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1.
Lancet Planet Health ; 8(7): e476-e488, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38969475

RESUMO

BACKGROUND: Climate actions targeting combustion sources can generate large ancillary health benefits via associated air-quality improvements. Therefore, understanding the health costs associated with ambient fine particulate matter (PM2·5) from combustion sources can guide policy design for both air pollution and climate mitigation efforts. METHODS: In this modelling study, we estimated the health costs attributable to ambient PM2·5 from six major combustion sources across 204 countries using updated concentration-response models and an age-adjusted valuation method. We defined major combustion sources as the sum of total coal, liquid fuel and natural gas, solid biofuel, agricultural waste burning, other fires, and 50% of the anthropogenic fugitive, combustion, and industrial dust source. FINDINGS: Global long-term exposure to ambient PM2·5 from combustion sources imposed US$1·1 (95% uncertainty interval 0·8-1·5) trillion in health costs in 2019, accounting for 56% of the total health costs from all PM2·5 sources. Comparing source contributions to PM2·5 concentrations and health costs, we observed a higher share of health costs from combustion sources compared to their contribution to population-weighted PM2·5 concentration across 134 countries, accounting for more than 87% of the global population. This disparity was primarily attributed to the non-linear relationship between PM2·5 concentration and its associated health costs. Globally, phasing out fossil fuels can generate 23% higher relative health benefits compared to their share of PM2·5 reductions. Specifically, the share of health costs for total coal was 36% higher than the source's contributions to corresponding PM2·5 concentrations and the share of health costs for liquid fuel and natural gas was 12% higher. Other than fossil fuels, South Asia was expected to show 16% greater relative health benefits than the percentage reduction in PM2·5 from the abatement of solid biofuel emissions. INTERPRETATION: In most countries, targeting combustion sources might offer greater health benefits than non-combustion sources. This finding provides additional rationale for climate actions aimed at phasing out combustion sources, especially those related to fossil fuels and solid biofuel. Mitigation efforts designed according to source-specific health costs can more effectively avoid health costs than strategies that depend solely on the source contributions to overall PM2·5 concentration. FUNDING: The Health Effects Institute, the National Natural Science Foundation of China, and NASA.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Saúde Global , Material Particulado , Material Particulado/análise , Poluição do Ar/economia , Poluição do Ar/prevenção & controle , Humanos , Poluentes Atmosféricos/análise , Modelos Teóricos , Exposição Ambiental/prevenção & controle , Carvão Mineral/economia
2.
PLoS One ; 19(7): e0293777, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38980881

RESUMO

An improved algorithm based on Yolov8s is proposed to address the slower speed, higher number of parameters, and larger computational cost of deep learning in coal gangue target detection. A lightweight network, Fasternet, is used as the backbone to increase the speed of object detection and reduce the model complexity. By replacing Slimneck with the C2F part in the HEAD module, the aim is to reduce model complexity and improve detection accuracy. The detection accuracy is effectively improved by replacing the Detect layer with Detect-DyHead. The introduction of DIoU loss function instead of CIoU loss function and the combination of BAM block attention mechanism makes the model pay more attention to critical features, which further improves the detection performance. The results show that the improved model compresses the storage size of the model by 28%, reduces the number of parameters by 28.8%, reduces the computational effort by 34.8%, and improves the detection accuracy by 2.5% compared to the original model. The Yolov8s-change model provides a fast, real-time and efficient detection solution for gangue sorting. This provides a strong support for the intelligent sorting of coal gangue.


Assuntos
Algoritmos , Aprendizado Profundo , Humanos , Carvão Mineral , Redes Neurais de Computação
3.
Environ Geochem Health ; 46(8): 288, 2024 Jul 06.
Artigo em Inglês | MEDLINE | ID: mdl-38970676

RESUMO

The combustion of coal in power plants releases significant amounts of polycyclic aromatic hydrocarbons (PAHs), which are highly toxic and carcinogenic. This study assesses the ecological and human health impacts of PAHs contamination from a coal-fired power plant over 8 years. The monitoring site selection considered the distance from the power plant and the prevailing wind direction in the investigated area. The results reveal that, during the monitoring period, PAH levels increased on average by 43%, 61%, and 37% in the zone of the prevailing wind direction, in the area proximate to the power plant, and the zone distant from it, respectively. The site, which has a radius of 4.5 km in the prevailing wind direction, exhibited the highest ecological and human health impacts. Additionally, a strong correlation was observed between environmental and human health impacts, depending on the distance from the power plant, particularly in areas with the prevailing wind direction. These insights contribute to a comprehensive understanding of the intricate dynamics linking power plant emissions, PAHs contamination, and their far-reaching consequences on the environment and human health.


