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Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions.
Shen, Chong; Liu, Ren-Rong; Fan, Ren-Jie; Li, Ying-Long; Xu, Teng-Fei; Gao, Jian-Rong; Jia, Yi-Xia.
Afiliación
  • Shen C; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Liu RR; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Fan RJ; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Li YL; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Xu TF; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Gao JR; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
  • Jia YX; College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
J Am Chem Soc ; 137(15): 4936-9, 2015 Apr 22.
Article en En | MEDLINE | ID: mdl-25849154
A highly enantioselective intramolecular arylative dearomatization of indoles via palladium-catalyzed reductive Heck reactions was developed. The new strategy led to a series of optically active indolines bearing C2-quaternary stereocenters in modest to good yields with excellent enantioselectivities (up to 99% ee).
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Paladio / Indoles Idioma: En Revista: J Am Chem Soc Año: 2015 Tipo del documento: Article País de afiliación: China
Texto completo
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Imprimir
XML
PubMed Links
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Texto completo: 1 Colección: 01-internacional Base de datos: MEDLINE Asunto principal: Compuestos Organometálicos / Paladio / Indoles Idioma: En Revista: J Am Chem Soc Año: 2015 Tipo del documento: Article País de afiliación: China