Bimodal calix[2]triazole[2]arene fluorescent ionophore.
Org Lett
; 15(16): 4058-61, 2013 Aug 16.
Article
en En
| MEDLINE
| ID: mdl-23915313
ABSTRACT
Pyrene-appended calix[2]triazole[2]arene capable of bimodal sensing has been synthesized. Upon addition of Zn(2+) (or Cd(2+)), it selectively exhibits an enhanced monomeric emission (~13-20-fold) over other metal ions. On the other hand, it displays excellent selectivity for Fe(2+) over other metal ions (even over Fe(3+)) from the angle of excimeric emissions (10-fold enhancement). Density Functional Theory (DFT) based theoretical calculations distinguished the bimodal activity of the probe and supported the experimental observations.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Triazoles
/
Calixarenos
/
Ionóforos
/
Metales
Idioma:
En
Revista:
Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2013
Tipo del documento:
Article