Assuntos
Carvão Mineral , Monitoramento Ambiental , Hidrocarbonetos Policíclicos Aromáticos , Centrais Elétricas , Poluentes do Solo , Hidrocarbonetos Policíclicos Aromáticos/análise , Humanos , Monitoramento Ambiental/métodos , Poluentes do Solo/análise , Vento , Avaliação do Impacto na Saúde
4.
Sci Rep ; 14(1): 15420, 2024 07 04.
Artigo em Inglês | MEDLINE | ID: mdl-38965345

RESUMO

Due to the low permeability characteristics of the deep gas-containing coal seam, the conventional prevention and control measures that cannot solve the problems of gas outbursts are unsatisfactory for the prevention and control of the coal and gas outbursts disaster. Therefore, in this study, a strain of methane-oxidizing bacteria M07 with high-pressure resistance, strong resistance, and high methane degradation rate was selected from coal mines. The growth and degradation abilities of M07 in chelating wetting agent solutions to assess its adaptability and find the optimal agent-to-M07 ratio. It provides a new method for integrating the reduction of impact tendency and gas pressure in deep coal mines. The experimental results show that M07 is a Gram-positive bacterium of the genus Bacillus, which has strong resistance and adaptability to high-pressure water injection. By degrading 70 mol of methane, M07 produces 1 mol of carbon dioxide, which can reduce gas pressure and reduce the risk of gas outbursts in coal mines. As the experiment proves, the best effect was achieved when the M07 concentration of the chelating wetting agent was 0.05%. The methane-oxidizing bacteria based on the chelating wetting agent as carriers prove a new prevention and control method for the integrated prevention and control of coal and gas outbursts in coal mines and also provide a new idea for microbial application in coal mine disaster control.


Assuntos
Biodegradação Ambiental , Quelantes , Metano , Metano/metabolismo , Metano/química , Quelantes/química , Quelantes/farmacologia , Quelantes/metabolismo , Bacillus/metabolismo , Carvão Mineral , Minas de Carvão
5.
J Environ Manage ; 365: 121650, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38968881

RESUMO

Enhancing the coal-based fulvic acid (FA) yield through the effect of oxidation methods was of great importance. However, the realization of an efficient and environmentally friendly method for the preparation of FA, along with understanding of its formation mechanism, remains imperative. Herein, coal-based FA was prepared by oxidizing lignite with H2O2 and NaOH/KOH. The experimental data showed that ML lignite was pickled with HCl, metal ions such as iron, aluminum, and calcium can be removed, and this lignite is used as raw material, the reaction time was 150 min, the reaction temperature was 50 °C, and the volume ratio of H2O2 (30%) to KOH (3 mol/L) was 1:1, the effect of H2O2 and KOH on FA extraction was the best. The coal-based FA yield could reach 60.49%. The addition of silicone defoaming agent during the experiment resulted in a significant diminished the presence of bubbles and prevent the production of CO2. A decrease in N2 content was detected by GC. The FTIR, XPS, Py-GC/MS and other characterization results showed that FA has more polar functional groups (-COOH, -OH), and it contains more O-CO structure. Consequently, a greater quantity of FA molecules is generated during the reaction process. Moreover, the partial Gibbs free energies during the formation process of coal-based FA were calculated by density-functional theory (DFT). The highest energy required for free radicals was found to be between 1.3 and 1.7 eV. This study would provide theoretical support for exploring the FA formation process and the promotion of lignite humification by adding H2O2 or alkali to lignite.


