Formation of the intermediate-spin iron(III) porphyrin complexes with (dxz, dyz)3(dxy)1(dz2)1 electron configuration.
J Am Chem Soc
; 125(43): 13028-9, 2003 Oct 29.
Article
en En
| MEDLINE
| ID: mdl-14570467
On the basis of the difference in meso-13C chemical shifts, we have concluded that the intermediate-spin iron(III) complexes with highly ruffled and highly saddled porphyrins have different electron configurations. While the latter has a conventional (dxy)2(dxz, dyz)2(dz2)1, the former adopts a novel (dxz, dyz)3(dxy)1(dz2)1.
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J Am Chem Soc
Año:
2003
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Article
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Japón