rac-1-(Furan-2-ylmeth-yl)-N-nitro-5-(oxolan-2-ylmeth-yl)-1,3,5-triazinan-2-imine.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 10): o2581, 2010 Sep 18.
Article
en En
| MEDLINE
| ID: mdl-21587563
In the title compound C(13)H(19)N(5)O(4), which belongs to the insecticidally active neonicotinoid group of compounds, the triazane ring exhibits a half-chair conformation. The large discrepancy between the two nitro O-N-N bond angles [116.1â
(2) and 123.98â
(19)°] may be attributed to intra-molecular N-Hâ¯O hydrogen bonding involving one of the nitro O atoms as the acceptor. The delocalization of the electrons extends as far as the nitro group, forming coplanar π-electron networks. In the crystal, inversion dimers lined by pairs of N-Hâ¯O hydrogen bonds occur.
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Acta Crystallogr Sect E Struct Rep Online
Año:
2010
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Article