Synthesis of methyl 4'-O-methyl-13C12-beta-D-cellobioside from 13C6-D-glucose. Part 1: reaction optimization and synthesis.
Carbohydr Res
; 340(15): 2428-35, 2005 Oct 31.
Article
en En
| MEDLINE
| ID: mdl-16153619
ABSTRACT
A high yielding synthetic route for methyl 4'-O-methyl-beta-D-cellobioside starting from d-glucose was established. The reaction conditions optimized with nonlabeled materials were used for the synthesis of methyl 4'-O-methyl-13C12-beta-D-cellobioside, a compound having more than 99% 13C enrichment at each of the twelve pyranose carbon atoms. The labeled compound is required to study the hydrogen bond network of cellodextrins and cellulose by CPMAS NMR experiments.
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Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Celobiosa
/
Glucosa
Idioma:
En
Revista:
Carbohydr Res
Año:
2005
Tipo del documento:
Article
País de afiliación:
Austria