Syntheses of sugar poly(orthoesters) through reverse anomeric effect.

Li, Lingyao; Wang, Jun; Obrinske, Melissa; Milligan, Ian; O'Hara, Kylie; Bitterman, Lindsay; Du, Wenjun

Li, Lingyao; Wang, Jun; Obrinske, Melissa; Milligan, Ian; O'Hara, Kylie; Bitterman, Lindsay; Du, Wenjun.

Afiliación

Li L; Department of Chemistry and Biochemistry, Science of Advanced Materials, Central Michigan University, Mount Pleasant, MI 48859, USA. du1w@cmich.edu.

Chem Commun (Camb) ; 51(32): 6972-5, 2015 Apr 25.

Article en En | MEDLINE | ID: mdl-25797911

ABSTRACT

ABSTRACT

High molecular weight sugar poly(orthoesters) were synthesized through reverse anomeric effect (RAE). We demonstrated that when RAE-enabled promoters, such as 4-(dimethylamino)pyridine (DMAP), triphenylphosphine (TPP) or imidazole, were employed, efficient polymerizations were achieved, giving sugar poly(orthoesters) with molecular weights up to 18 kDa.

Asunto(s)

Carbohidratos/química; Poliésteres/química; Poliésteres/síntesis química; Técnicas de Química Sintética; Estereoisomerismo

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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Poliésteres / Carbohidratos Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2015 Tipo del documento: Article País de afiliación: Estados Unidos

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