Assuntos
Benzopiranos , Carvão Mineral , Benzopiranos/química , Peróxido de Hidrogênio/química , Oxirredução , Espectroscopia de Infravermelho com Transformada de Fourier
6.
Radiat Prot Dosimetry ; 200(11-12): 1076-1083, 2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-39016495

RESUMO

In this present study, the nuclear track detector LR-115 (II) was employed to assess radon (222Rn) exhalation rate, effective radium (226Ra) content, and the annual effective dose from coal and soil samples collected in and around the coal mining area of Tiru region of Nagaland, India. The 222Rn mass and surface exhalation rates and 226Ra contents were found to be in the ranges of 7.3-17.3 mBq kg-1 h-1, 242.9-573.6 mBq m-2 h-1 and 1.0-2.3 Bq kg-1, respectively, for coal and 15.8-22.0 mBq kg-1 h-1, 523.8-730.4 mBq m-2 h-1 and 2.1-2.9 Bq kg-1, respectively, for soil. The 222Rn exhalation rates and 226Ra contents in soils were found to be higher than in coal. The estimated annual effective doses for coal and soils were found to be in the ranges of 17.6-41.6 and 38.0-53.0 µSv y-1, respectively. This study is an important contribution to the understanding of radiation exposure in the coal mining area of the thrust-bound sedimentary sequence of the Naga Schuppen Belt, and it would have potential impact on further human health studies. However, the measured values for all the samples were found to be within the globally recognised permissible range.


Assuntos
Poluentes Radioativos do Ar , Doses de Radiação , Monitoramento de Radiação , Rádio (Elemento) , Radônio , Poluentes Radioativos do Solo , Radônio/análise , Índia , Monitoramento de Radiação/métodos , Poluentes Radioativos do Solo/análise , Rádio (Elemento)/análise , Poluentes Radioativos do Ar/análise , Carvão Mineral/análise , Humanos , Minas de Carvão
7.
Environ Geochem Health ; 46(9): 319, 2024 Jul 16.
Artigo em Inglês | MEDLINE | ID: mdl-39012521

RESUMO

Pneumoconiosis is the most common occupational disease among coal miners, which is a lung disease caused by long-term inhalation of coal dust and retention in the lungs. The early stage of this disease is highly insidious, and pulmonary fibrosis may occur in the middle and late stages, leading to an increase in patient pain index and mortality rate. Currently, there is a lack of effective treatment methods. The pathogenesis of pneumoconiosis is complex and has many influencing factors. Although the characteristics of coal dust have been considered the main cause of different mechanisms of pneumoconiosis, the effects of coal dust composition, particle size and shape, and coal dust concentration on the pathogenesis of pneumoconiosis have not been systematically elucidated. Meanwhile, considering the irreversibility of pneumoconiosis progression, early prediction for pneumoconiosis patients is particularly important. However, there is no early prediction standard for pneumoconiosis among coal miners. This review summarizes the relevant research on the pathogenesis and prediction of pneumoconiosis in coal miners in recent years. Firstly, the pathogenesis of coal worker pneumoconiosis and silicosis was discussed, and the impact of coal dust characteristics on pneumoconiosis was analyzed. Then, the early diagnostic methods for pneumoconiosis have been systematically introduced, with a focus on image collaborative computer-aided diagnosis analysis and biomarker detection. Finally, the challenge of early screening technology for miners with pneumoconiosis was proposed.


Assuntos
Minas de Carvão , Poeira , Humanos , Pneumoconiose , Antracose/epidemiologia , Exposição Ocupacional/efeitos adversos , Biomarcadores , Carvão Mineral , Doenças Profissionais/etiologia , Doenças Profissionais/epidemiologia
8.
FEMS Microbiol Lett ; 3712024 Jan 09.
Artigo em Inglês | MEDLINE | ID: mdl-38849297

RESUMO

Biogenic coalbed methane (CBM) is a developing clean energy source. However, it is unclear how the mechanisms of bio-methane production with different sizes of coal. In this work, pulverized coal (PC) and lump coal (LC) were used for methane production by mixed fungi-methanogen microflora. The lower methane production from LC was observed. The aromatic carbon of coal was degraded slightly by 2.17% in LC, while 11.28% in PC. It is attributed to the proportion of lignin-degrading fungi, especially Penicillium, which was reached 67.57% in PC on the 7th day, higher than that of 11.38% in LC. The results suggested that the limited interaction area in LC led to microorganisms hardly utilize aromatics. It also led the accumulation of aromatic organics in the fermentation broth in PC. Increasing the reaction area of coal and facilitating the conversion of aromatic carbon are suggested means to increase methane production in situ.


