1.
Chem Commun (Camb)
; 60(51): 6520-6523, 2024 Jun 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38836330
RESUMO
Adding HClO4 to [(BnTPEN)MnIII-OO]+ in MeOH generates a short-lived MnIII-OOH species, which converts to a putative MnVîO species. The potent MnVîO species in MeCN oxidizes the pendant phenyl ring of the ligand in an intramolecular fashion. The addition of benzene causes the formation of (BnTPEN)MnIII-phenolate. These findings suggest that high valent Mn species have the potential to catalyze challenging aromatic hydroxylation reactions.