RESUMO
The importance of environmental issues and the existence of humans have led to the recognition of environmental concerns as the main risk to modern life. Notably, one major concern for protecting and managing the environment and human health is the presence of dyes in wastewater. Therefore, before discharging wastewater into mainstream water, it is crucial to remove dyes. Among all lignocellulosic materials, lignin is a highly fragrant biopolymer. Its abundant availability, complex structure, and numerous functional moieties, including hydroxyl, carboxyl, and phenolic, are used in different chemicals and applications. Based on this, lignin is a very useful green material for adsorption, specifically in removing both heavy metals and organic pollutants from wastewater. This article describes the use of lignin-based adsorbents as a recent breakthrough in the removal of dye from aqueous solutions. On the other hand, the review intends to encourage readers to study both established and novel avenues in lignin-based dye removal materials.
Assuntos
Corantes , Lignina , Poluentes Químicos da Água , Purificação da Água , Lignina/química , Corantes/química , Corantes/isolamento & purificação , Adsorção , Poluentes Químicos da Água/isolamento & purificação , Poluentes Químicos da Água/química , Purificação da Água/métodos , Águas Residuárias/químicaRESUMO
Gac fruit (Momordica cochinchinensis Spreng.) is a prominent source of carotenoids, renowned for its exceptional concentration of these compounds. This study focuses on optimizing the extraction of active components from the aril of gac fruit by evaluating the effects of extraction temperature, solid-liquid ratio, and extraction time. The primary objective is to maximize the yield of gac oil while assessing its antioxidant capacity. To analyze the kinetics of the solid-liquid extraction process, both first-order and second-order kinetic models were employed, with the second-order model providing the best fit for the experimental data. In addition, the potential of gac fruit peel as a precursor for biochar production was investigated through carbonization. The resultant biochars were evaluated for their efficacy in adsorbing crystal violet (CV) dye from aqueous solutions. The adsorption efficiency of the biochars was found to be dependent on the carbonization temperature, with the highest efficiency observed for BCMC550 (91.72%), followed by BCM450 (81.35%), BCMC350 (78.35%), and BCMC250 (54.43%). The adsorption isotherm data conformed well to the Langmuir isotherm model, indicating monolayer adsorption behavior. Moreover, the adsorption kinetics were best described by the pseudo-second-order model. These findings underscore the potential of gac fruit and its byproducts for diverse industrial and environmental applications, highlighting the dual benefits of optimizing gac oil extraction and utilizing the peel for effective dye removal.
Assuntos
Carvão Vegetal , Frutas , Violeta Genciana , Carvão Vegetal/química , Adsorção , Frutas/química , Violeta Genciana/química , Violeta Genciana/isolamento & purificação , Cinética , Corantes/química , Corantes/isolamento & purificação , Temperatura , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificaçãoRESUMO
The purpose of this research was to evaluate the efficacy of sodium lignosulfonate (LS) as a dye adsorbent in the removal of methylene blue (MB) from water by polymer-enhanced ultrafiltration. Various parameters were evaluated, such as membrane molecular weight cut-off, pH, LS dose, MB concentration, applied pressure, and the effect of interfering ions. The results showed that the use of LS generated a significant increase in MB removal, reaching an elimination of up to 98.0 % with 50.0 mg LS and 100 mg L-1 MB. The maximum MB removal capacity was 21 g g-1 using the enrichment method. In addition, LS was reusable for up to four consecutive cycles of dye removal-elution. The removal test in a simulated liquid industrial waste from the textile industry was also effective, with a MB removal of 97.2 %. These findings indicate that LS is highly effective in removing high concentrations of MB dye, suggesting new prospects for its application in water treatment processes.