Assuntos
Biodegradação Ambiental , Carvão Mineral , Fungos , Lignina , Metano , Metano/metabolismo , Carvão Mineral/microbiologia , Fungos/metabolismo , Fungos/classificação , Lignina/metabolismo , Fermentação , Penicillium/metabolismo
9.
Sci Rep ; 14(1): 14827, 2024 06 27.
Artigo em Inglês | MEDLINE | ID: mdl-38937498

RESUMO

Microbial bioaugmentation of coal is considered as a viable and ecologically sustainable approach for the utilization of low-rank coals (LRC). The search for novel techniques to derive high-value products from LRC is currently of great importance. In response to this demand, endeavors have been undertaken to develop microbially based coal solubilization and degradation techniques. The impact of supplementing activated sludge (AS) as a microbial augmentation to enhance LRC biodegradation was investigated in this study. The LRC and their biodegradation products were characterized using the following methods: excitation-emission Matrices detected fluorophores at specific wavelength positions (O, E, and K peaks), revealing the presence of organic complexes with humic properties. FTIR indicated the increased amount of carboxyl groups in the bioaugmented coals, likely due to aerobic oxidation of peripheral non-aromatic structural components of coal. The bacterial communities of LRC samples are primarily composed of Actinobacteria (up to 36.2%) and Proteobacteria (up to 25.8%), whereas the Firmicutes (63.04%) was the most abundant phylum for AS. The community-level physiological profile analysis showed that the microbial community AS had high metabolic activity of compared to those of coal. Overall, the results demonstrated successful stimulation of LRC transformation through supplementation of exogenous microflora in the form of AS.


Assuntos
Biodegradação Ambiental , Carvão Mineral , Esgotos , Esgotos/microbiologia , Bactérias/metabolismo , Actinobacteria/metabolismo , Espectroscopia de Infravermelho com Transformada de Fourier , Proteobactérias/metabolismo
10.
Environ Sci Technol ; 58(26): 11301-11308, 2024 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-38900968

RESUMO

Tens of thousands of people in southern Europe suffer from Balkan endemic nephropathy (BEN), and four times as many are at risk. Incidental ingestion of aristolochic acids (AAs), stemming from the ubiquitousAristolochia clematitis(birthwort) weed in the region, leads to DNA adduct-induced toxicity in kidney cells, the primary cause of BEN. Numerous cofactors, including toxic organics and metals, have been investigated, but all have shown small contributions to the overall BEN relative to non-BEN village distribution gradients. Here, we reveal that combustion-derived pollutants from wood and coal burning in Serbia also contaminate arable soil and test as plausible causative factors of BEN. Using a GC-MS screening method, biomass-burning-derived furfural and coal-burning-derived medium-chain alkanes were detected in soil samples from BEN endemic areas levels at up to 63-times and 14-times higher, respectively, than in nonendemic areas. Significantly higher amounts were also detected in colocated wheat grains. Coexposure studies with cultured kidney cells showed that these pollutants enhance DNA adduct formation by AA, - the cause of AA nephrotoxicity and carcinogenicity. With the coincidence of birthwort-derived AAs and the widespread practice of biomass and coal burning for household cooking and heating purposes and agricultural burning in rural low-lying flood-affected areas in the Balkans, these results implicate combustion-derived pollutants in promoting the development of BEN.


