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Formation and properties of metal clusters isolated in helium droplets.
Tiggesbäumker, Josef; Stienkemeier, Frank.
Afiliación
  • Tiggesbäumker J; Institut für physik, Universität Rostock, 18051, Rostock, Germany.
Phys Chem Chem Phys ; 9(34): 4748-70, 2007 Sep 14.
Article en En | MEDLINE | ID: mdl-17712454
The unique conditions forming atomic and molecular complexes and clusters using superfluid helium nanodroplets have opened up an innovative route for studying the physical and chemical properties of matter on the nanoscale. This review summarizes the specific characteristics of the formation of atomic clusters partly generated far from equilibrium in the helium environment. Special emphasis is on the optical response, electronic properties as well as dynamical processes which are mostly affected by the surrounding quantum matrix. Experiments include the optical induced response of isolated cluster systems in helium under quite different excitation conditions ranging from the linear regime up to the violent interaction with a strong laser field leading to Coulomb explosion and the generation of highly charged atomic fragments. The variety of results on the outstanding properties in the quantum size regime highlights the peculiar capabilities of helium nanodroplet isolation spectroscopy.
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Modelos Moleculares / Sustancias Macromoleculares / Helio / Metales / Modelos Químicos Tipo de estudio: Prognostic_studies Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2007 Tipo del documento: Article País de afiliación: Alemania
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Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Modelos Moleculares / Sustancias Macromoleculares / Helio / Metales / Modelos Químicos Tipo de estudio: Prognostic_studies Idioma: En Revista: Phys Chem Chem Phys Asunto de la revista: BIOFISICA / QUIMICA Año: 2007 Tipo del documento: Article País de afiliación: Alemania
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