) test. However, (15/35; 15 mass% CR and 35 mass% K) hybrid composites showed the highest time to ignition, highest fire performance index, lowest total heat release rate, average mass loss rate, average fire growth rate index and maximum average rate of heat emission. Moreover, the smoke density of all hybrid composites was found to be less than 200 which meets the federal aviation regulations (FAR) 25.853d standard. Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) was carried out to select an optimal composite sample considering the thermal, visco-elastic and fire-retardant behaviors. Through TOPSIS analysis, the hybrid (15/35; 15 mass% CR and 35 mass% K) composite sample has been selected as an optimal composite which can be used for high-temperature aircraft and automotive applications.

Selection of Natural Fibre for Pultruded Hybrid Synthetic/Natural Fibre Reinforced Polymer Composites Using Analytical Hierarchy Process for Structural Applications.

Application of synthetic fibres in composites has been raising environmental issues due to carbon emissions from the production site and reliability on non-renewable resources upon production. Hence, this research sets as a preliminary study to select suitable natural fibres to be hybridized with glass fibres for the development of sustainable and high-performance hybrid composites as potential alternative to conventional pultruded fibreglass composites in structural profile applications. In this study, analytical hierarchy process (AHP) was conducted to select the ideal natural fibre as reinforcement in the hybrid pultruded FRP composites suitable for structural applications. Hence, 13 natural fibre candidates were selected as alternatives and six criteria were chosen and analysed to select the best candidate for pultruded hybrid FRP. Criteria such as tensile strength, tensile modulus, density, cellulose content, elongation, and availability of fibres were assigned as the standard of selecting natural fibres for the application intended in this study. Among the 13 alternatives, kenaf was found to be the most suitable reinforcement for the application as it yielded the highest priority vector at 0.1. The results were then validated by carrying out sensitivity analysis to ensure kenaf is the most suitable material for the research.

Review of Recent Efforts in Cooling Photovoltaic Panels (PVs) for Enhanced Performance and Better Impact on the Environment.

The global need for energy has grown in tandem with mankind's development and spread. This has resulted in an increase in the use of fossil energy sources, a decline in these sources and an increase in pollution, necessitating the search for renewable energy sources. One of the important ways to reduce pollution resulting from the increasing consumption of fossil energy is to enhance the sources of solar energy, of which photovoltaic cells (PV) are one of its most important tools. Therefore, it was necessary to pay attention to improving its efficiency for it to become a promising source of clean energy. PVs turn solar energy into electricity; however, the amount of electricity generated decreases as the temperature of the cells rises in response to the sun's heat. Cooling of the optical surfaces is one of the most important elements to consider while running solar PV systems to obtain maximum efficiency. The electrical efficiency of PVs is enhanced when suitable cooling technology is used, and the rate of cell breakdown is reduced over time, extending the life of the PV panels. There are many materials used to remove unwanted heat in PV cells, and in recent years, the focus has been on integrating nanomaterials in specific proportions with traditional cooling materials such as water to improve their thermal properties. As a bio-material that is environmentally friendly, renewable, sustainable, inexpensive and has high mechanical properties, cellulose nanocrystals (CNCs) are one of the most promising materials for improving the properties of cooling materials for cooling PV cells and improving their performance.

A Review on the Effect of Fabric Reinforcement on Strength Enhancement of Natural Fiber Composites.

The main objective of this study is to examine the impact of reinforcements on the strength of natural fiber composites. Recent advancements in natural fiber composites have minimized the usage of man-made fibers, especially in the field of structural applications such as aircraft stiffeners and rotor blades. However, large variations in the strength and modulus of natural fiber degrade the properties of the composites and lower the safety level of the structures under dynamic load. Without compromising the safety of the composite structure, it is significant to enrich the strength and modulus of natural fiber reinforcement for real-time applications. The strength and durability of natural fiber can be enriched by reinforcing natural fiber. The reinforcement effect on natural fiber in their woven, braided, and knit forms enhances their structural properties. It improves the properties of natural fiber composites related to reinforcement with short and random-orientation fibers. The article also reviews the effect of the hybridization of natural fiber with cellulosic fiber, synthetic fiber, and intra-ply hybridization on its mechanical properties, dynamic mechanical properties, and free vibration characteristics, which are important for predicting the life and performance of natural fiber composites for weight-sensitive applications under dynamic load.

Effect of Prosopis Juliflora Thorns on Mechanical Properties of Plastic Waste Reinforced Epoxy Composites.

Plastics are unavoidable at this times, putting our planet in danger. The Prosopis juliflora (PJ) thorns are collected, processed, and powdered. The mechanical characteristics of these powders are examined when combined with polymer composites. Pores are the main cause of moisture input, hence using powder filler materials reduces the number of pores in the composite, increasing water resistance. The composites are made by altering three parameters: waste plastic content, filler powder composition, and chemical treatment. It was discovered that the integration of thorn powder increased the wear resistance. The composites were tested in accordance with ASTM standards, and the results were optimized. Based on the results, composite specimens were created and tested for validation.