Assuntos
Lignina , Azul de Metileno , Ultrafiltração , Poluentes Químicos da Água , Purificação da Água , Azul de Metileno/química , Lignina/química , Lignina/análogos & derivados , Ultrafiltração/métodos , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Concentração de Íons de Hidrogênio , Corantes/química , Corantes/isolamento & purificação , Adsorção , Polímeros/químicaRESUMO
The ongoing challenge of water scarcity persists alongside a concerning rise in water pollution driven by population expansion and industrial development. As a result, urgent measures are imperative to address the pressing need for a clean and sustainable water supply. In this study, a sustainable and green approach was utilized to prepare four chitosan-based sponges from a chemically modified chitosan with different alkyl chains in aqueous medium and at room temperature. The resulting sponges displayed excellent stability in water with outstanding dye removal efficiency. The adsorption capacity was associated with the alkyl chain length incorporated to the polymer backbone. All sponges displayed a high adsorption capacity of methyl orange (MO) ranges between 238 and 380 mg g-1, while a low capacity were obtained for methylene blue (MB) and Rhodamine B (RB). Competitive adsorption experiments were conducted on binary and ternary mixtures to assess the selective removal of MO from a mixture of dyes in which the separation factor was found to be ranging between 1.6 and 32. The adsorption kinetics isotherms of all sponges followed the pseudo-second-order, and the Langmuir model was found to be more suitable than the Freundlich for the adsorption of MO on the sponges. The chitosan-based sponges showed stable performance, robustness and reusability over 5 adsorption-desorption cycles, indicating their great potential for water treatment applications.
Assuntos
Quitosana , Corantes , Poluentes Químicos da Água , Purificação da Água , Quitosana/química , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Corantes/química , Corantes/isolamento & purificação , Cinética , Azul de Metileno/química , Azul de Metileno/isolamento & purificação , Compostos Azo/química , Compostos Azo/isolamento & purificação , Concentração de Íons de Hidrogênio , Rodaminas/químicaRESUMO
Biomaterials like chitosan, hydroxyapatite have been used in biomedical and pharmaceutical field, due to its valuable biochemical and physiological properties. In current work firstly our group has isolated a polysaccharide chitosan along with hydroxyapatite biomaterial from the same source by varying the process condition via greener approach. We have adapted greener approach for the isolation of chitosan within a short period of time and this is the very first report for the isolation of both chitosan and hydroxyapatite simultaneously from the same waste edible garden snail shells. Both these materials were thoroughly characterized by using UV, FT-IR, SEM techniques. Among synthetic colourants, congo red dye is recognized as carcinogens, which are usually used in the textile manufacturing. Interestingly, one of our biomaterial hydroxyapatite has shown good selectivity towards Congo red dye. The sensitivity range was obtained from 10 to 100 µM within the LOD of 101.52 nM. The developed sensor has been tested for various industrial effluents and shown good agreement with our results. Meanwhile these chitosan and hydroxyapatite have also been used as capping agent for the preparation of stable gold nanoparticles.
Assuntos
Quitosana , Vermelho Congo , Durapatita , Quitosana/química , Vermelho Congo/química , Animais , Durapatita/química , Caramujos/química , Exoesqueleto/química , Química Verde/métodos , Corantes/química , Corantes/isolamento & purificação , Corantes/análise , Espectroscopia de Infravermelho com Transformada de Fourier , Nanopartículas Metálicas/química , Ouro/químicaRESUMO
The most prominent and easily identifiable factor of water purity is its colour, which may be both physically undesirable, and act as an alert towards potential environmental contamination. The current study describes the optimum synthesis technique for Lemon Peel-Chitosan hydrogel using the Response Surface Methodology integrated Central composite Design (RSM-CCD). This adsorbent is both environmentally friendly and cost-effective. The hydrogel exhibited a maximal dye removal capacity of 24.984, 24.788, 24.862, 23.483, 24.409, and 24.726 mg g-1, for 10 mg L-1 aqueous medium of Safranin O, Methylene blue, Basic fuchsin, Toluidine blue, Brilliant green and Crystal violet, respectively. The adsorption kinetics and isotherm data suggest that the Pseudo second-order kinetic and Freundlich adsorption isotherm models precisely represent the respective behaviour of all the dyes. The thermodynamic viability of the process is determined by the values of ΔG, ΔH, and ΔS. The probable mechanism of adsorption was the electrostatic interaction between the dye molecules and the hydrogel. The regenerated hydrogel had removal efficiencies of over 80 % even after enduring six cycles. Hence, the exceptional recyclability and utility of the adsorbent show their sustainability for wastewater treatment in textile factories.