Assuntos
Nefropatia dos Bálcãs , Inundações , Nefropatia dos Bálcãs/induzido quimicamente , Nefropatia dos Bálcãs/epidemiologia , Humanos , Carvão Mineral , Sérvia , Poluentes do Solo/toxicidade , Ácidos Aristolóquicos , Animais , Aristolochia/química , Península Balcânica , Madeira , Nefropatias/induzido quimicamente
11.
Environ Sci Technol ; 58(25): 11118-11127, 2024 Jun 25.
Artigo em Inglês | MEDLINE | ID: mdl-38864774

RESUMO

Intermediate volatility organic compounds (IVOCs) are important precursors to secondary organic aerosols (SOAs), but they are often neglected in studies concerning SOA formation. This study addresses the significant issue of IVOCs emissions in the Qinghai-Tibetan plateau (QTP), where solid fuels are extensively used under incomplete combustion conditions for residential heating and cooking. Our field measurement data revealed an emission factor of the total IVOCs (EFIVOCs) ranging from 1.56 ± 0.03 to 9.97 ± 3.22 g/kg from various combustion scenarios in QTP. The markedly higher EFIVOCs in QTP than in plain regions can be attributed to oxygen-deficient conditions. IVOCs were dominated by gaseous phase emissions, and the primary contributors of gaseous and particulate phase IVOCs are the unresolved complex mixture and alkanes, respectively. Total IVOCs emissions during the heating and nonheating seasons in QTP were estimated to be 31.7 ± 13.8 and 6.87 ± 0.45 Gg, respectively. The estimated SOA production resulting from combined emissions of IVOCs and VOCs is nearly five times higher than that derived from VOCs alone. Results from this study emphasized the pivotal role of IVOCs emissions in air pollution and provided a foundation for compiling emission inventories related to solid fuel combustion and developing pollution prevention strategies.


Assuntos
Aerossóis , Poluentes Atmosféricos , Carvão Mineral , Compostos Orgânicos Voláteis , Compostos Orgânicos Voláteis/análise , Poluentes Atmosféricos/análise , China , Animais , Tibet , Monitoramento Ambiental
12.
Environ Sci Pollut Res Int ; 31(28): 41208-41220, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38849616

RESUMO

Reasonable treatment of large amounts of sludge excavated from landfills has gained increasing attention due to the diminishing availability of landfill space in China. In this study, five landfill sludge (LS) treatment technologies using life cycle assessment (LCA) and life cycle cost (LCC) were investigated, i.e., co-incineration in coal-fired power plants (CFPP) and waste incineration power plant (WIPP), co-processing in cement kiln, bricks production, and sintering ceramsite. The LCA results demonstrate that sintering ceramsite outperforms other technologies and LCC results indicate sintering ceramsite also provides the highest economic benefit ($869.94). To further enhance environmental and economic performances of the LS treatment, the substitution of coal with natural gas and biomass can reduce Energy Conservation and Emission Reduction (ECER) index by 74% and 98%, respectively. This substitution can increase economic returns by 24% and 26%, respectively. Furthermore, national-level economic benefit and carbon emission reduction potential of different LS treatment technology alternative scenarios were assessed. Results display that a combination of 50% CFPP, 25% bricks, and 25% ceramsite (biomass) offers the highest economic gain, which is 3.02 times that of 50% CFPP and 50% cement (original case). Conversely, the replacement of 25% brick with 25% cement in the above combination result in the lowest carbon reduction, which is 9.35 times that of the original case.


Assuntos
Esgotos , Instalações de Eliminação de Resíduos , China , Incineração , Carvão Mineral
13.
Environ Sci Pollut Res Int ; 31(30): 43351-43368, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38900404

