Total synthesis of (-)-sessilifoliamide J.
J Org Chem
; 78(1): 35-41, 2013 Jan 04.
Article
en En
| MEDLINE
| ID: mdl-22946828
ABSTRACT
An efficient synthesis of the Stemona alkaloid (-)-sessilifoliamide J (1) in 12 steps and 7.7% overall yield from the known building block 8 is presented. The synthesis features the Corey lactonization reaction and a highly diastereoselective α-methylation reaction to build the spiro-lactone moiety.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Compuestos de Espiro
/
Alcaloides
/
Lactonas
Idioma:
En
Revista:
J Org Chem
Año:
2013
Tipo del documento:
Article
