Tuning of ruthenium complex properties using pyrrole- and pyrrolidine-containing polypyridine ligands.
Inorg Chem
; 46(6): 2272-7, 2007 Mar 19.
Article
en En
| MEDLINE
| ID: mdl-17305332
ABSTRACT
The effect of pyrrole- and pyrrolidine-containing ligands (L) on the properties of heteroleptic [RuL2dcbpy]2+ complexes has been investigated. TiO2 electrodes modified with the new complexes exhibited extended absorption domains and high absorbances. Providing that a cobalt-based mediator was used for regeneration of the RuII state, good incident photon-to-current efficiency (near 80%) values were obtained in the pyrrole series.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2007
Tipo del documento:
Article
País de afiliación:
Francia