RESUMO

To solve the problem of unclear targeted inhibition of key free radicals by antioxidants, this paper took the hydroxyl radical with the highest oxidation activity of coal as the inhibition target and selected five antioxidants such as ethylene diamine tetraacetic acid, tea polyphenol, citric acid, vitamin C, and proanthocyanidins. Based on the theory of quantum chemistry, the characteristics and oxidation pathway of antioxidants inhibiting coal oxidation of hydroxyl radical were analyzed. Analyze the influence characteristics of antioxidants on the evolution of free radicals in coal through an electron paramagnetic resonance experiment (ESR). The results showed that the electron density of antioxidants was mainly distributed in the functional groups of carboxyl and hydroxyl, which played a key inhibitory role, and the vicinity of carboxyl and hydroxyl and other functional groups was positive potential, which was the active site of inhibiting hydroxyl radical. The order of inhibitory capacity of the five antioxidants was determined as GTP > PC > EDTA > CA > VC. It is concluded that the energy barrier of hydroxyl radical inhibition by citric acid is much lower than that of EDTA. For the hydrogen extraction reaction, VC inhibited the hydroxyl radical pathway with a higher energy barrier than the other three antioxidants. The mechanism of five antioxidants inhibiting •OH reaction was comprehensively analyzed. It was found that tea polyphenols have more active sites that can react with •OH to quench it, so the inhibition of tea polyphenols should be the most significant. When antioxidants inhibit coal spontaneous combustion, the type, complexity, concentration, and linewidth of free radicals in coal molecules are lower than those in raw coal, with GTP antioxidants having the best inhibitory effect. The research results have important theoretical and practical significance for revealing the mechanism of coal spontaneous combustion inhibition and developing directional coal spontaneous combustion inhibition technology.


Assuntos
Antioxidantes , Carvão Mineral , Radical Hidroxila , Oxirredução , Radical Hidroxila/química , Antioxidantes/química , Antioxidantes/farmacologia , Espectroscopia de Ressonância de Spin Eletrônica
14.
J Environ Manage ; 365: 121474, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38936022

RESUMO

In the current global context, there is a pressing need to curtail greenhouse gas emissions, making the utilization of a coal and zero-carbon energy blend an imperative strategy for reducing carbon emissions from coal-fired power generation. The planar flame burner serves as a tool to simulate the temperature and atmospheric conditions within the reburning zone, facilitating extensive examination of the physical and chemical structural alterations, as well as the nitrogen oxide reduction potential, during NH3/CH4 activation for reburning pulverized coal. Experimental results underscore that blending high-activity fuels optimizes the combustion performance of coal char. Through the addition of NH3 and CH4, the NO reduction capability of coal char is bolstered by approximately 0.67 times compared to sole reliance on recirculating flue gas transport. Furthermore, NH3 introduction facilitates the conversion of C]O double bonds into C-O single bonds, rendering them more amenable to reduction by NO. While the joint influence of NH3 and CH4 does not significantly impact char particle size, it does foster the evolution of N-Q to N-5 and N-6 on the char surface. Furthermore, there was a significant increase in the BET-specific surface area, which rose by 50%. Additionally, the total pore volume increased by approximately 21.43%. The comprehensive understanding of NH3 and CH4 modified pulverized coal reburning technology holds significant promise for optimizing power plant operations and mitigating carbon dioxide and nitrogen oxide emissions.


Assuntos
Amônia , Carvão Mineral , Metano , Metano/química , Amônia/química , Centrais Elétricas
15.
Environ Sci Pollut Res Int ; 31(29): 41980-41989, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38856857

RESUMO

Coal is one of the primary energy sources in China and is widely used for electricity generation. Crops growing in overlapped areas of farmland and coal resources (OAFCR) suffer from coal fly ash stress, especially during stem elongation, which is a key stage that impacts wheat yield and is sensitive to environmental stress. As a primary food crop of China, wheat is essential for food security. However, the characteristics of wheat under the combined stress of fly ash and various heavy metals have not been sufficiently investigated. In this study, we explored the response of stem elongation in wheat to different levels of coal fly ash stress and determined the content of heavy metals (HMs) in wheat leaves. We found that with an increase in fly ash content, the Cu content in the shoots increased, while that in the roots decreased. Coal fly ash exposure reduced the proportions of Pb and Zn in the cytoderm, and the proportion of Cu in the soluble constituents decreased from 58.3% to 45.7%. Total chlorophyll, chlorophyll a, and chlorophyll b levels decreased significantly, whereas peroxidase (POD) and catalase (CAT) activities generally increased with increasing fly ash dose. Meanwhile, chloroplasts, mitochondria, and their internal structures were damaged, and the cell structures of leaves, such as the internal membrane structure, were damaged.


