Surface structure of V_{2}O_{3}(0001) revisited.
Phys Rev Lett
; 114(21): 216101, 2015 May 29.
Article
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| MEDLINE
| ID: mdl-26066445
ABSTRACT
In a recent paper [A. J. Window et al., Phys. Rev. Lett. 107, 016105 (2011)], it was proposed that V_{2}O_{3}(0001) is terminated by the so-called O_{3} termination, a reconstruction with a terminating distorted hexagonal oxygen layer. We show that the surface is terminated by vanadyl (VâO) groups instead. This conclusion is based on quantitative low-energy electron diffraction combined with scanning tunneling microscopy, fast atom scattering, and density functional theory employing the Heyd-Scuseria-Ernzerhof functional. New insights into the subsurface sensitivity of ion beam triangulation show that results previously interpreted in favor of the O_{3} termination are reconcilable with vanadyl termination as well.
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Colección:
01-internacional
Base de datos:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Año:
2015
Tipo del documento:
Article
País de afiliación:
Alemania