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1.
Acta Crystallogr Sect E Struct Rep Online ; 68(Pt 3): m283-4, 2012 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-22412430

RESUMO

In the title coordination compound, [Cu(NCS)(C(9)H(7)N)(C(18)H(15)P)](n), the Cu(I) atom is tetra-hedrally coordinated by one N atom from an isoquinoline ligand, one P atom from a triphenyl-phospane ligand, and one N and one S atom from two thio-cyanate anions. The thio-cyanide anions bridge the Cu(I) atoms into a chain along [100]. π-π inter-actions between the pyridine and benzene rings of the isoquinoline ligands connect the chains [centroid-to-centroid distance = 3.722 (3) Å].

2.
Artigo em Inglês | MEDLINE | ID: mdl-22259542

RESUMO

In the crystal structure of the title compound, C(5)H(8)N(4), adjacent mol-ecules are connected through N-H⋯N hydrogen bonds, resulting in a zigzag chain along [100]. The amino groups and heterocyclic N atoms are involved in further N-H⋯N hydrogen bonds, forming R(2) (2)(8) motifs.

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