Assuntos
Quitosana , Citrus , Corantes , Hidrogéis , Poluentes Químicos da Água , Purificação da Água , Quitosana/química , Adsorção , Corantes/química , Corantes/isolamento & purificação , Hidrogéis/química , Citrus/química , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Cinética , Purificação da Água/métodos , Concentração de Íons de Hidrogênio , Termodinâmica , Cátions/químicaRESUMO
Cosmetics, textiles, foodstuffs, and medicines frequently contain the yellow dye tartrazine. It has carcinogenic properties and can trigger allergies. In this study, a unique NH2-MIL-101(Cr)/chitosan composite (MIL/chitosan composite) was created using a hydrothermal process. The effectiveness of this composite in removing Tartrazine (TZ) from aqueous solutions was investigated. It was characterized via FT-IR, XPS, XRD, and BET analysis. The surface area of the MIL/chitosan nanoadsorbent sample was 1256.64 m2/g, where after five times recycling, it was reduced to 1068.14 m2/g. The study analyzed the impact of dye concentration, pH, temperature, and MIL/chitosan composite dosage. Experimental measurements were taken for the equilibrium isotherms of dye adsorption. The kinetic models and adsorption isotherm were used to analyze the results. The adsorption process was found to match Langmuir and pseudo-second-order kinetic models. Chemisorption was the mechanism of the adsorption process. Based on thermodynamic parameters, it was determined that the adsorption process was endothermic. The MIL/chitosan composite was recycled up to five cycles. Using the MIL/chitosan composite towards the adsorption of the tartrazine from the real sample has been checked. The interaction process between the MIL/chitosan nanoadsorbent and Tartrazine adsorbate has been investigated. The TZ electrical characteristics, reactivity, and shape were ascertained through the application of density functional theory (DFT). The placement of electrophilic and nucleophilic attack sites is in good agreement with the molecular orbitals (HOMO and LUMO) and MEP results, according to DFT. The optimization of adsorption results was accomplished using Box-Behnken design (BBD).
Assuntos
Quitosana , Estruturas Metalorgânicas , Tartrazina , Poluentes Químicos da Água , Quitosana/química , Tartrazina/química , Estruturas Metalorgânicas/química , Adsorção , Cinética , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Concentração de Íons de Hidrogênio , Purificação da Água/métodos , Temperatura , Termodinâmica , Corantes/química , Corantes/isolamento & purificação , Água/química , SoluçõesRESUMO
Membrane separation technology has emerged as a powerful tool to separate organic dyes from industrial wastewater. However, continuously selective separation of organic dyes with similar molecular weight remains challenging. Herein, we presented a pH-triggered membrane composed of polydopamine-decorated tunicate-derived cellulose nanofibers (PDA@TCNFs) for selective separation of organic dyes. Such self-supporting membranes with nanoporous structure were fabricated by facile vacuum-assisted filtration of PDA@TCNF suspension. The incorporation of polydopamine not only enhanced the stability of the membranes, but also endowed membranes with excellent pH sensitivity, facilitating the continuously selective separation of organic dyes. These pH-triggered PDA@TCNF membranes could selectively separate Methyl Orange (MO) and Rhodamine B (RB) from the MO/RB mixed solution by switching the pH values. The continuously selective separation of the MO/RB mixed solution was demonstrated, where both MO and RB recovery ratios maintained at â¼99 % during 50 repeated cycles. This work provides a new strategy to develop a pH-triggered sustainable nanocellulose-based membrane for continuously selective separation of mixed dyes.
Assuntos
Celulose , Corantes , Indóis , Membranas Artificiais , Polímeros , Celulose/química , Indóis/química , Concentração de Íons de Hidrogênio , Polímeros/química , Corantes/química , Corantes/isolamento & purificação , Nanofibras/química , Rodaminas/química , Compostos Azo/química , Compostos Azo/isolamento & purificaçãoRESUMO
The widespread use of organic dyes in various industrial applications, driven by rapid industrialization, has become a significant environmental concern. Thus, highly efficient and reusable adsorbent for removal of pollutant dyes have gained increasing attention in water treatment. In this study, we present TiO2 nanoparticle-embedded mesoporous starch-based microparticle (TiO2@MSMP) with hierarchical rose-like structure were synthesis by using acetone precipitation of short-chain glucan (SCG) obtained from waxy maize starch. The resulting TiO2@MSMP exhibits an A-type crystalline polymorph and mean particle size of approximately 2 µm, displaying a type IV adsorption isotherm with a mean pore diameter of 19 nm and an average surface area of 12.34 m2/g. The adsorption ability of TiO2@MSMP towards methyl orange (MO) and crystal violet (CV) were 85.8 mg/g and 103.8 mg/g, respectively. The reusability of TiO2@MSMP was achieved by UV irradiation, which resulted in photodegradation of the adsorbed dye over 80 % while maintaining good absorption ability and structural stability during the recycling process. Given its cost-effectiveness, high adsorption capacity, and excellent reusability, TiO2@MSMP holds promise as an effective and environmentally friendly adsorbent with significant potential for removing dyes from aqueous solutions and purifying water.
