Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)5CrC(NC4H8)CH3].
Phys Chem Chem Phys
; 16(39): 21230-3, 2014 Oct 21.
Article
en En
| MEDLINE
| ID: mdl-25188765
ABSTRACT
Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.
Texto completo:
1
Colección:
01-internacional
Base de datos:
MEDLINE
Asunto principal:
Compuestos Organometálicos
/
Temperatura
/
Monóxido de Carbono
/
Cromo
/
Técnicas Electroquímicas
/
Metano
Idioma:
En
Revista:
Phys Chem Chem Phys
Asunto de la revista:
BIOFISICA
/
QUIMICA
Año:
2014
Tipo del documento:
Article
País de afiliación:
Irlanda