Assuntos
Cinza de Carvão , Metais Pesados , Fotossíntese , Triticum , Fotossíntese/efeitos dos fármacos , Carvão Mineral , Folhas de Planta , Caules de Planta/efeitos dos fármacos , Clorofila , China , Estresse Fisiológico
16.
Environ Sci Pollut Res Int ; 31(29): 42230-42250, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38865043

RESUMO

This research focuses on the synthesis of novel low-cost granular sorbents based on bentonite clay of the Navbahor deposit, dust fraction of Angren brown coal, and agricultural wastes such as straw and sawdust to meet the internal needs of the Republic of Uzbekistan. The impact of the initial mixture ingredients on the structural and textural properties of bentonite-coal sorbents (BCSs) has been studied using X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, optical microscopy, and nitrogen adsorption-desorption analysis. For determining the sorption capacity of BCSs, a standard model substance methylene blue (MB), was applied. It was revealed that the maximum adsorption amount of MB was 5.3 mg∙g-1 during 2 h of contact. Prolonging the contact time to 24 h allowed for more extensive diffusion of dye molecules into the sorbent's pores, increasing the adsorption capacity to 13 mg∙g-1. It was demonstrated that BCSs could be regenerated by strong oxidizing agents such as sulfuric acid and hydrogen peroxide, with sulfuric acid proving more effective. Regeneration fully restores sorption properties, particularly at low dye concentrations (up to 0.2 mg∙ml-1). Despite slight reductions in adsorption capacity over multiple regeneration cycles, the sorbents maintain their structural integrity and durability. It is shown that compared to imported expensive activated carbon, the gross profitability of the in-house production of such granular BCSs within the territory of Uzbekistan increases from 48 to 78%, while the net income increases almost three times.


Assuntos
Bentonita , Carbono , Bentonita/química , Adsorção , Cinética , Carbono/química , Espectroscopia de Infravermelho com Transformada de Fourier , Difração de Raios X , Uzbequistão , Carvão Mineral
17.
Environ Monit Assess ; 196(7): 593, 2024 Jun 03.
Artigo em Inglês | MEDLINE | ID: mdl-38829441

RESUMO

Coal power activities could cause regional fluctuations of trace elements, but the distribution information of these trace elements in arid and semi-arid areas is insufficient. In this study, the soil trace elements (As, B, Be, Cd, Co, Cr, Cu, Fe, Ga, Ge, Mn, Mo, Ni, Pb, Sb, Sn, Sr, Ti, Tl, and Zn) of Ningdong Coal Power Production Base in China were monitored. Results showed that the concentrations of B, Tl, Mn, Pb, Cr, K, Cu, and Co exceeded background values. The maximum risk index reached 265.66, while the trace elements posed a cancer risk to children. Combining correlation analyses (CA), principal component analysis (PCA), and positive matrix factorization (PMF) techniques, it indicated that trace elements were mainly coming from coal combustion (34.15%), livestock farming (17.44%), traffic emissions (12.42%), and natural factors (35.99%). This study reveals the sources and potential ecological risks of soil trace elements in the Ningdong Coal and Power Production Base. It provides a scientific basis for developing targeted environmental management measures and reducing human health risks.


Assuntos
Carvão Mineral , Monitoramento Ambiental , Poluentes do Solo , Solo , Oligoelementos , China , Oligoelementos/análise , Poluentes do Solo/análise , Solo/química , Centrais Elétricas , Humanos
18.
J Environ Manage ; 365: 121441, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38897076