Assuntos
Corantes , Amido , Titânio , Poluentes Químicos da Água , Purificação da Água , Titânio/química , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Corantes/química , Corantes/isolamento & purificação , Amido/química , Purificação da Água/métodos , Porosidade , Água/química , Solubilidade , Compostos Azo/química , Compostos Azo/isolamento & purificaçãoRESUMO
This study explores the effectiveness of Alginate-coated nanoiron oxide combined with copper-based MOFs (Cu-BTC@Alg/Fe3O4) composites for the sustainable and efficient removal of Rhodamine B (RhB) dye from wastewater through adsorption and photocatalysis. Utilizing various characterization techniques such as FTIR, XRD, SEM, and TEM, we confirmed the optimal synthesis of this composite. The composites exhibit a significant surface area of approximately 160 m2 g-1, as revealed by BET analysis, resulting in an impressive adsorption capacity of 200 mg g-1 and a removal efficiency of 97 %. Moreover, their photocatalytic activity is highly effective, producing environmentally friendly degradation byproducts, thus underlining the sustainability of Cu-BTC@Alg/Fe3O4 composites in dye removal applications. Our investigation delves into kinetics and thermodynamics, revealing a complex adsorption mechanism influenced by both chemisorption and physisorption. Notably, the adsorption kinetics indicate equilibrium attainment within 100 min across all initial concentrations, with the pseudo-second-order kinetic model fitting the data best (R2 ≈ 0.999). Furthermore, adsorption isotherm models, including Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich, elucidate the adsorption behavior, with the Temkin and Dubinin-Radushkevich models showing superior accuracy compared to the Langmuir model (R2 ≈ 0.98 and R2 ≈ 0.96, respectively). Additionally, thermodynamic analysis reveals a negative Gibbs free energy value (-6.40 kJ mol-1), indicating the spontaneity of the adsorption process, along with positive enthalpy (+24.3 kJ mol-1) and entropy (+82.06 kJ mol-1 K) values, suggesting an endothermic and disorderly process at the interface. Our comprehensive investigation provides insights into the optimal conditions for RhB adsorption onto Cu-BTC@Alg/Fe3O4 composites, highlighting their potential in wastewater treatment applications.
Assuntos
Alginatos , Cobre , Rodaminas , Águas Residuárias , Poluentes Químicos da Água , Purificação da Água , Rodaminas/química , Alginatos/química , Cobre/química , Cobre/isolamento & purificação , Águas Residuárias/química , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Cinética , Compostos Férricos/química , Termodinâmica , Estruturas Metalorgânicas/química , Catálise , Corantes/química , Corantes/isolamento & purificaçãoRESUMO
Considering the increase in the discharge of industrial effluents containing dyes and antibiotic resistance as a consequence of increasing the prescription and easy distribution of antibiotic drugs at the global level, designing efficient, biodegradable and non-toxic absorbents is necessary to reduce environmental harm effects. Herein, we present a series of novel eco-friendly ternary hybrid nanocomposite hydrogels CS/TiO2@MWCNT (CTM) composed of chitosan (CS), TiO2, and multiwalled carbon nanotube (MWCNT) for removal of methylene blue (MB) and methyl orange (MO) and common antibiotic ciprofloxacin (CIP) in aqueous medium. The combination of MWCNT and TiO2 improves the physicochemical properties of CS hydrogel and increases the adsorption capacity toward pollutants in the presence of different loadings. CTM hydrogel showed a specific surface area of 236.45 m2 g-1 with a pore diameter of 7.89 nm. Adsorption mechanisms were investigated in detail using kinetic, isotherm, and thermodynamic studies of adsorption as well as various spectroscopic techniques. Adsorption of these pollutants by CTM nanocomposite hydrogel occurred using various interactions at different pHs, which showed the obvious dependence of CTM adsorption capacity on pH. Electrostatic attractions, complex formation, π-π stacking and hydrogen bonds played a key role in the adsorption process. The adsorption of MB, MO, and CIP was fitted with the Langmuir isotherm with maximum adsorption capacities of 531.91, 1763.6, and 1510.5 mg g-1, respectively. CTM had a minor decrease in adsorption strength and showed good structural stability even after 8 adsorptions-desorption cycles. The total cost of producing a 1 kg adsorbent was calculated to be $ 450, which helped us determine the economic feasibility of the adsorbent in large-scale applications.