The Effect of Stacking Sequence on Fatigue Behaviour of Hybrid Pineapple Leaf Fibre/Carbon-Fibre-Reinforced Epoxy Composites.

This study examined the fatigue behaviour of pineapple leaf fibre/carbon hybrid laminate composites under various stacking sequences. The vacuum infusion technique was used to fabricate the symmetric quasi-isotropic oriented laminates, in which the stacking was varied. The laminate was tested under static and fatigue tensile load according to ASTM D3039-76 and ASTM D3479-96, respectively. Maximum tensile strength and modulus of 119.34 MPa and 6.86 GPa, respectively, were recorded for the laminate with external PALF ply and internal carbon ply oriented at [± 45°2, 0°/90°2]s (PCCP_45090). The fatigue tests showed that PCCP_45090 and CPPC_09045 (with internal PALF ply and external carbon ply oriented at [0°/90°2, ± 45°2]s) exhibited a higher useful life, especially at the high-stress level of the ultimate tensile strength. The normalised stress against the number of cycles showed that the stacking sequences of different ply orientations affected the fatigue behaviour more than the stacking sequences of the material. The laminate stacking sequence significantly affected the hysteresis energy and stiffness evolution. The scanning electron microscopy images showed that the fatigue failure modes included fibre pull-out, fibre breakage, matrix cracking, debonding, and delamination. The study concluded that PCCP_45090 exhibited an outstanding fatigue performance.

Physical, Mechanical, and Morphological Properties of Hybrid Cyrtostachys renda/Kenaf Fiber Reinforced with Multi-Walled Carbon Nanotubes (MWCNT)-Phenolic Composites.

Adequate awareness of sustainable materials and eco-legislation have inspired researchers to identify alternative sustainable and green composites for synthetic fiber-reinforced polymer composites in the automotive and aircraft industries. This research focused on investigating the physical, mechanical, and morphological properties of different hybrid Cyrtostachys renda (CR)/kenaf fiber (K) (10C:0K, 7C:3K, 5C:5K, 3C:7K, 0C:10K) reinforced with 0.5 wt% MWCNT-phenolic composites. We incorporated 0.5 wt% of MWCNT into phenolic resin (powder) using a ball milling process for 25 h to achieve homogeneous distribution. The results revealed that CR fiber composites showed higher voids content (12.23%) than pure kenaf fiber composites (6.57%). CR fiber phenolic composite was more stable to the swelling tendency, resulting in the lowest percentage of swelling rate (4.11%) compared to kenaf composite (5.29%). The addition of kenaf fiber into CR composites had improved the tensile, flexural, and impact properties. The highest tensile and flexural properties were found for weight fraction of CR and kenaf fiber at 5C:5K (47.96 MPa) and 3C:7K (90.89 MPa) composites, respectively. In contrast, the highest impact properties were obtained for 0C:10K composites (9.56 kJ/m2). Based on the FE-SEM image, the CR fiber lumen was larger in comparison to kenaf fiber. The lumen of CR fiber was attributed to higher void and water absorption, lower mechanical properties compared to kenaf fiber. 5C:5K composite was selected as an optimal hybrid composite, based on the TOPSIS method. This hybrid composite can be used as an interior component (non-load-bearing structures) in the aviation and automotive sectors.

COVID-19 outbreak in Malaysia: Actions taken by the Malaysian government.

BACKGROUND: Coronavirus disease 2019 (COVID-19), a novel pneumonia disease originating in Wuhan, was confirmed by the World Health Organization on January 12, 2020 before becoming an outbreak in all countries. OUTBREAK SITUATION: A stringent screening process at all airports in Malaysia was enforced after the first case outside China was reported in Thailand. Up to April 14, 2020, Malaysia had reported two waves of COVID-19 cases, with the first wave ending successfully within less than 2 months. In early March 2020, the second wave occurred, with worrying situations. ACTIONS TAKEN: The Government of Malaysia enforced a Movement Control Order starting on March 18, 2020 to break the chain of COVID-19. The media actively spread the hashtag #stayhome. Non-governmental organizations, as well as prison inmates, started to produce personal protective equipment for frontliners. Various organizations hosted fundraising events to provide essentials mainly to hospitals. A provisional hospital was set up and collaborations with healthcare service providers were granted, while additional laboratories were assigned to enhance the capabilities of the Ministry of Health. ECONOMIC DOWNTURN: An initial financial stimulus amounting to RM 20.0 billion was released in February 2020, before the highlighted PRIHATIN Package, amounting to RM 250 billion, was announced. The PRIHATIN Package has provided governmental support to society, covering people of various backgrounds from students and families to business owners.