RESUMO

In response to environmental concerns at the global level, there is considerable momentum in the exploration of materials derived from waste that are both sustainable and eco-friendly. In this study, CS-Fe (carbon, silica, and iron) composite was synthesized from coal gasification slag (CGS) and innovatively applied as a catalyst to activate PS (persulfate) for the degradation of trichloroethylene (TCE) in water. Scanning electron microscope (SEM), fourier transmission infrared spectroscopy (FTIR), energy dispersive x-ray spectroscopy (EDS), brunauer, emmet, and teller (BET) technique, and x-ray diffractometer (XRD) spectra were employed to investigate the surface morphology and physicochemical composition of the CS-Fe composite. CS-Fe catalyst showed a dual nature by adsorption and degradation of TCE simultaneously, displaying 86.1% TCE removal in 3 h. The synthesized CS-Fe had better adsorption (62.1%) than base material CGS (36.4%) due to a larger BET surface area (770.8 m2 g-1), while 24.0% TCE degradation was recorded upon the activation of PS by CS-Fe. FTIR spectra confirmed the adsorption and degradation of TCE by investigating the used and fresh samples of CS-Fe catalyst. Scavengers and Electron paramagnetic resonance (EPR) analysis confirmed the availability of surface radicals and free radicals facilitated the degradation process. The acidic nature of the solution favored the degradation while the presence of bicarbonate ion (HCO3-) hindered this process. In conclusion, these results for real groundwater, surfactant-added solution, and degradation of other TCE-like pollutants propose that the CS-Fe composite offers an economically viable and favorable catalyst in the remediation of organic contaminants within aqueous solutions. Further investigation into the catalytic potential of coal gasification slag-based carbon materials and their application in Fenton reactions is warranted to effectively address a range of environmental challenges.


Assuntos
Carvão Mineral , Ferro , Tricloroetileno , Tricloroetileno/química , Ferro/química , Poluentes Químicos da Água/química , Adsorção , Catálise , Espectroscopia de Infravermelho com Transformada de Fourier
19.
Calcif Tissue Int ; 115(2): 117-123, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-38902530

RESUMO

The cause of Paget's disease of bone (PDB) is unknown. It emerged as a distinct entity in Britain in the late nineteenth century when it was prevalent, and florid presentation not uncommon. Epidemiological surveys in the 1970s showed that Britain had a substantially higher prevalence of PDB than any other country. Studies in the late twentieth and early twenty-first centuries have documented an unexplained change in presentation, with a greatly reduced prevalence and less severe disease than formerly. The emergence of PDB in Britain coincided with rapid industrialization which, in turn, was driven by the use of coal for energy. In the home, bituminous coal was customarily burnt on an open hearth for heating. Using data on coal production, population size, and estimates of domestic use, the estimated exposure to domestic coal burning rose threefold in Britain during the nineteenth century and began to fall after 1900. This pattern fits well with the decline in PDB documented from death certification and prevalence surveys. Colonists moving from Britain to North America, Australia and New Zealand established coal mines and also used coal for domestic heating. PDB was found in these settler populations, but was largely absent from people indigenous to these lands. In all parts of the world PDB prevalence has fallen as the burning of coal in open hearths for domestic heating has reduced. The nature of the putative factor in coal that could initiate PDB is unknown, but possible candidates include both organic and inorganic constituents of bituminous coal.


Assuntos
Carvão Mineral , Osteíte Deformante , Humanos , Carvão Mineral/efeitos adversos , Osteíte Deformante/epidemiologia , Reino Unido/epidemiologia , História do Século XIX , Prevalência , História do Século XX , Minas de Carvão
20.
Environ Sci Pollut Res Int ; 31(31): 43712-43730, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38907821

RESUMO

To control the diffusion of high concentrations of coal dust during tunnel boring and minimize the threat to the life and health of coal miners, theoretical analysis, numerical simulations, and field measurements were combined in this study. First, computational fluid dynamic simulation software was used to simulate the generation of dust particles and their transport pattern in the tunnel. Subsequently, an innovative orthogonal test was performed to study the effect of four ventilation parameters [the pressure airflow rate (Q), distance between the air duct center and heading face (LA), distance between the air duct center and tunnel floor (LB), and distance between the air duct center and nearest coal wall (LC)] on dust diffusion. According to the orthogonal test results, the optimal ventilation parameters for effective dust control are as follows: Q = 1400 m3/min, LA = 7 m, LB = 2.8 m, and LC = 1 m. The optimized set of ventilation parameters was applied to the Wangpo 3206 working face. The results show that dust diffusion in the tunnel was effectively controlled and that the air quality was sufficiently improved.


Assuntos
Carvão Mineral , Poeira , Ventilação , Poluição do Ar/prevenção & controle , Hidrodinâmica , Simulação por Computador , Minas de Carvão , Humanos
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