Assuntos
Antibacterianos , Quitosana , Corantes , Nanocompostos , Nanotubos de Carbono , Titânio , Poluentes Químicos da Água , Purificação da Água , Quitosana/química , Titânio/química , Antibacterianos/química , Adsorção , Corantes/química , Corantes/isolamento & purificação , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Nanotubos de Carbono/química , Nanocompostos/química , Purificação da Água/métodos , Cinética , Concentração de Íons de Hidrogênio , Compostos Azo/química , Compostos Azo/isolamento & purificação , Termodinâmica , Hidrogéis/química , Azul de Metileno/química , Azul de Metileno/isolamento & purificação , Propriedades de SuperfícieRESUMO
Jatobá-do-cerrado fruit shells, archetypical of lignocellulosic-based biomass, were used as an adsorbent to remove crystal violet (CV) and methylene blue (MB) from water. The adsorbent was characterized using various techniques, and kinetic studies showed dye adsorption followed second-order kinetics. An experimental design investigated the effects of pH and temperature on removal efficiency, with a quadratic model fitting the data best. The results suggest pH influences MB's adsorption capacity more than temperature and at 25 °C and pH 8, MB had a desirability value of 0.89, with 95 % removal efficiency. For CV, temperature had a greater influence, with a desirability value of 0.874 at 25 °C and pH 10, and 95 % removal efficiency. Adsorption isotherm studies revealed maximum adsorption capacities of 123.0 mg·g-1 and 113.0 mg·g-1 for CV and MB, respectively. Experimental thermodynamic parameters indicated an endothermic and spontaneous process which it was supported by quantum chemistry calculations. The protocols developed confirmed the potential for adsorbing CV and MB dyes in water, achieving over 73.1 and 74.4 mg g-1 dyes removal.
Assuntos
Biomassa , Corantes , Lignina , Azul de Metileno , Poluentes Químicos da Água , Adsorção , Lignina/química , Corantes/química , Corantes/isolamento & purificação , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Concentração de Íons de Hidrogênio , Cinética , Azul de Metileno/química , Azul de Metileno/isolamento & purificação , Temperatura , Purificação da Água/métodos , Violeta Genciana/química , Violeta Genciana/isolamento & purificação , Termodinâmica , Teoria da Densidade FuncionalRESUMO
The persistent water treatment and separation challenge necessitates innovative and sustainable advances to tackle conventional and emerging contaminants in the aquatic environment effectively. Therefore, a unique three-dimensional (3D) network composite film (BNC-KC) comprised of bacterial nanocellulose (BNC) incorporated nano-kaolinite clay particles (KC) was successfully synthesized via an in-situ approach. The microscopic characterization of BNC-KC revealed an effective integration of KC within the 3D matrix of BNC. The investigated mechanical properties of BNC-KC demonstrated a better performance compared to BNC. Thereafter, the sorption performance of BNC-KC films towards basic blue 9 dye (Bb9) and norfloxacin (NFX) antibiotic from water was investigated. The maximum sorption capacities of BNC-KC for Bb9 and NFX were 127.64 and 101.68 mg/g, respectively. Mechanistic studies showed that electrostatic interactions, multi-layered sorption, and 3D structure are pivotal in the NFX/Bb9 sorption process. The intricate architecture of BNC-KC effectively traps molecules within the interlayer spaces, significantly increasing sorption efficiency. The distinctive structural configuration of BNC-KC films effectively addressed the challenges of post-water treatment separation while concurrently mitigating waste generation. The environmental evaluation, engineering, and economic feasibility of BNC-KC are also discussed. The cost estimation assessment of BNC-KC revealed the potential to remove NFX and Bb9 from water at an economically viable cost.
