An isocyanide probe for heme electronic structure: bis(tert-butylisocyanide) complex of diazaporphyrin showing a unique (dxy)2(dxz, dyz)3 ground state.
Chem Commun (Camb)
; (44): 4590-2, 2006 Nov 28.
Article
en En
| MEDLINE
| ID: mdl-17082852
Isocyanide-bound model hemes always adopt the (dxz, dyz)4(dxy)1 ground state, however, we have found that the replacement of porphyrin by diazaporphyrin leads to the formation of an unprecedented low-spin bis(tert-butylisocyanide) complex with the (dxy)2(dxz, dyz)3 ground state.
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Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Compuestos Férricos
/
Electrones
/
Hemo
/
Metaloporfirinas
/
Nitrilos
Tipo de estudio:
Prognostic_studies
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2006
Tipo del documento:
Article
País de afiliación:
Japón