Assuntos
Celulose , Poluentes Químicos da Água , Celulose/química , Poluentes Químicos da Água/química , Poluentes Químicos da Água/análise , Adsorção , Argila/química , Purificação da Água/métodos , Norfloxacino/química , Antibacterianos/química , Silicatos de Alumínio/química , Corantes/química , Corantes/isolamento & purificaçãoRESUMO
Textile and cosmetic industries generate large amounts of dye effluents requiring treatment before discharge. This wastewater contains high levels of reactive dyes, low to none-biodegradable materials and chemical residues. Technically, dye wastewater is characterised by high chemical and biological oxygen demand. Biological, physical and pressure-driven membrane processes have been extensively used in textile wastewater treatment plants. However, these technologies are characterised by process complexity and are often costly. Also, process efficiency is not achieved in cost-effective biochemical and physical treatment processes. Membrane distillation (MD) emerged as a promising technology harnessing challenges faced by pressure-driven membrane processes. To ensure high cost-effectiveness, the MD can be operated by solar energy or low-grade waste heat. Herein, the MD purification of dye wastewater is comprehensively and yet concisely discussed. This involved research advancement in MD processes towards removal of dyes from industrial effluents. Also, challenges faced by this process with a specific focus on fouling are reviewed. Current literature mainly tested MD setups in the laboratory scale suggesting a deep need of further optimization of membrane and module designs in near future, especially for textile wastewater treatment. There is a need to deliver customized high-porosity hydrophobic membrane design with the appropriate thickness and module configuration to reduce concentration and temperature polarization (CP and TP). Also, energy loss should be minimized while increasing dye rejection and permeate flux. Although laboratory experiments remain pivotal in optimizing the MD process for treating dye wastewater, the nature of their time intensity poses a challenge. Given the multitude of parameters involved in MD process optimization, artificial intelligence (AI) methodologies present a promising avenue for assistance. Thus, AI-driven algorithms have the potential to enhance overall process efficiency, cutting down on time, fine-tuning parameters, and driving cost reductions. However, achieving an optimal balance between efficiency enhancements and financial outlays is a complex process. Finally, this paper suggests a research direction for the development of effective synthetic and natural dye removal from industrially discharged wastewater.
Assuntos
Corantes , Destilação , Membranas Artificiais , Indústria Têxtil , Eliminação de Resíduos Líquidos , Águas Residuárias , Poluentes Químicos da Água , Águas Residuárias/química , Destilação/métodos , Corantes/química , Corantes/isolamento & purificação , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/química , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Resíduos IndustriaisRESUMO
In the study, a novel chitosan biopolymer and 1-ethyl-3-methylimidazolium tetrafluoroborate ionic liquid (IL)-incorporated sulfonated poly (ether ether ketone) (SPEEK) composite (Ch-IL@SPEEK) was prepared for adsorption of cationic crystal violet (CV) dye. The proposed composite was well characterized by several techniques. CV adsorption performance was examined via batch studies by varying various variables involving adsorbent dosage, contact time pH and temperature. The isotherm results were demonstrated the adsorption characters of the processes were Langmuirian. The maximum adsorption capacity was determined as 77.66 mg g-1 for the composite which was significantly higher than SPEEK (qmax = 45.36 mg g-1). The determined equilibrium time of the operated system was 360 min and the kinetic model was assessed as Elovich. At low pHs the protonated surface groups repelled the positively charged CV and the adsorption rate increased with increasing pH. The process is spontaneous and favorable as it proceeds via endothermic interactions. Furthermore, even at the end of 5 successful adsorption cycles, 77.86 % CV removal was obtained. Remarkable efficiencies were also achieved in the removal performance of different organic pollutants. Based on the reported results, Ch-IL@SPEEK composite were exhibited as an impressive adsorbent material for adsorption processes.
Assuntos
Quitosana , Violeta Genciana , Líquidos Iônicos , Poluentes Químicos da Água , Quitosana/química , Líquidos Iônicos/química , Violeta Genciana/química , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Concentração de Íons de Hidrogênio , Cinética , Temperatura , Corantes/química , Corantes/isolamento & purificação , Purificação da Água/métodos , Polímeros/química , Polietilenoglicóis/químicaRESUMO
Since the potential carcinogenic, toxic and non-degradable dyes trigger serious environmental contamination by improper treatment, developing novel adsorbents remains a major challenge. A novel high efficiency and biopolymer-based environmental-friendly adsorbent, chitosansodium tripolyphosphate-melamine sponge (CTS-STPP-MS) composite, was prepared for Orange II removing with chitosan as raw material, sodium tripolyphosphate as cross-linking agent. The composite was carefully characterized by SEM, EDS, FT-IR and XPS. The influence of crosslinking conditions, dosage, pH, initial concentration, contacting time and temperature on adsorption were tested through batch adsorption experiments. CTS-STPP-MS adsorption process was exothermic, spontaneous and agreed with Sips isotherm model accompanying the maximum adsorption capacity as 948 mgâg-1 (pH = 3). Notably, the adsorption performance was outstanding for high concentration solutions, with a removal rate of 97 % in up to 2000 mgâL-1 OII solution (100 mg sorbent dosage, 50 mL OII solution, pH = 3, 289.15 K). In addition, the adsorption efficiency yet remained 97.85 % after 5 repeated adsorption-desorption cycles. The driving force of adsorption was attributed to electrostatic attraction and hydrogen bonds which was proved by adsorption results coupled with XPS. Owing to the excellent properties of high-effective, environmental-friendly, easy to separate and regenerable, CTS-STPP-MS composite turned out to be a promising adsorbent in contamination treatment.
Assuntos
Compostos Azo , Quitosana , Triazinas , Poluentes Químicos da Água , Quitosana/química , Quitosana/análogos & derivados , Adsorção , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Triazinas/química , Compostos Azo/química , Compostos Azo/isolamento & purificação , Concentração de Íons de Hidrogênio , Purificação da Água/métodos , Benzenossulfonatos/química , Cinética , Polifosfatos/química , Ânions/química , Temperatura , Corantes/química , Corantes/isolamento & purificaçãoRESUMO
Polyvinyl chloride (PVC), known for its chemical stability and flame-retardant qualities, has many uses in various fields, such as pipes, electric wires, and cable insulation. Research has established its potential recovery as a fluidic fuel through pyrolysis, but the use of PVC pyrolysis oil, which is tainted by chlorine, is constrained by its low heat value and harmful environmental effects. This study engineered a layered double hydroxide (LDH) to tackle these challenges. The LDH facilitated dechlorination during PVC pyrolysis and bolstered thermal stability via cross-linking. During pyrolysis with LDH, PVC was transformed into carbon-rich precursors to sorbents. Chemical activation of these residues using KOH created sorbents with a specific surface area of 1495.4 m2 gâ»1, rendering them hydrophilic. These resulting sorbents displayed impressive adsorption capabilities, removing up to 486.79 mg gâ»1 of methylene blue and exhibiting the simultaneous removal of cations and anions.
Assuntos
Corantes , Hidróxidos , Cloreto de Polivinila , Cloreto de Polivinila/química , Hidróxidos/química , Adsorção , Corantes/química , Corantes/isolamento & purificação , Compostos de Potássio/química , Poluentes Químicos da Água/química , Azul de Metileno/química , PiróliseRESUMO
The development of biopolymer-based filtration systems for water remediation applications is an extremely fascinating area of research. In this paper, we developed a biopolymer-based filtration system using sodium alginate (NaAlg) and carrageenan (Car) for the removal of the toxic cationic dye, methylene blue (MB). The membrane's properties were assessed using FTIR, TGA, UTM, FESEM, EDS, XRD, and water uptake, revealing commendable thermomechanical stability (5.79 MPa), good hydrophilicity, and compatibility. The experimental results further revealed that lambda Car/calcium alginate (λ-Car/CaAlg) exhibited superior dye rejection (100%) and flux (11.67 L m-2 h-1) compared to kappa Car/CaAlg (κ-Car/CaAlg) (99.22% and 11.19 L m-2 h-1) and plain alginate (CaAlg) (99.63% and 9.79 L m-2 h-1). The high MB rejection rate was attributed to the sieving mechanism and electrostatic interaction. A rejection rate of 100% was achieved at an initial MB concentration of 10 mg/L, pressure of 0.1 MPa, pH of 7, and temperature of 25°C. Furthermore, the hydrogel membranes demonstrated excellent recyclability over nine cycles, indicating their potential for water treatment applications.
Assuntos
Alginatos , Carragenina , Corantes , Membranas Artificiais , Purificação da Água , Alginatos/química , Carragenina/química , Purificação da Água/métodos , Corantes/química , Corantes/isolamento & purificação , Hidrogéis/química , Filtração/métodos , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Azul de Metileno/química , Azul de Metileno/isolamento & purificação , Cátions/química , Concentração de Íons de HidrogênioRESUMO
The present work develops an effective bioadsorbent of cross-linked chitosan-genipin/SiO2 adsorbent (CHI-GNP/SiO2). The developed CHI-GNP/SiO2 was employed for the removal of organic dye (reactive orange 16, RO16) from simulated wastewater. The optimization of the fundamental adsorption variables (CHI-GNP/SiO2 dose, time, and pH) via the Box-Behnken design (BBD) was attained for achieving maximal adsorption capacity and high removal efficiency. The good agreement between the Freundlich isotherms and empirical data of RO16 adsorption by CHI-GNP/SiO2 indicates that the adsorption process follows a multilayer adsorption mechanism. The reasonable agreement between the pseudo-second-order model and the kinetic data of RO16 adsorption by CHI-GNP/SiO2 was obtained. The maximum RO16 adsorption capacity (qmax) of CHI-GNP/SiO2 was identified to be 57.1 mg/g. The adsorption capacity of CHI-GNP/SiO2 is attributed to its unique surface properties, including its highly porous structure and the presence of functional groups such as amino and hydroxyl groups. According to the results of this investigation, CHI-GNP/SiO2 has the potential to be an adsorbent for the removal of acidic dyes from wastewater.
Assuntos
Compostos Azo , Quitosana , Dióxido de Silício , Poluentes Químicos da Água , Purificação da Água , Quitosana/química , Dióxido de Silício/química , Adsorção , Compostos Azo/química , Compostos Azo/isolamento & purificação , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Cinética , Purificação da Água/métodos , Concentração de Íons de Hidrogênio , Modelos Estatísticos , Águas Residuárias/química , Corantes/química , Corantes/isolamento & purificação , IridoidesRESUMO
The development of chitosan-based adsorbents with facile preparation, high adsorption performance and reusability for the removal of contaminant dyes remains a persistent challenge. To overcome this challenge, herein, we have developed a novel and extremely facile one-step strategy by which a new high-performance chitosan/polyethyleneimine/polyethylene glycol diglycidyl ether adsorbent (named as CC/PEI/PGDE) has been successfully fabricated via direct functionalization of CC by PEI at ambient temperature followed by subsequent freeze-drying. The Box-Behnken Design was employed to optimize the concentrations of adsorbent components. Attractively, this adsorbent exhibit outstanding adsorption performances to congo red (RED), acid blue-25 (BLUE) and amino black-10B (BLACK) with 2901 mg g-1 (90.9 %), 3434 mg g-1 (90.9 %), and 1438 mg g-1 (90.1 %) of adsorption capacities (removal efficiencies), respectively, and maintains nearly the same adsorption behaviors to original adsorbent even after 6 cycles of adsorption-desorption processes. Meanwhile, three kinetic models, three isothermal models, and the Vant Hoff model are employed to further investigate the adsorption behaviors of RED, BLUE, and BLACK dyes by CC/PEI/PGDE. The results from SEM, EDS, BET, FT-IR, pHZPC and XPS confirm that hydrogen bond interactions and electrostatic attractions play crucial roles in facilitating dyes adsorption by CC/PEI/PGDE. It is expected that this work can bring forward a new perspective for the facile design of high-performance adsorbent for removing anionic dyes from wastewater.